97384-48-0

Basic information

• Product Name: CitrowanilB
• Synonyms: 2-Benzyl-2-methyl-3-butenitrile;2-benzyl-2-Methylbut-3-enenitrile
• CAS NO: 97384-48-0
• Molecular Formula: C₁₂H₁₃N
• Molecular Weight: 171.23832
• EINECS: 407-870-4
• Mol File: 97384-48-0.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 286.4±9.0 °C(Predicted)
• Appearance: /
• Density: 0.968±0.06 g/cm3(Predicted)
• Vapor Pressure: 5Pa at 20℃
• Water Solubility: 175mg/L at 20℃
• CAS DataBase Reference: CitrowanilB(CAS DataBase Reference)
• NIST Chemistry Reference: CitrowanilB(97384-48-0)
• EPA Substance Registry System: CitrowanilB(97384-48-0)

Safety Data

• Hazard Codes: Xn
• Statements: 22-52/53
• Safety Statements: 61
• Hazardous Substances Data: 97384-48-0(Hazardous Substances Data)

Usage

General Description

CitrowanilB is a chemical compound used in the manufacturing of various consumer products including detergents, soaps, and personal care items. It is commonly used as a fragrance ingredient due to its pleasant, citrus-like aroma. CitrowanilB is also known for its ability to enhance the scent of other ingredients and provide a long-lasting fragrance. In addition to its aromatic properties, CitrowanilB can also act as a stabilizer and preservative in certain formulations. However,

InChI:InChI=1/C12H13N/c1-3-12(2,10-13)9-11-7-5-4-6-8-11/h3-8H,1,9H2,2H3

Upstream product

• 30574-97-1 tiglonitrile 
• 100-44-7 benzyl chloride 
• 33802-51-6 α-methyl-β-phenylpropionitrile 
• 111-34-2 -butyl vinyl ether 
• 66064-58-2 1-dimethylamino-3,4-dimethyl-1-aza-1,3-butadiene 
• 497-03-0 2-methylbut-2-enal 
• 119045-80-6 2-benzyl-2-methyl-3-butenal N,N-dimethylhydrazone 
• 100-39-0 benzyl bromide 

Downstream Products

• 166661-94-5 2-methyl-2-(phenylmethyl)-3-butenamide 

Relevant articles and documents

Indium Tribromide Catalyzed Coupling Reaction of Enol Ethers with Silyl Ketene Imines toward the Synthesis of β,γ-Unsaturated Nitriles

Herein, a coupling reaction of enol ethers with silyl ketene imines in the presence of catalytic amounts of InBr3 and Me3SiBr is described. Kinetic studies have revealed that an indium catalyst and Me3SiBr accelerated the coupling process and the regeneration of the catalyst, respectively. Various types of enol ethers and silyl ketene imines are applicable. In addition, a formal synthesis of verapamil was achieved by using this novel coupling reaction. Let's get together: The coupling reaction of enol ethers with silyl ketene imines in the presence of a catalytic amount of InBr3 and Me3SiBr is shown (see scheme, TBS=tert-butyl dimethylsilyl). Kinetic studies revealed that an indium salt and Me3SiBr accelerated the coupling process and the regeneration of the catalyst. Several enol ethers and silyl ketene imines are applicable to this strategy.

Alpha-tertiary nitriles

Alpha-tertiary nitriles, a process for making the same, and fragrant substances containing the same, in which the nitriles having the general formula STR1 wherein R1 represents an alkyl radical with 1-3 carbon atoms, R2 and R3/