96914-63-5Relevant articles and documents
Direct Cyclopropanation of α-Cyano β-Aryl Alkanes by Light-Mediated Single Electron Transfer Between Donor–Acceptor Pairs
Li, Jing,Lear, Martin J.,Hayashi, Yujiro
, p. 5901 - 5905 (2021/03/09)
Cyclopropanes are traditionally prepared by the formal [2+1] addition of carbene or radical based C1 units to alkenes. In contrast, the one-pot intermolecular cyclopropanation of alkanes by redox active C1 units has remained unrealised. Herein, we achieve
Nitro Compounds as Nucleophilic Alkylidene Transfer Reagents
Ono, Noboru,Yanai, Tetsuya,Hamamoto, Isami,Kamimura, Akio,Kaji, Aritsune
, p. 2806 - 2807 (2007/10/02)
Nitro compounds can be used as useful and general nucleophilic alkylidene transfer reagents for the preparation of various cyclopropanes.