96278-02-3

Basic information

• Product Name: 3,4,5-tribenzyloxybenzamide
• Synonyms: 3,4,5-tribenzyloxybenzamide
• CAS NO: 96278-02-3
• Molecular Weight: 439.511
• Mol File: 96278-02-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3,4,5-tribenzyloxybenzamide(CAS DataBase Reference)
• NIST Chemistry Reference: 3,4,5-tribenzyloxybenzamide(96278-02-3)
• EPA Substance Registry System: 3,4,5-tribenzyloxybenzamide(96278-02-3)

Safety Data

• Hazardous Substances Data: 96278-02-3(Hazardous Substances Data)

Upstream product

• 1486-48-2 3,4,5-tribenzyloxybenzoic acid 
• 70424-94-1 methyl 3,4,5-tris(benzyloxy)benzoate 

Downstream Products

• 618-73-5 3,4,5-trihydroxybenzamide 

Relevant articles and documents

Design and synthesis of two aromatic amines with dendritic structure

The design and synthesis of two aromatic amines with dendritic structures, i.e. 3,4,5-tribenzyloxyaniline (3,4,5-G1-NH2) and 2,5-dibenzyloxyaniline (2,5-G1-NH2), were conducted. A coupling reaction of three or two equivalents of benzyl bromide to one equivalent of methyl hydroxybenzoate generated methyl 3,4,5-tribenzyloxybenzoate (3,4,5-G1-COOCH3), methyl 2,5-dibenzyloxybenzoate (2,5-G1-COOCH3) and 2,6-dibenzyloxybenzoate (2,6-G1-COOCH3) in high yields. All G1-COOCH3 derivatives were studied by X-ray analysis. The results show that these dendrons have sufficient volume to be used as the fine ligands for certain catalysts. The amide intermediates (benzamide, G1-CONH2) were obtained by reaction between ammonia and G1-COOCH3. Interestingly, 2,6-dibenzyloxybenzamide (2,6-G1-CONH2) can not be prepared in the same condition, which may be due to the overlarge steric block. Sodium hypochlorite was an effective oxidant to generate methyl carbamates G1-NHCO2CH3.