97431-31-7

Basic information

• Product Name: Hexadecanoic acid, 2-bromo-, 2-(phenylmethoxy)ethyl ester
• CAS NO: 97431-31-7
• Molecular Formula: C25H41BrO3
• Molecular Weight: 469.503
• Mol File: 97431-31-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Hexadecanoic acid, 2-bromo-, 2-(phenylmethoxy)ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Hexadecanoic acid, 2-bromo-, 2-(phenylmethoxy)ethyl ester(97431-31-7)
• EPA Substance Registry System: Hexadecanoic acid, 2-bromo-, 2-(phenylmethoxy)ethyl ester(97431-31-7)

Safety Data

• Hazardous Substances Data: 97431-31-7(Hazardous Substances Data)

Upstream product

• 69319-95-5 α-bromopalmitoyl chloride 
• 622-08-2 2-Benzyloxyethanol 

Downstream Products

• 97431-35-1 2-(2-Benzyloxy-ethoxy)-hexadecanoic acid 
• 97431-32-8 2-(benzyloxy)ethyl 2-<2-(benzyloxy)ethoxy>hexadecanoate 

Relevant articles and documents

Synthesis of +(1.1.1)>X- Cryptates Assisted by Intramolecular Hydrogen Bonding

Condensation of diazacoronand and diethylene glycol bis(methanesulfonate)as well as with its alkylsubstituted derivatives in the presence of 1 molar equiv of BuLi or KH gives the corresponding +(1.1.1)>X- cryptates in 31-43percent yields.Experimental results indicate that in the intermediate monosubstituted diazacoronand, the NH hydrogen plays a templating role, thus favoring the bicyclic ring closure by intramolecular hydrogen bonding.Similar base-promoted condensations of and diazacoronands with triethylene glycol bis(methanesulfonates) afford and cryptates in 20-35percent yields.