96516-91-5Relevant articles and documents
Selective alkyl ether cleavage by cationic bis(phosphine)iridium complexes
Jones, Caleb A. H.,Schley, Nathan D.
supporting information, p. 1744 - 1748 (2019/02/20)
Catalysts capable of heterolytic silane activation have been successfully applied to the conversion of alkyl ethers to silyl ethers via C-O bond cleavage. The previously-reported cationic pincer-supported iridium complex for this transformation suffers fr
Synthesis and Utilization of the Chiral Synthon Methyl 3-O-Benzyl-2,4,6-trideoxy-6-iodo-α-D-erythro-hexopyranoside in the Synthesis of a Potent HMG-CoA Reductase Inhibitor
Prugh, John D.,Rooney, C. Stanley,Deana, Albert A.,Ramjit, Harri G.
, p. 648 - 657 (2007/10/02)
Synthesis of the potent HMG-CoA reductase inhibitor 1a has been achieved by utilizing the chiral synthon 2, which was prepared from methyl α-D-glucopyranoside in 12 steps (6 new).A key step in this sequence, which should have general applicability for the