99369-23-0

Basic information

• Product Name: 1-(1,2-diphenyl)-1H-imidazole
• Synonyms: 1-(1,2-diphenyl)-1H-imidazole
• CAS NO: 99369-23-0
• Molecular Weight: 248.327
• Mol File: 99369-23-0.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1-(1,2-diphenyl)-1H-imidazole(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(1,2-diphenyl)-1H-imidazole(99369-23-0)
• EPA Substance Registry System: 1-(1,2-diphenyl)-1H-imidazole(99369-23-0)

Safety Data

• Hazardous Substances Data: 99369-23-0(Hazardous Substances Data)

Upstream product

• 4238-71-5 1-benzylimidazole 
• 100-39-0 benzyl bromide 
• 100-44-7 benzyl chloride 
• 620-05-3 iodomethylbenzene 
• 288-32-4 1H-imidazole 
• 19816-85-4 N'-(1,2-diphenylethylidene)-4-methylbenzenesulfonohydrazide 
• 451-40-1 phenyl benzyl ketone 

Downstream Products

• 99369-24-1 1-(1,2-Diphenyl-ethyl)-1H-imidazole; compound with naphthalene-1,5-disulfonic acid 

Relevant articles and documents

Copper acetoacetonate [Cu(acac)2]/BINAP-promoted Csp 3-N bond formation via reductive coupling of N-tosylhydrazones with anilines

We report the the copper(II) acetoacetonate [Cu(acac)2]/BINAP- catalyzed synthesis of arylamines from N-tosylhydrazones and anilines. A fine tuning of the reaction conditions was required to accomplish the cross-coupling successfully, including the ligands effect and the addition of small amounts of water. The characteristic feature of this protocol is its functional group compatibility and its chemoselectivity when various aminophenol derivatives were used. Taking into consideration the interest for this copper-reductive coupling in which no stoichiometric metal hydride reagent is employed, this can be considered as an alternative to the conventional reductive amination.

α-Lithiation of N-Arylmethylimidazoles and Triazoles: A General Method for the Synthesis of 1,2-Diaryl-1-(N-azolyl)-ethanes

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