99564-80-4

Basic information

• Product Name: (Z)-1-phenyl-1,3-bis(trimethylsilyloxy)-1,3-butadiene
• Synonyms: (Z)-1-phenyl-1,3-bis(trimethylsilyloxy)-1,3-butadiene
• CAS NO: 99564-80-4
• Molecular Weight: 306.552
• Mol File: 99564-80-4.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: (Z)-1-phenyl-1,3-bis(trimethylsilyloxy)-1,3-butadiene(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-1-phenyl-1,3-bis(trimethylsilyloxy)-1,3-butadiene(99564-80-4)
• EPA Substance Registry System: (Z)-1-phenyl-1,3-bis(trimethylsilyloxy)-1,3-butadiene(99564-80-4)

Safety Data

• Hazardous Substances Data: 99564-80-4(Hazardous Substances Data)

Upstream product

• 1206-46-8 trimethyl(pentafluorophenyl)silane 
• 93-91-4 1-phenylbutan-1,3-dione 
• 27607-77-8 trimethylsilyl trifluoromethanesulfonate 
• 75-77-4 chloro-trimethyl-silane 
• 74590-81-1 1-(trimethylsiloxy)-1-phenyl-1-buten-3-one 

Downstream Products

• 113949-31-8 2-vinyl-4-benzoyl-5-methyl-2,3-dihydrofuran 
• 144175-15-5 2-(E)-(phenylcarbonylmethylidene)-4-methyltetrahydrofuran 
• 102555-48-6 (3-benzoyl-4-hydroxyphenyl)(2-hydroxyphenyl)methanone 
• 1093748-18-5 (2-hydroxy-4-methoxy-6-propylphenyl)(phenyl)methanone 
• 113949-33-0 ((3aS,7aS)-2-Methyl-3a,4,5,7a-tetrahydro-benzofuran-3-yl)-phenyl-methanone 
• 1434132-23-6 [2-hydroxy-4-tridecyl-6-(trifluoromethyl)phenyl](phenyl)methanone 
• 1402928-99-7 (R)-2-(naphthalen-2-yl)-6-phenyl-2H-pyran-4(3H)-one 
• 1369867-37-7 C₁₆H₁₁F₃O₃ 
• 1315276-81-3 2-hydroxy-6-methylthio-4-(trifluoromethyl)benzophenone 
• 1214744-76-9 4-(1-N-methoxycarboyl-2-dihydroquinolyl)-1,3-dioxo-1-phenylbutane 
• 1197988-82-1 2-dichloromethyl-6-(2-oxo-2-phenylethyl)pyran-4-one 
• 1189819-97-3 (2-ethyl-6-hydroxyphenyl)phenylmethanone 
• 78473-50-4 4-Aethyl-2-hydroxy-benzophenon 
• 1069130-60-4 C₁₄H₁₀Cl₂O₂ 

Relevant articles and documents

Utilisation de Me3SiI prepare in situ pour l'obtention de bis(trimethylsiloxy-1,3) diene-1,3

The in situ generation of iodotrimethylsilane, in the presence of triethylamine, is a convenient route to 1,3-bis(trimethylsiloxy)-1,3-diene.

Bis-Silyloxydienes from Diketones

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Reactions of Trialkylsilyl Trifluoromethanesulfonates, III. - Synthesis of 1,3-Bis(trimethylsiloxy)-1,3-dienes and 3-Trimethylsiloxy-2-butenoates Silylated in Position 4

Bis(trimethylsiloxy)-1,3-dienes 5a - n are obtained by reaction of 1,3-dicarbonyl compounds 1 with trimethylsilyl trifluoromethanesulfonate (2) in the presence of triethylamine (3).The silyl enol ether 8 is silylated by 2/3 to yield 1,3-bis(trimethylsiloxy)-1,3-butadiene (5o).Depending on the conditions, alkyl 3-oxobutanoates 12 react with 2/3 to give the γ-silylated alkyl 3-trimethylsiloxy-2-butenoates 15 or 16.