99747-47-4

Basic information

• Product Name: Pyridine, 3-methyl-2-(1-methyl-1-propenyl)-, (E)- (9CI)
• Synonyms: Pyridine, 3-methyl-2-(1-methyl-1-propenyl)-, (E)- (9CI)
• CAS NO: 99747-47-4
• Molecular Formula: C10H13N
• Molecular Weight: 147.21692
• Product Categories: PYRIDINE
• Mol File: 99747-47-4.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Pyridine, 3-methyl-2-(1-methyl-1-propenyl)-, (E)- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Pyridine, 3-methyl-2-(1-methyl-1-propenyl)-, (E)- (9CI)(99747-47-4)
• EPA Substance Registry System: Pyridine, 3-methyl-2-(1-methyl-1-propenyl)-, (E)- (9CI)(99747-47-4)

Safety Data

• Hazardous Substances Data: 99747-47-4(Hazardous Substances Data)

Upstream product

• 22032-77-5 (E)-crotylmagnesium chloride 
• 87673-60-7 2-(1-methyl-2-propen-1-yl)-3-methylpyridine 
• 3430-17-9 2-bromo-3-picoline 

Relevant articles and documents

Regioselective Addition of Butenyl Grignard Reagent to the Unactivated Double Bond of 2-(α-Methylallyl) Aza Aromatic Compounds

The addition of the butenyl Grignard reagent to the unactivated double bond of 2-(α-methylallylic) aza aromatic compounds is completely regioselective giving the 2-(1,4-dimethyl-5 hexen-1-yl) aza aromatics in good yield.A preliminary coordination of magnesium atom to nitrogen atom and the formation of a six-center transition state involving the butenyl Grignard and the vinyl group has been proposed in order to explain the selectivity of the reaction.