97088-22-7Relevant articles and documents
Preparation of bis-Benzyne Precursor 2,5-bis(Trimethylsilyl)-1,4-Phenylene bis(Trifluoromethanesulfonate)
Carpenter, Casey A.,Wegwerth, Sarah E.,Douglas, Christopher J.
, p. 498 - 502 (2019)
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Side functionalization of diboronic acid precursors for covalent organic frameworks
Faury, Thomas,Dumur, Frederic,Clair, Sylvain,Abel, Mathieu,Porte, Louis,Gigmes, Didier
, p. 2067 - 2075 (2013/04/23)
A series of substituted 1,4-benzenediboronic acids (BDBA) was synthesized and their thermal properties investigated. Two diboronic acids were studied as building-blocks for covalent organic framework (COF) formation, namely 2,5-dimethoxy-1,4-benzenediboronic acid and 2-nitro-1,4-benzeneboronic acid. Interestingly, substitution of the BDBA core caused a dramatic decrease of the polymerization temperature leading to the formation of a less organized structure.