99968-32-8Relevant articles and documents
Reaction of Carboxonium Ions of Cyclic Acetals, IX. - Synthesis of Rosefuran and Structurally Related Terpene-like Esters, Alcohols, and Olefins
Meier, Lothar,Scharf, Hans-Dieter
, p. 731 - 740 (2007/10/02)
Thermolysis of the 4-(o-toluoyloxy)-1,3-dioxolanes 4 leads to the furans 6/7 which, via Grignard reaction, can be converted into the alcohols 8/9.Subsequent dehydratization affords the olefins 10/11, e.g. rosefuran (10a).