99430-44-1

Basic information

• Product Name: 5-nitro-5-hydroxymethyl-2-phenyl-1,3-dioxane
• CAS NO: 99430-44-1
• Molecular Weight: 239.228
• Mol File: 99430-44-1.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 5-nitro-5-hydroxymethyl-2-phenyl-1,3-dioxane(CAS DataBase Reference)
• NIST Chemistry Reference: 5-nitro-5-hydroxymethyl-2-phenyl-1,3-dioxane(99430-44-1)
• EPA Substance Registry System: 5-nitro-5-hydroxymethyl-2-phenyl-1,3-dioxane(99430-44-1)

Safety Data

• Hazardous Substances Data: 99430-44-1(Hazardous Substances Data)

Upstream product

• 100-52-7 benzaldehyde 
• 126-11-4 2-hydroxymethyl-2-nitro-propane-1,3-diol 

Relevant articles and documents

Synthesis and structure of 2-aryl-5,5-disubstituted-1,3-dioxanes and conversion into chiral (1,1,1-trishydroxymethyl) methane derivatives

Pentaerythritol, (1,1,1-trishydroxymethyl)methyl methane and (1,1,1-trishydroxymethyl)nitromethane are converted into 2-aryl-5,5-bis(hydroxymethyl), 2-aryl-5-hydroxymethyl-5-methyl- or 2-aryl-5-hydroxymethyl-5-nitro-1,3-dioxanes and a range of derivatives. X-Ray and NMR analysis establishes that the latter is obtained as a single diastereomer whose structure is unambiguously determined. These materials can be elaborated to chiral derivatives of the starting (1,1,1-trishydroxymethyl) methanes.

CONFORMATION OF 5,5-DISUBSTITUTED 2,2-DIMETHYL-1,3-DIOXANES

It was established by PMR spectral data that in solutions of derivatives of 5-acetoxymethyl-, 5-methyl-, and 5-hydroxymethyl-2,2-dimethyl-1,3-dioxanes with nitrogen-containing substituents (2,4-disubstituted 1,3,5-triazin-6-ylamino, benzamido, and nitro g