99865-14-2

Basic information

• Product Name: Benzenepropanal, 2-acetyl-
• Synonyms: Benzenepropanal, 2-acetyl-;3-(2-acetylphenyl)propanal
• CAS NO: 99865-14-2
• Molecular Formula: C₁₁H₁₂O₂
• Molecular Weight: 176.21178
• Mol File: 99865-14-2.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 291.953°C at 760 mmHg
• Flash Point: 108.852°C
• Appearance: /
• Density: 1.051g/cm³
• Vapor Pressure: 0.002mmHg at 25°C
• Refractive Index: 1.516
• CAS DataBase Reference: Benzenepropanal, 2-acetyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenepropanal, 2-acetyl-(99865-14-2)
• EPA Substance Registry System: Benzenepropanal, 2-acetyl-(99865-14-2)

Safety Data

• Hazardous Substances Data: 99865-14-2(Hazardous Substances Data)

Usage

InChI:InChI=1/C11H12O2/c1-9(13)11-7-3-2-5-10(11)6-4-8-12/h2-3,5,7-8H,4,6H2,1H3

Upstream product

• 200425-59-8 (S)-(+)-1-methyl-1,2,3,4-tetrahydronaphthalen-1-ol 
• 39202-04-5 1-methyl-1,2,3,4-tetrahydronaphthalen-1-ol 
• 529-34-0 3,4-dihydronaphthalene-1(2H)-one 
• 51086-31-8 1-methyl-1,2-tetralindiol 
• 4373-13-1 4-methyl-1,2-dihydronaphthalene 
• 67-66-3 chloroform 

Downstream Products

• 51086-31-8 1-methyl-1,2,3,4-tetrahydronaphthalene-r-1,c-2-diol 
• 1352630-74-0 1-(2-(4-methylpent-3-en-1-yl)phenyl)ethanone 
• 133103-12-5 1-[2-(3,3-dimethoxy-propyl)-phenyl]-ethanone 

Relevant articles and documents

Synthesis of β-acetoxy alcohols by PhI(OAc)2-mediated metal-free diastereoselective β-acetoxylation of alcohols

β-Acetoxy alcohols can be synthesized in good yields with excellent diastereoselectivity from tertiary alcohols through PhI(OAc)2-mediated metal-free β-acetoxylation. Mechanistic studies showed that the β-acetoxylation process might undergo dehydration and sequential highly regioselective and diastereoseletive dioxygenation. Gram scale and diverse useful scaffolds could be prepared via this β-acetoxylation process.

Metal-free intramolecular carbonyl-olefin metathesis of ortho-prenylaryl ketones

On treatment with boron trifluoride etherate as a Lewis acid, acetophenone and benzophenone derivatives bearing a prenyl (or a related) side chain in ortho-position were shown to undergo intramolecular carbonyl-olefin metathesis, in the absence of any tra