96794-10-4Relevant articles and documents
Mixed oxides as highly selective catalysts for the flash pyrolysis of phenacyl benzotriazole: One-pot synthesis of dibenzazepin-7-one
Lener, German,Carbonio, Raul E.,Moyano, E. Laura
, p. 1020 - 1025 (2013/07/25)
The one-pot synthesis of dibenzo[b,d]azepin-7-one (3) was selectively achieved from 1-phenacyl-1,2,3-benzotriazole (1) using the catalytic flash vacuum pyrolysis (cfvp) methodology. Catalysts with the scheelite structure ABO4 (A = Ca2+, Sr2+, Ba2+ and B = Mo6+, W6+) and fergusonite BiVO4 were explored in this new catalytic reaction. These oxides promoted high conversion of starting material at lower temperatures than those observed for noncatalytic reactions. The chemical nature of A and B cations in the scheelite structure showed a strong influence on the formation toward the desired azepinone. In addition, the catalyst's morphology had a significant influence on the course of the cfvp reaction.
One-pot synthesis of 7H-dibenzo[b,d]azepin-7-one by heterogeneous flash vacuum pyrolysis with MCM-41 catalysts
Moyano, Elizabeth L.,Lucero, Paola L.,Eimer, Griselda A.,Herrero, Eduardo R.,Yranzo, Gloria I.
, p. 2179 - 2181 (2008/02/03)
Homogeneous and heterogeneous flash vacuum pyrolysis (fvp) reactions of 2-(1H-1,2,3-benzo1riazol-1-yl)phenylethanone (1) are reported. Heterogeneous reactions were carried out with Al-MCM-41 catalysts, mesoporous molecular sieves of the type M41S. In both cases, 7H-dibenzo[b,d]azepin-7-one (4) was the major product; however, in the catalytic reactions, yields and selectivity were very high. A mechanism for this reaction is also discussed.