96424-10-1

Basic information

• Product Name: 1-Pyrrolidinecarboxylic acid, 2,5-dimethyl-, ethyl ester, cis-
• CAS NO: 96424-10-1
• Molecular Formula: C9H17NO2
• Molecular Weight: 171.239
• Mol File: 96424-10-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-Pyrrolidinecarboxylic acid, 2,5-dimethyl-, ethyl ester, cis-(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Pyrrolidinecarboxylic acid, 2,5-dimethyl-, ethyl ester, cis-(96424-10-1)
• EPA Substance Registry System: 1-Pyrrolidinecarboxylic acid, 2,5-dimethyl-, ethyl ester, cis-(96424-10-1)

Safety Data

• Hazardous Substances Data: 96424-10-1(Hazardous Substances Data)

Upstream product

• 7319-00-8 (E)-1,4-hexadiene 
• 51-79-6 urethane 

Relevant articles and documents

Stereoselective Addition of Carbamates to Unsaturated Systems by Means of Mecury(II) Nitrate. Synthesis of Saturated Nitrogen-containing Heterocycles

The aminomercuration of dienes with carbamates and mercury(II) nitrate affords, after in situ demercuration with sodium borohydride, stereoselectively saturated nitrogen-containing heterocycles.Thus, the corresponding amidomercuration-demercuration of 1,4- or 1,5-hexadiene, and diallyl ether gives respectively N-alkoxycarbonyl cis-2,5-dimethylpyrrolidines and trans-3,5-dimethylmorpholines.From 1,5-cyclooctadiene 9-alkoxycarbonyl-9-azabicyclo- and -nonanes (molar ratio ca.1:1) are obtained.By amidomercuration-demercuration of N-allylurethane cis-N,N'-bis(ethoxycarbonyl)-2,5-dimethylpiperazine is obtained.The intermolecular amidomercuration of unsaturated systems results stereochemically opposite to the same aminomercuration process.