97222-19-0

Basic information

• Product Name: Boc-Ahe-(BzlO)Apr-OMe
• Synonyms: Boc-Ahe-(BzlO)Apr-OMe
• CAS NO: 97222-19-0
• Molecular Weight: 422.522
• Mol File: 97222-19-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Boc-Ahe-(BzlO)Apr-OMe(CAS DataBase Reference)
• NIST Chemistry Reference: Boc-Ahe-(BzlO)Apr-OMe(97222-19-0)
• EPA Substance Registry System: Boc-Ahe-(BzlO)Apr-OMe(97222-19-0)

Safety Data

• Hazardous Substances Data: 97222-19-0(Hazardous Substances Data)

Upstream product

• 6404-29-1 6-(tert-butoxycarbonylamino)hexanoic acid 
• 105393-61-1 3-Benzyloxyamino-propionic acid methyl ester; hydrochloride 
• 30204-31-0 3-(benzyloxyamino)propanoic acid methyl ester 

Downstream Products

• 97222-30-5 3-[Benzyloxy-(6-{3-[benzyloxy-(6-{3-[benzyloxy-(6-tert-butoxycarbonylamino-hexanoyl)-amino]-propionylamino}-hexanoyl)-amino]-propionylamino}-hexanoyl)-amino]-propionic acid 2,5-dioxo-pyrrolidin-1-yl ester 
• 97222-27-0 5,16,27-Tris-benzyloxy-1,5,12,16,23,27-hexaaza-cyclotritriacontane-2,6,13,17,24,28-hexaone 
• 97222-24-7 H-(BzlO)Apr-Ahe-(BzlO)Apr-Ahe-(BzlO)Apr-OMe 
• 97222-21-4 H-(BzlO)Apr-Ahe-(BzlO)Apr-OMe 
• 97222-26-9 Boc-Ahe-(BzlO)Apr-Ahe-(BzlO)Apr-Ahe-(BzlO)Apr-OH 
• 341035-21-0 3-[benzyloxy-(6-tert-butoxycarbonylamino-hexanoyl)-amino]-propionic acid 
• 97222-22-5 Boc-Ahe-(BzlO)Apr-Ahe-(BzlO)Apr-OMe 
• 97222-25-8 Boc-Ahe-(BzlO)Apr-Ahe-(BzlO)Apr-Ahe-(BzlO)Apr-OMe 
• 341035-26-5 3-{benzyloxy-[6-(3,5-bis-{5-[benzyloxy-(2-carboxy-ethyl)-carbamoyl]-pentylcarbamoyl}-benzoylamino)-hexanoyl]-amino}-propionic acid 
• 341035-23-2 3-{benzyloxy-[6-(3,5-bis-{5-[benzyloxy-(2-methoxycarbonyl-ethyl)-carbamoyl]-pentylcarbamoyl}-benzoylamino)-hexanoyl]-amino}-propionic acid methyl ester 

Relevant articles and documents

Iron(III) complexation behavior of benzene-centered tripodal mono-, di- and tritopic ligands carrying a repeating -Ahe-(HO)Apr- sequence [Ahe = 6-aminohexanoyl; (HO)Apr = 3-(N-hydroxy)-aminopropanoyl]

To investigate how three-directional molecules behave upon complexation with ferric iron, tripodal 1,3,5-benzene-centered mono-, di- and tritopic iron-chelating ligands {C6H3[CO-(Ahe-(HO)Apr)n-OH]3: 1, n = 1; 2, n = 2; 3, n = 3}, composed of strands containing an -Ahe-(HO)Apr- sequence [Ahe = 6-aminohexanoyl; (HO)Apr = 3-(N-hydroxy)aminopropanoyl], were synthesized. These hydroxamate ligands form intramolecular six-coordinate octahedral complexes with Fe(III): Fe1-1, Fe1-2, Fe2-2, Fe1-3, Fe2-3 and Fe3-3. The complexes formed were investigated from a topological viewpoint and examined in terms of stability against attack by H+ and HO-, monoprotonation equilibrium and iron removal kinetics using a 20-molar excess of EDTA. Fe1-1, Fe1-2 and Fe2-2 have tripodal interstrand structures. In particular, the iron removal reaction of Fe2-2 shows a consecutive first-order reaction pattern. From kinetic data of the first-order reactions, Fe1-3, Fe2-3 and Fe3-3 are concluded to possess one, two and three discrete ferrioxamine-type (intrastrand) structures, respectively.