99342-81-1Relevant articles and documents
Di-?-methane Rearrangement of Highly Sterically Congested Molecules: Inhibition of Free-Rotor Energy Dissipation. Mechanistic and Exploratory Organic Photochemistry
Zimmerman, Howard E.,Schissel, David N.
, p. 196 - 207 (2007/10/02)
Four highly sterically congested di-?-methane reactants were synthesized and their photochemistry was studied.These were 1,1,5,5-tetraphenyl-3,3-diisopropyl-1,4-pentadiene (1), 1,1,5,5-tetraphenyl-3-isopropyl-3-methyl-1,4-pentadiene(2), 1,1-dimesityl-5,5-