97747-36-9

Basic information

• Product Name: (4R,2'R,3'S,4'S)-3-(5'-Benzyloxy-3'-hydroxy-2',4'-dimethylpentanoyl)-4-isopropyl-2-oxazolidinone
• Synonyms: (4R,2'R,3'S,4'S)-3-(5'-Benzyloxy-3'-hydroxy-2',4'-dimethylpentanoyl)-4-isopropyl-2-oxazolidinone
• CAS NO: 97747-36-9
• Molecular Weight: 363.454
• Mol File: 97747-36-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (4R,2'R,3'S,4'S)-3-(5'-Benzyloxy-3'-hydroxy-2',4'-dimethylpentanoyl)-4-isopropyl-2-oxazolidinone(CAS DataBase Reference)
• NIST Chemistry Reference: (4R,2'R,3'S,4'S)-3-(5'-Benzyloxy-3'-hydroxy-2',4'-dimethylpentanoyl)-4-isopropyl-2-oxazolidinone(97747-36-9)
• EPA Substance Registry System: (4R,2'R,3'S,4'S)-3-(5'-Benzyloxy-3'-hydroxy-2',4'-dimethylpentanoyl)-4-isopropyl-2-oxazolidinone(97747-36-9)

Safety Data

• Hazardous Substances Data: 97747-36-9(Hazardous Substances Data)

Upstream product

• 74130-31-7 3-(benzyloxy)-2-methylpropanal 
• 77877-19-1 N-isopropyl oxazolidinone 
• 5658-46-8 ((2-methylallyloxy)methyl)benzene 
• 63930-46-1 3-(benzyloxy)-2-methylpropan-1-ol 
• 100-39-0 benzyl bromide 
• 79027-28-4 (2S)-3-(benzyloxy)-2-methylpropanal 
• 77877-19-1 (4R)-3-propanoyl-4-isopropyloxazolidin-2-one 
• 63930-49-4 (R)-3-(benzyloxy)-2-methylpropan-1-ol 

Downstream Products

• 87758-66-5 (2S,3R,4R)-5-Benzyloxy-3-hydroxy-2,4-dimethyl-pentanoic acid methyl ester 
• 87702-55-4 (±)-methyl (2S,3S,4S)-5-(benzyloxy)-3-hydroxy-2,4-dimethylpentanoate 
• 100649-10-3 (4R,2R,3'S,4'S)-3-<5'-Benzyloxy-3'-(tert-butyldimethylsilyloxy)-2',4'-dimethylpentanoyl>-4-isopropyl-2-oxazolidinone 
• 100837-02-3 (±)-methyl (2R,3S,4S)-5-(benzyloxy)-3-hydroxy-2,4-dimethylpentanoate 
• 108393-28-8 (2S,3R,4S)-5-benzyloxy-2,3-dimethylpentane-1,4-diol 
• 100649-11-4 (2S,3R,4S)-5-Benzyloxy-3-(tert-butyldimethylsilyloxy)-2,4-dimethyl-1-pentanol 
• 100649-12-5 (2S,3S,4S)-5-Benzyloxy-3-(tert-butyldimethylsilyloxy)-1-(methoxymethoxy)-2,4-dimethylpentane 
• 81470-77-1 (2S,3S,4S)-5-Benzyloxy-1,3-isopropylidenedioxy-2,4-dimethylpentane 

Relevant articles and documents

Total Synthesis of (+)-11,11'-Di-O-methylelaiophylidene: An Aglycone of Elaiophylin

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STUDIES IN MACROLIDE SYNTHESIS: AN EFFICIENT SYNTHESIS OF TWO CHIRAL FRAGMENTS OF ERYTHRONOLIDE A

An efficient asymmetric synthesis of the C1-C5 fragment (3) together with the epimeric C7-C11 fragment (4) used in the Stork approach to the synthesis of erythronolide A is described.