99325-91-4

Basic information

• Product Name: 4-(p-cyanobenzoyl)-cis-2,6-dimethylmorpholine
• CAS NO: 99325-91-4
• Molecular Weight: 244.293
• Mol File: 99325-91-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 4-(p-cyanobenzoyl)-cis-2,6-dimethylmorpholine(CAS DataBase Reference)
• NIST Chemistry Reference: 4-(p-cyanobenzoyl)-cis-2,6-dimethylmorpholine(99325-91-4)
• EPA Substance Registry System: 4-(p-cyanobenzoyl)-cis-2,6-dimethylmorpholine(99325-91-4)

Safety Data

• Hazardous Substances Data: 99325-91-4(Hazardous Substances Data)

Upstream product

• 141-91-3 2,6-dimethyl morpholine 
• 6068-72-0 4-cyanobenzoyl chlorIde 

Relevant articles and documents

Conformation and Stereodynamics of N,N-Dialkylbenzamides; a 1H and 13C Nuclear Magnetic Resonance Investigation of para-Substituted 4-Benzoyl-cis-2,6-dimethylmorpholines

A high-field 13C n.m.r. study of the title compounds below -80 deg C has enabled measurement of the barriers to rotation around the aryl-C(O) bond.These barriers (ΔG(excit.) 7.7-9.5 kcal mol-1), and those for rotation around the C(O)-N bond (ΔG(excit.) 13.6-15.6 kcal mol-1) determined by 1H n.m.r. at higher temperatures, correlate well with Hammett ?+ substituent parameters.The ground-state conformation has the phenyl ring twisted out of the amide plane.Some 1H and 13C chemical shift correlations are also reported.