99657-93-9

Basic information

• Product Name: N'-tert-Butyl-phosphorohydrazidic acid diphenyl ester
• CAS NO: 99657-93-9
• Molecular Weight: 320.328
• Mol File: 99657-93-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N'-tert-Butyl-phosphorohydrazidic acid diphenyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: N'-tert-Butyl-phosphorohydrazidic acid diphenyl ester(99657-93-9)
• EPA Substance Registry System: N'-tert-Butyl-phosphorohydrazidic acid diphenyl ester(99657-93-9)

Safety Data

• Hazardous Substances Data: 99657-93-9(Hazardous Substances Data)

Upstream product

• 7400-27-3 tertbutylhydrazine hydrochloride 
• 2524-64-3 chlorophosphoric acid diphenyl ester 

Relevant articles and documents

Phosphinylhydrazyls R2NNP(O)L2, an ESR Study. Influence of the Captodative Effect on the Three-Electron NN ? Bond

1,1-Dimethyl-2-phosphinylhydrazyls and 1-tert-butyl-2-phosphinylhydrazyls have been generated from the corresponding hydrazines.Their radical structures have been assigned on the basis of their ESR spectral parameters.In contrast with the behavior of trialkylhydrazyls or 1,2-dialkylhydrazyls it has been shown that in the phosphinylhydrazyls the larger nitrogen splitting is due to the tervalent nitrogen.Phosphinylhydrazyls have been shown to exist in equilibrium with their dimer form.The radical Me2NNP(O)(OEt)2 is particularly persistent, and the free activation energy for the rotation about the NN bond has been measured (ΔG=9.8 +/- 0.5 mol)