98760-22-6

Basic information

• Product Name: C₈H₉Br₂N
• CAS NO: 98760-22-6
• Molecular Weight: 278.974
• Mol File: 98760-22-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₈H₉Br₂N(CAS DataBase Reference)
• NIST Chemistry Reference: C₈H₉Br₂N(98760-22-6)
• EPA Substance Registry System: C₈H₉Br₂N(98760-22-6)

Safety Data

• Hazardous Substances Data: 98760-22-6(Hazardous Substances Data)

Upstream product

• 67344-77-8 1-(3-bromophenyl)-N-methylmethanamine 

Downstream Products

• 35003-56-6 m-Bromo-N-methylbenzylidenamin 
• 67344-77-8 1-(3-bromophenyl)-N-methylmethanamine 

Relevant articles and documents

Reactions of N-Halogenobenzylmethylamines with Triethylamine in Acetonitrile. Effect of Leaving Group upon the Imine-forming Transition State

Reactions of N-halogenobenzylmethylamines (1) and (2) with Et3N-MeCN have been investigated kinetically.Eliminations from (1) and (2) were quantitative and regiospecific, producing only benzylidenemethylamines.For the elimination reaction of (1) with Et3N, kH/kD 5.7, ρ 0.88, 9.1 kcal mol-1, and -42.4 cal mol-1 K-1 were determined.The transition-state structure is assessed as being highly symmetric with similar extents of Cβ-H and Nα-Cl bond cleavage, little carbanionic character, and significant ?-bond formation.The structure of the transition state changes only slightly with the change in the leaving group from Cl to Br.