97799-95-6Relevant articles and documents
BECKMANN REARRANGEMENT OF ACETYLTHIOPHENE OXIME BENZENESULFONATES AS A METHOD FOR THE SYNTHESIS OF ACETAMIDOTHIOPHENES
Fabrichnyi, B. P.,Bulgakova, V. N.,Gol'dfarb, Ya. L.
, p. 401 - 403 (2007/10/02)
The Beckmann rearrangement of 2-acetylthiophene, 5-methyl-2-acetylthiophene, 5-chloro-2-acetylthiophene, and 2,5-dichloro-3-acetylthiphene oxime benzenesulfonates to the corresponding acetamidothiophenes was carried out by heating with an aqueous methanol solution of sodium acetate.This method can be used for the preparative synthesis of 2-acetamidothiophene and 2,5-dichloro-3-acetamidothiophene.