98514-83-1

Basic information

• Product Name: N-(pyridin-2-ylmethyl)benzenesulfonamide
• Synonyms: N-(pyridin-2-ylmethyl)benzenesulfonamide
• CAS NO: 98514-83-1
• Molecular Formula: C₁₂H₁₂N₂O₂S
• Molecular Weight: 248.30088
• Mol File: 98514-83-1.mol
• Article Data: 6

Chemical Properties

• Appearance: /
• CAS DataBase Reference: N-(pyridin-2-ylmethyl)benzenesulfonamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-(pyridin-2-ylmethyl)benzenesulfonamide(98514-83-1)
• EPA Substance Registry System: N-(pyridin-2-ylmethyl)benzenesulfonamide(98514-83-1)

Safety Data

• Hazardous Substances Data: 98514-83-1(Hazardous Substances Data)

Upstream product

• 3731-51-9 2-(Aminomethyl)pyridine 
• 873-55-2 sodium benzenesulfonate 
• 98-09-9 benzenesulfonyl chloride 

Downstream Products

• 353298-91-6 [copper(II)(N-(2-methylpyridyl)benzenesulfonylamidate)2] 
• 13707-43-2 N,N-dimethyl-N′-(phenylsulfonyl)formimidamide 
• 1315594-60-5 [(p-cymene)RuCl(NC₅H₄CH₂NHSO₂Ph)]Cl 
• 1054582-79-4 [(NC₅H₄CH₂NSO₂C₆H₅)AuCl₂] 
• 77417-85-7 Ni(C₅H₄NCH₂NSO₂C₆H₅)2 
• 77417-88-0 Zn(C₅H₄NCH₂NSO₂C₆H₅)2 

Relevant articles and documents

Preparation method of sulfonyl amidine with 2-Picolylamine and DMF-DMA as amine sources

The invention discloses a preparation method of sulfonyl amidine with 2-Picolylamine and DMF-DMA as amine sources. The method comprises the following steps: reacting sulfonyl chloride with 2-Picolylamine to obtain an intermediate product; and then reacting the intermediate product with DMF-DMA in the presence of a catalyst at a temperature of 60-100 DEG C, then performing cooling to room temperature, extracting the reaction solution with ethyl acetate, performing layering, drying and then concentrating to obtain a target product sulfonyl amidine. According to the method disclosed by the invention, the reaction of secondary sulfonamide and DMF-DMA is realized, and the synthesis path of sulfonyl amidine is expanded. The synthetic reaction is simple in operation, mild in condition and convenient in post-treatment, and the obtained intermediate product and the product are high in purity and yield.

Palladium(II) complexes bearing bidentate pyridyl-sulfonamide ligands: Synthesis and catalytic applications

New palladium(II) complexes ([Pd(1-5)2], 6-10, (1-5 = bidentate pyridyl-sulfonamide ligands)) were obtained from the reaction between Pd(OAc)2 and bidentate pyridyl-sulfonamide ligands. The synthesized compounds were characterized by

Synthesis of ruthenium(II) complexes containing tridentate triamine (′NNN′) and bidentate diamine ligands (NN′): As catalysts for transfer hydrogenation of ketones

A series of neutral and cationic Ru(II) complexes (1-10), bearing pyridine-based tridentate (′NNN′), pyridine-based bidentate (NN′), and mixed ′NNN′ + NN′ ligands, were synthesized by starting from [RuCl 2(DMSO)4] and [RuCl2(p-cymene)]2 precursors. Solid-state structures of mixed-ligand complexes 9 and 10 were determined by single-crystal X-ray diffraction. Both complexes are unusual in that NN′ ligands were spontaneously oxidized in air under base-free conditions to give imine-amine bidentate ligands upon replacement of p-cymene by meridional ′NNN′. The complexes 1-10 were screened for transfer hydrogenation (TH) of aryl ketones with 2-propanol. The highest catalytic activity was obtained with the complexes containing tridentate ′NNN′ and 7, which contain nonsulfonated 2-(aminomethyl)pyridine. However, for complexes 6a-c, containing p-cymene (a facial tridentate ligand), a slower reaction rate was observed.