98055-12-0

Basic information

• Product Name: 1H-Indole, 5-methoxy-2-methyl-3-(phenylthio)-
• CAS NO: 98055-12-0
• Molecular Formula: C16H15NOS
• Molecular Weight: 269.367
• Mol File: 98055-12-0.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: 1H-Indole, 5-methoxy-2-methyl-3-(phenylthio)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1H-Indole, 5-methoxy-2-methyl-3-(phenylthio)-(98055-12-0)
• EPA Substance Registry System: 1H-Indole, 5-methoxy-2-methyl-3-(phenylthio)-(98055-12-0)

Safety Data

• Hazardous Substances Data: 98055-12-0(Hazardous Substances Data)

Upstream product

• 5042-53-5 1-(phenylsulfanyl)acetone 
• 19501-58-7 4-methoxyphenylhydrazine hydrochloride 
• 1076-74-0 5-methoxy-2-methyl-1H-indole 
• 194720-38-2 2,3,5,6-tetramethyl-4-oxo-1-phenylthiocyclohexa-2,5-dienyl 2-chloroacetate 
• 98-09-9 benzenesulfonyl chloride 
• 882-33-7 diphenyldisulfane 
• 98-80-6 phenylboronic acid 
• 169216-70-0 4-Benzenesulfinyl-2,3,5,6-tetramethyl-phenol 
• 14204-27-4 N-phenylthiophthalimide 
• 98055-11-9 N-(4-Methoxy-phenyl)-N'-[1-methyl-2-phenylsulfanyl-eth-(E)-ylidene]-hydrazine 

Downstream Products

• 1076-74-0 5-methoxy-2-methyl-1H-indole 

Relevant articles and documents

Synergistic Effect of Squaric Acid in Bromine-Catalyzed Deoxygenation of Sulfonyl Derivatives: Mechanistic Investigations and Synthetic Applications in Electrophilic (Fluoroalkyl)sulfenylation

A method for electrophilic (fluoroalkyl)sulfenylation of nucleophiles by collaborative CTAB- and squaric acid-promoted deoxygenation of sulfonyl derivatives is reported. Mechanistic studies indicate that squaric acid dramatically decreased the energy barr

Palladium-Catalyzed Oxidative Sulfenylation of Indoles and Related Electron-Rich Heteroarenes with Aryl Boronic Acids and Elemental Sulfur

An efficient and convenient palladium-catalyzed C-H bond oxidative sulfenylation of indoles and related electron-rich heteroarenes with aryl boronic acids and elemental sulfur has been described. This procedure provides a useful and direct approach for the assembly of a wide range of structurally diverse 3-sulfenylheteroarenes with moderate to excellent yields from simple and readily available starting materials. Moreover, this synthetic protocol is suitable for N-protected and unprotected indoles. Notably, the construction of two C-S bonds in one step was also achieved in this transformation.

Facile and efficient sulfenylation method using quinone mono-O,S-acetals under mild conditions

A novel sulfenylation method induced by aromatization of quinone mono-O,S-acetals is described. These sulfenylation reagents readily react with silyl enolethers or electron rich aromatic compounds to give sulfenylation products under mild conditions. In particular, O,S-acetal 2j, which possesses a pentafluorophenylthio function, is the most effective reagent from the standpoint of the adaptability for various substrates.