97877-74-2

Basic information

• Product Name: bis(acetonitrile)(5,10,15,20-tetramesitylporphyrinato)ruthenium(II)
• CAS NO: 97877-74-2
• Molecular Weight: 964.231
• Mol File: 97877-74-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: bis(acetonitrile)(5,10,15,20-tetramesitylporphyrinato)ruthenium(II)(CAS DataBase Reference)
• NIST Chemistry Reference: bis(acetonitrile)(5,10,15,20-tetramesitylporphyrinato)ruthenium(II)(97877-74-2)
• EPA Substance Registry System: bis(acetonitrile)(5,10,15,20-tetramesitylporphyrinato)ruthenium(II)(97877-74-2)

Safety Data

• Hazardous Substances Data: 97877-74-2(Hazardous Substances Data)

Upstream product

• 92669-43-7 (carbonyl)(5,10,15,20-tetramesitylporphyrinato)ruthenium(II) 
• 75-05-8 acetonitrile 
• 79235-76-0 (5,10,15,20-tetramesitylporphyrinato)ruthenium(II) 
• 92669-44-8 dioxo(tetramesitylporphyrinato)ruthenium(VI) 
• 7440-66-6 zinc 

Downstream Products

• 92669-44-8 dioxo(tetramesitylporphyrinato)ruthenium(VI) 
• 79235-76-0 (5,10,15,20-tetramesitylporphyrinato)ruthenium(II) 
• 115227-06-0 Ru(TMP)(DMF)(N₂) 
• 106210-08-6 Ru(TMP)(Et₂O)2 
• 106210-11-1 Ru(TMP)(Et₂O)(N₂) 
• 115227-07-1 Ru(TMP)(Et₃N)(N₂) 
• 106210-09-7 Ru(TMP)(N₂)2 
• 1357363-71-3 Ru(meso-tetrakis(2,4,6-trimethylphenyl)porphyrin)(EtSH)2 
• 1357363-85-9 Ru(meso-tetrakis(2,4,6-trimethylphenyl)porphyrin)(MeSMe)2 
• 1357363-91-7 Ru(meso-tetrakis(2,4,6-trimethylphenyl)porphyrin)(EtSSEt)2 
• 1357363-93-9 Ru(meso-tetrakis(2,4,6-trimethylphenyl)porphyrin)(nPrSSnPr)2 
• 1357363-77-9 Ru(meso-tetrakis(2,4,6-trimethylphenyl)porphyrin)(i-PrSH)2 
• 1357363-97-3 Ru(meso-tetrakis(2,4,6-trimethylphenyl)porphyrin)(MeSSSMe)2 
• 1357363-79-1 Ru(meso-tetrakis(2,4,6-trimethylphenyl)porphyrin)(t-BuSH)2 

Relevant articles and documents

Cis-Trans Isomerization of Epoxides Catalyzed by Ruthenium(II) Porphyrins

Bis(tetrahydrofuran)(5,10,15,20-tetramesyitylporphyrinato)ruthenium(II) IITMP(THF)2> and the corresponding p-tolylporphyrin IITTP(THF)2> have been found to catalyze the cis-trans isomerization of epoxides under mild conditions.For β-methylstyrene oxide an equilibrium ratio of 5.4:1 (trans/cis) was achieved with either isomer indicating a free energy difference of 1 kcal/mol.Inhibition of the isomerization by added olefins was observed and attributed to olefin coordination to ruthenium(II). cis-β-Methylstyrene oxide readily formed an adduct with RuIITMP(CO), while the trans isomer did not.The isomerization of trans-(1S,2S)-β-methylstyrene oxide gave only cis-(1R,2S)β-methylstyrene oxide.A mechanism for epoxide isomerization involving homolytic cleavage of the C1-O bond to give carbon radical intermediate is proposed.

Synthesis and Reactivity of a Monomeric 14-Electron 'Bare' Ruthenium(II) Porphyrin Complex; Reversible Binding of Dinitrogen to form Mono- and Bis-dinitrogen Complexes

The 14-electron species Ru(TMP), obtained via vacuum pyrolysis of Ru(TMP)(MeCN)2, reacts with a plethora of ligands to form bis-ligated species, including the first bis(dinitrogen) metalloporphyrin complex .