97505-89-0

Basic information

• Product Name: Benzenemethanamine, a-methyl-N-(1,7,7-trimethylbicyclo[2.2.1]hept-2-ylidene)-
• CAS NO: 97505-89-0
• Molecular Formula: C18H25N
• Molecular Weight: 255.403
• Mol File: 97505-89-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzenemethanamine, a-methyl-N-(1,7,7-trimethylbicyclo[2.2.1]hept-2-ylidene)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanamine, a-methyl-N-(1,7,7-trimethylbicyclo[2.2.1]hept-2-ylidene)-(97505-89-0)
• EPA Substance Registry System: Benzenemethanamine, a-methyl-N-(1,7,7-trimethylbicyclo[2.2.1]hept-2-ylidene)-(97505-89-0)

Safety Data

• Hazardous Substances Data: 97505-89-0(Hazardous Substances Data)

Upstream product

• 736109-58-3 1,7,7-trimethyl-bicyclo[2.2.1]heptan-2-one 
• 2627-86-3 (S)-1-phenyl-ethylamine 
• 3886-69-9 (R)-1-phenyl-ethyl-amine 

Downstream Products

• 128593-67-9 exo-(1R)-N-(1-phenylethyl)bornanamine 

Relevant articles and documents

ASYMMETRIC DEPROTONATION OF PROCHIRAL KETONES USING CHIRAL LITHIUM AMIDE BASES

A number of chiral secondary amines have been prepared and used as precursors to the corresponding chiral lithium amide bases.Treatment of either cis-2,6-dimethylcyclohexanone or 4-tert-butylcyclohexanone with a chiral lithium amide, followed by electrophilic quench, gives chiral products in up to 88 percent enantiomeric excess.The results with 4-tert-butylcyclohexanone are in disagreement with an earlier literature report, giving products of lower enantiomeric excess but higher optical rotation.