99733-97-8

Basic information

• Product Name: 3-methyl-5-(2',6',6'-trimethylcyclohex-1'-enyl)-1-penten-3-ol
• Synonyms: 3-methyl-5-(2',6',6'-trimethylcyclohex-1'-enyl)-1-penten-3-ol
• CAS NO: 99733-97-8
• Molecular Weight: 222.371
• Mol File: 99733-97-8.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 3-methyl-5-(2',6',6'-trimethylcyclohex-1'-enyl)-1-penten-3-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 3-methyl-5-(2',6',6'-trimethylcyclohex-1'-enyl)-1-penten-3-ol(99733-97-8)
• EPA Substance Registry System: 3-methyl-5-(2',6',6'-trimethylcyclohex-1'-enyl)-1-penten-3-ol(99733-97-8)

Safety Data

• Hazardous Substances Data: 99733-97-8(Hazardous Substances Data)

Upstream product

• 593-60-2 Vinyl bromide 
• 17283-81-7 4-(2,6,6-Trimethyl-cyclohex-1-enyl)-butan-2-on 
• 57291-29-9 3-methyl-5-(2′,6′,6′-trimethylcyclohex-1′-enyl)-1-penten-3-ol 
• 1826-67-1 vinyl magnesium bromide 

Downstream Products

• 1040738-26-8 C₂₀H₂₈FNO 
• 468-84-8 (+/-)-(4aR,6aS,10aS,10bS)-4a,7,7,10a-tetramethyldodecahydrobenzo[f]chromen-3-one 
• 3738-00-9 (3aRS,5aSR,9aSR,9bSR)-dodecahydro-3a,6,6,9a-tetramethylnaphtho[2,1-b]furan 
• 3738-00-9 (±)-ambrox 
• 110202-07-8 (E)-4-Methyl-6-(2',6',6'-trimethyl-1'-cyclohexenyl)hex-3-en-1-ol 
• 110202-08-9 (Z)-4-Methyl-6-(2',6',6'-trimethyl-1'-cyclohexenyl)hex-3-en-1-ol 
• 3738-00-9 (3aRS,5aRS,9aRS,9bSR)-dodecahydro-3a,6,6,9a-tetramethylnaphtho[2,1-b]furan 
• 173323-70-1 (Z)-β-monocyclohomofarnesylic acid dimethyl amide 
• 173323-69-8 (E)-β-monocyclohomofarnesylic acid dimethyl amide 
• 108893-76-1 cis-β-Monocyclofarnesylacetic acid 
• 108893-75-0 trans-β-Monocyclofarnesylacetic acid 

Relevant articles and documents

Breaking the dichotomy of reactivity vs. chemoselectivity in catalytic SN1 reactions of alcohols

The inability to decouple Lewis acid catalysis from undesirable Bronsted acid catalysed side reactions when water or other protic functional groups are necessarily present has forced chemists to choose between powerful but harsh catalysts or poor but mild

Allylic alcohols as radical allylating agents. An overall olefination of aldehydes and ketones

2-Fluoropyridyl derivatives of allylic alcohols react with xanthates in the presence of lauroyl peroxide to give alkenes, often with high stereoselectivity. If the allylic alcohols are themselves derived from aldehydes or ketones, the overall process becomes a synthetic equivalent of the classical Wittig and related olefination reactions. Copyright

New Syntheses of (+/-)-Ambrox, (+/-)-Ambra Oxide and Their Stereoisomers

New and efficient syntheses of (+/-)-ambrox (1a), (+/-)-ambra oxide (2a) and their stereoisomers (1b, 2b ca. c), amber-like odorous compounds, are described.Starting from dihydro β- and α-ionone (5,12), these substances were obtained in only a few steps via stereoselective acid-catalized cyclization of monocyclodienoic acid (7a ca. b, 11a ca. b, 15a).