96806-48-3

Basic information

• Product Name: chlorophenyl(CO)platinum{1,3-bis(diphenylphosphino)propane}
• CAS NO: 96806-48-3
• Molecular Weight: 748.1
• Mol File: 96806-48-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: chlorophenyl(CO)platinum{1,3-bis(diphenylphosphino)propane}(CAS DataBase Reference)
• NIST Chemistry Reference: chlorophenyl(CO)platinum{1,3-bis(diphenylphosphino)propane}(96806-48-3)
• EPA Substance Registry System: chlorophenyl(CO)platinum{1,3-bis(diphenylphosphino)propane}(96806-48-3)

Safety Data

• Hazardous Substances Data: 96806-48-3(Hazardous Substances Data)

Upstream product

• 76705-02-7 chlorophenyl(CO)platinum(cod) 
• 6737-42-4 1,3-bis-(diphenylphosphino)propane 
• 96806-44-9 chlorophenylplatinum{1,3-bis(diphenylphosphino)propane} 

Downstream Products

• 59329-00-9 [1,3-bis(diphenylphosphino)propane]dichloroplatinum(II) 
• 96806-44-9 [PtCl(C₆H₅)(((C₆H₅)2PCH₂)2CH₂)] 

Relevant articles and documents

Preparation of phenylplatinum-zirconium complexes with Ph2PC5H4 or PhP(C5H4)2 bridging ligands and their reactions with carbon monoxide

Reaction of [PtPh2(cod)] or [PtClPh(cod)] with (Ph2PC5H4)2ZrCl2 yields the Ph2PC5H4-bridged species [PtXPh(Ph2PC5H4)2ZrCl2] (X = Ph, Cl). Treatment of [PtPh2(cod)] or [PtClPh(cod)] with 2 equiv of PhP(C5H4)2ZrCl2, prepared by reaction of [ZrCl4(THF)2] with (TlC5H4)2PPh, yields cis- [PtPh2{PhP-(C6H4)2ZrCl 2}2] or trans-[PtClPh{PhP(C5H4)2ZrCl2} 2]. Each of the mixed-metal complexes has been isolated as an air-sensitive solid and characterized by elemental analysis and NMR spectroscopy. [PtPh2-(Ph2PC5H4) 2ZrCl2] does not react with carbon monoxide, and cis-[PtPh2{PhP(C5H4)2ZrCl 2}2] undergoes a slow displacement of phosphine by CO, whereas the two chlorophenylplatinum complexes undergo smooth carbonylation to the corresponding benzoylplatinum species.