96597-85-2

Basic information

• Product Name: Benzene, 1-bromo-2-[(3-methyl-2-butenyl)oxy]-
• CAS NO: 96597-85-2
• Molecular Formula: C11H13BrO
• Molecular Weight: 241.128
• Mol File: 96597-85-2.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Benzene, 1-bromo-2-[(3-methyl-2-butenyl)oxy]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-bromo-2-[(3-methyl-2-butenyl)oxy]-(96597-85-2)
• EPA Substance Registry System: Benzene, 1-bromo-2-[(3-methyl-2-butenyl)oxy]-(96597-85-2)

Safety Data

• Hazardous Substances Data: 96597-85-2(Hazardous Substances Data)

Upstream product

• 95-56-7 2-hydroxybromobenzene 
• 870-63-3 prenyl bromide 

Downstream Products

• 14309-15-0 phenyl prenyl ether 
• 3279-17-2 2,3-dihydro-3-isopropylbenzofuran 

Relevant articles and documents

Photoredox transformations with dimeric gold complexes

Let the sunshine in! Unactivated alkyl and aryl bromides underwent a light-enabled reductive radical cyclization in the presence of a dimeric phosphine-gold complex as a photocatalyst (see scheme; X=C(CO 2Et)2, NR, O). Sunlight can be used as the energy source for this simple and efficient radical reaction, which does not require potentially hazardous and toxic chemical reagents, such as organostannanes and chemical initiators.

A dehydrogenative diels-alder reaction of prenyl derivatives with 2,3-dichloro-5,6-dicyanobenzoquinone

An efficient dehydrogenative Diels-Alder (DHDA) reaction of prenyl derivatives with 2,3-dichloro-5,6-dicyanobenzoquinone (DDQ) has been developed under mild conditions, leading to a series of cyclohexene derivatives with good to excellent yields and excellent diastereoselectivity.