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Name |
cis-1,2-Diaminocyclohexane |
EINECS | 205-754-6 |
CAS No. | 1436-59-5 | Density | 0.939 g/cm3 |
PSA | 52.04000 | LogP | 1.61560 |
Solubility | Completely miscible in water | Melting Point |
8 °C |
Formula | C6H14N2 | Boiling Point | 193.643 °C at 760 mmHg |
Molecular Weight | 114.191 | Flash Point | 75 °C |
Transport Information | UN 2735 8/PG 2 | Appearance | Clear colorless liquid |
Safety | 26-36/37/39-45 | Risk Codes | 34 |
Molecular Structure | Hazard Symbols | C | |
Synonyms |
1,2-Cyclohexanediamine,cis- (8CI);(R)(S)-1,2-Diaminocyclohexane;cis-(1S,2R)-1,2-Diaminocyclohexane;cis-1,2-Cyclohexanediamine;cis-1,2-Diaminocyclohexane;meso-1,2-Cyclohexanediamine;meso-1,2-Diaminocyclohexane; |
Article Data | 30 |
cis-cyclohexane-1,2-diammonium sulfate
cis-cyclohexane-1,2-diamine
Conditions | Yield |
---|---|
With sodium hydroxide In water for 1.16667h; | 67% |
trans-1,2-cyclohexandiol
A
1,2,3,4,6,7,8,9-octahydrophenazine
B
2-aminocyclohexanol
C
cis-cyclohexane-1,2-diamine
Conditions | Yield |
---|---|
With dodecacarbonyl-triangulo-triruthenium; 4,5-bis((diisopropylphosphanyl)methyl)acridine; ammonia In tert-Amyl alcohol at 170℃; for 21h; Temperature; Inert atmosphere; Schlenk technique; Autoclave; | A 44.8% B n/a C 45.9% |
Conditions | Yield |
---|---|
With DL-tartaric acid In ethanol at 20℃; Reflux; Large scale; | 19.2% |
Conditions | Yield |
---|---|
With chloroform; tris-(2-chloro-ethyl)-amine at 40℃; Erhitzen des Reaktionsprodukts mit methanol.KOH bis auf 130grad; | |
With sodium azide; chloroform; sulfuric acid at 40℃; Erhitzen des Reaktionsprodukts mit methanol.KOH bis auf 130grad; |
cis-cyclohexane-1,2-dicarboxylic acid dihydrazide
cis-cyclohexane-1,2-diamine
Conditions | Yield |
---|---|
With hydrogenchloride; sodium nitrite Erhitzen des Reaktionsprodukts mit methanol.KOH bis auf 130grad; |
1,3-cyclohexanedionedioxime
A
cis-cyclohexane-1,2-diamine
trans-cyclohexane-1,3-diamine
Conditions | Yield |
---|---|
With acetic acid; platinum Hydrogenation; |
diethyl (1RS,2SR)-cyclohexane-1,2-diylbiscarbamate
cis-cyclohexane-1,2-diamine
Conditions | Yield |
---|---|
With hydrogenchloride at 120℃; |
(3aRS,7aSR)-octahydro-2H-benzimidazol-2-one
cis-cyclohexane-1,2-diamine
Conditions | Yield |
---|---|
With sulfuric acid at 105℃; |
(1R,2S)-1,2-diazidocyclohexane
cis-cyclohexane-1,2-diamine
Conditions | Yield |
---|---|
With hydrogen; platinum(IV) oxide In ethanol |
(3aR,7aS)-2-Ethoxy-3a,4,5,6,7,7a-hexahydro-1H-benzoimidazole
cis-cyclohexane-1,2-diamine
Conditions | Yield |
---|---|
With barium dihydroxide at 120℃; for 18h; Yield given; |
Molecular Structure of cis-1,2-Diaminocyclohexane (CAS No.1436-59-5):
Molecular Formula: C6H14N2
Molecular Weight: 114.19
CAS No: 1436-59-5
XLogP3-AA: -0.3
H-Bond Donor: 2
H-Bond Acceptor: 2
Rotatable Bond Count: 0
Exact Mass: 114.115698
MonoIsotopic Mass: 114.115698
Topological Polar Surface Area: 52
Heavy Atom Count: 8
Formal Charge: 0
Complexity: 62.9
Isotope Atom Count: 0
Defined Atom StereoCenter Count: 0
Undefined Atom StereoCenter Count: 2
Defined Bond StereoCenter Count: 0
Undefined Bond StereoCenter Count: 0
Covalently-Bonded Unit Count: 1
Index of Refraction: 1.483
Molar Refractivity: 34.77 cm3
Molar Volume: 121.5 cm3
Surface Tension: 37 dyne/cm
Density: 0.939 g/cm3
Flash Point: 75 °C
Enthalpy of Vaporization: 42.98 kJ/mol
Boiling Point: 193.6 °C at 760 mmHg
Vapour Pressure: 0.46 mmHg at 25°C
Chemical Properties Clear colorless liquid
IUPAC Name: Cyclohexane-1,2-diamine
Canonical SMILES: C1CCC(C(C1)N)N
InChI: InChI=1S/C6H14N2/c7-5-3-1-2-4-6(5)8/h5-6H,1-4,7-8H2
InChIKey: SSJXIUAHEKJCMH-UHFFFAOYSA-N
Hazard Codes: C
Risk Statements: 34
R34:Causes burns.
Safety Statements: 26-36/37/39-45
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection.
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
RIDADR: UN 2735 8/PG 2
WGK Germany: 3
F: 10-34
HazardClass: 8
PackingGroup: II
cis-1,2-Diaminocyclohexane (CAS No.1436-59-5), it also can be called 1,2-Cyclohexanediamine ; Cyclohexane-1,2-diamine ; 1,2-Diaminocyclohexane, mixture of cis and trans .