97512-72-6

Basic information

• Product Name: methyl (Z)-2-({(2S)-2-[(tert-butoxycarbonyl)amino]-3-phenylpropanoyl}-amino)-3-phenyl-2-propenoate
• Synonyms: methyl (Z)-2-({(2S)-2-[(tert-butoxycarbonyl)amino]-3-phenylpropanoyl}-amino)-3-phenyl-2-propenoate
• CAS NO: 97512-72-6
• Molecular Weight: 424.497
• Mol File: 97512-72-6.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: methyl (Z)-2-({(2S)-2-[(tert-butoxycarbonyl)amino]-3-phenylpropanoyl}-amino)-3-phenyl-2-propenoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl (Z)-2-({(2S)-2-[(tert-butoxycarbonyl)amino]-3-phenylpropanoyl}-amino)-3-phenyl-2-propenoate(97512-72-6)
• EPA Substance Registry System: methyl (Z)-2-({(2S)-2-[(tert-butoxycarbonyl)amino]-3-phenylpropanoyl}-amino)-3-phenyl-2-propenoate(97512-72-6)

Safety Data

• Hazardous Substances Data: 97512-72-6(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 110697-93-3 Boc-Phe-Phe-azlactone 
• 34290-59-0 (S)-methyl 2-((2S)-2-[(tert-butoxycarbonyl)-3-phenylpropanamido]-3-hydroxy)-propanoate 
• 13734-34-4 N-tert-butoxycarbonyl-L-phenylalanine 
• 591-50-4 iodobenzene 
• 79807-13-9 methyl 2-({(2S)-2-[(tert-butoxycarbonyl)amino]-3-phenylpropanoyl}-amino)-acrylate 
• 74805-42-8 N-carboxy-α-dehydrophenylalanine anhydride 
• 186581-53-3 diazomethane 
• 97510-44-6 (Z)-Boc-Phe-ΔPhe 

Downstream Products

• 1242683-57-3 Boc-L-Phe-Z-ΔPhe(β-I)-OMe 
• 1242683-71-1 Boc-L-Phe-E-ΔPhe(β-Br)-OMe 
• 1242683-42-6 Boc-L-Phe-Z-ΔPhe(β-Br)-OMe 

Relevant articles and documents

Pd(0)-catalyzed Heck-type arylation of didehydropeptides

Pd(0)-catalyzed Heck-type arylation of several didehydropeptides has been studied and the process has been found to be a viable method for the synthesis of the corresponding arylated products stereoselectively but in moderate yields. Copyright Taylor & Fr

SYNTHESIS OF PEPTIDES WITH α,β-DEHYDROAMINO ACIDS. PART VIII. A CONVENIENT SYNTHESIS OF N-PROTECTED α,β-DEHYDROPEPTIDE METHYL ESTERS

Based on results of the examination of the action of diazomethane on Z-Gly-ΔAbu and/or Z-Gly-ΔAbu-OMe (Table 1) a series of twelve model N-protected α,β-dehydrodipeptide methyl esters 1-12 was obtained.Yields and purity of isolated products amounted to 80-94percent and 98-100percent, respectively (Table 2).