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CAS : 75-00-3 ProductName : Ethyl chloride
1.
1.1
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product identifiers
Product name
Product Number
Brand
Index-No.
CAS-No.
:
:
:
:
:
Chloroethane
295310
Anonymous
602-009-00-0
75-00-3
1.2
Relevant identified uses of the substance or mixture and uses advised against
Identified uses
:
Laboratory chemicals, Manufacture of substances
2.
2.1
2.2
HAZARDS IDENTIFICATION
Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008 [EU-GHS/CLP]
Flammable gases (Category 1)
Gases under pressure (Liquefied gas)
Carcinogenicity (Category 2)
Chronic aquatic toxicity (Category 3)
Classification according to EU Directives 67/548/EEC or 1999/45/EC
Extremely flammable. Limited evidence of a carcinogenic effect. Harmful to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Label elements
Labelling according Regulation (EC) No 1272/2008 [CLP]
Pictogram
Signal word
Hazard statement(s)
H220
H280
H351
H412
Precautionary statement(s)
P210
Danger
Extremely flammable gas.
Contains gas under pressure; may explode if heated.
Suspected of causing cancer.
Harmful to aquatic life with long lasting effects.
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P273
P281
P410 + P403
Supplemental Hazard
Avoid release to the environment.
Use personal protective equipment as required.
Protect from sunlight. Store in a well-ventilated place.
none
Statements
According to European Directive 67/548/EEC as amended.
Hazard symbol(s)
R-phrase(s)
R12
R40
R52/53
Extremely flammable.
Limited evidence of a carcinogenic effect.
Harmful to aquatic organisms, may cause long-term adverse effects in
the aquatic environment.
S-phrase(s)
S9
S16
S33
S36/37
S61
Keep container in a well-ventilated place.
Keep away from sources of ignition - No smoking.
Take precautionary measures against static discharges.
Wear suitable protective clothing and gloves.
Avoid release to the environment. Refer to special instructions/ Safety
data sheets.
2.3
3.
3.1
Other hazards - none
COMPOSITION/INFORMATION ON INGREDIENTS
Substances
Synonyms
Formula
Molecular Weight
Component
Chloroethane
:
:
:
Ethyl chloride
C2H5Cl
64,51 g/mol
Concentration
CAS-No.
EC-No.
Index-No.
75-00-3
200-830-5
602-009-00-0
-
4.
4.1
4.2
FIRST AID MEASURES
Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Consult a physician.
In case of eye contact
Flush eyes with water as a precaution.
If swallowed
Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with
water. Consult a physician.
Most important symptoms and effects, both acute and delayed
abdominal cramps, Vomiting, Headache, Cough, intoxication, Incoordination., Dizziness, Damage of the:,
Liver, Kidney, It is readily absorbed through lungs and skin, but is also rapidly given off through the lungs.,
Exposure can aggravate:, Dermatitis, Consumption of alcohol may increase toxic effects., At high
concentrations:, cardiac arrest, Acts as a simple asphyxiant by displacing air., Notes to physician: the use
of adrenaline as a stimulant should be avoided due to the sensitizing effect of chloroethane on the
myocardium., To the best of our knowledge, the chemical, physical, and toxicological properties have not
been thoroughly investigated.
4.3
5.
5.1
5.2
5.3
5.4
6.
6.1
6.2
6.3
6.4
7.
7.1
7.2
7.3
8.
8.1
8.2
Indication of any immediate medical attention and special treatment needed
no data available
FIREFIGHTING MEASURES
Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special hazards arising from the substance or mixture
Carbon oxides, Hydrogen chloride gas
Advice for firefighters
Wear self contained breathing apparatus for fire fighting if necessary.
Further information
Use water spray to cool unopened containers.
ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid breathing vapors, mist or gas. Ensure adequate ventilation.
Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to
form explosive concentrations. Vapours can accumulate in low areas.
Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the
environment must be avoided.
Methods and materials for containment and cleaning up
Clean up promptly by sweeping or vacuum.
Reference to other sections
For disposal see section 13.
HANDLING AND STORAGE
Precautions for safe handling
Avoid contact with skin and eyes. Avoid inhalation of vapour or mist.
Keep away from sources of ignition - No smoking.Take measures to prevent the build up of electrostatic
charge.
Conditions for safe storage, including any incompatibilities
Store in cool place. Keep container tightly closed in a dry and well-ventilated place.
Contents under pressure.
Specific end uses
no data available
EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Components with workplace control parameters
Exposure controls
Appropriate engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and
at the end of workday.
Personal protective equipment
Eye/face protection
Face shield and safety glasses Use equipment for eye protection tested and approved under
appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique
(without touching glove's outer surface) to avoid skin contact with this product. Dispose of
contaminated gloves after use in accordance with applicable laws and good laboratory practices.
Wash and dry hands.
The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and
the standard EN 374 derived from it.
Body Protection
Complete suit protecting against chemicals, Flame retardant antistatic protective clothing, The type
of protective equipment must be selected according to the concentration and amount of the
dangerous substance at the specific workplace.
Respiratory protection
Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator
with multi-purpose combination (US) or type AXBEK (EN 14387) respirator cartridges as a backup
to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air
respirator. Use respirators and components tested and approved under appropriate government
standards such as NIOSH (US) or CEN (EU).
9.
9.1
PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
a)
b)
c)
d)
e)
f)
g)
h)
Appearance
Odour
Odour Threshold
pH
Melting point/freezing
point
Initial boiling point and
boiling range
Flash point
Evaporation rate
Form: Liquefied gas
Colour: colourless
no data available
no data available
no data available
-139,0 °C
12,3 °C at 1.013 hPa
-50,0 °C - closed cup
no data available
i)
Flammability (solid, gas) no data available
j)
k)
l)
Upper/lower
flammability or
explosive limits
Vapour pressure
Vapour density
Upper explosion limit: 15,4 %(V)
Lower explosion limit: 3,8 %(V)
1.323,4 hPa at 20,0 °C
3.975,8 hPa at 55,0 °C
no data available
m) Relative density
0,921 g/cm3 at 0 - 4 °C
n)
o)
p)
q)
Water solubility
Partition coefficient: n-
octanol/water
Autoignition
temperature
Decomposition
temperature
no data available
no data available
no data available
no data available
r)
s)
t)
Viscosity
Explosive properties
Oxidizing properties
no data available
no data available
no data available
9.2
10.
10.1
10.2
10.3
10.4
10.5
10.6
11.
11.1
Other safety information
no data available
STABILITY AND REACTIVITY
Reactivity
no data available
Chemical stability
no data available
Possibility of hazardous reactions
no data available
Conditions to avoid
Heat, flames and sparks. Extremes of temperature and direct sunlight.
Incompatible materials
Strong oxidizing agents, Sodium/sodium oxides, Potassium, and its alloys
Hazardous decomposition products
Other decomposition products - no data available
TOXICOLOGICAL INFORMATION
Information on toxicological effects
Acute toxicity
LC50 Inhalation - rat - 2 h - 152.000 mg/m3
Remarks: Brain and Coverings:Other degenerative changes. Behavioral:General anesthetic. Blood:
Hemorrhage.
Skin corrosion/irritation
no data available
Serious eye damage/eye irritation
no data available
Respiratory or skin sensitization
no data available
Germ cell mutagenicity
no data available
Carcinogenicity
This product is or contains a component that has been reported to be possibly carcinogenic based on its
IARC, ACGIH, NTP, or EPA classification.
Limited evidence of carcinogenicity in animal studies
IARC:
No component of this product present at levels greater than or equal to 0.1% is identified as
probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity
no data available
Overexposure may cause reproductive disorder(s) based on tests with laboratory animals.
Specific target organ toxicity - single exposure
no data available
Specific target organ toxicity - repeated exposure
no data available
Aspiration hazard
no data available
Potential health effects
Inhalation
Ingestion
Skin
Eyes
May be harmful if inhaled. May cause respiratory tract irritation.
May be harmful if swallowed.
May be harmful if absorbed through skin. May cause skin irritation.
May cause eye irritation.
Signs and Symptoms of Exposure
abdominal cramps, Vomiting, Headache, Cough, intoxication, Incoordination., Dizziness, Damage of the:,
Liver, Kidney, It is readily absorbed through lungs and skin, but is also rapidly given off through the lungs.,
Exposure can aggravate:, Dermatitis, Consumption of alcohol may increase toxic effects., At high
concentrations:, cardiac arrest, Acts as a simple asphyxiant by displacing air., Notes to physician: the use
of adrenaline as a stimulant should be avoided due to the sensitizing effect of chloroethane on the
myocardium., To the best of our knowledge, the chemical, physical, and toxicological properties have not
been thoroughly investigated.
Additional Information
RTECS: KH7525000
12.
12.1
12.2
12.3
12.4
12.5
12.6
13.
13.1
14.
14.1
ECOLOGICAL INFORMATION
Toxicity
no data available
Persistence and degradability
no data available
Bioaccumulative potential
no data available
Mobility in soil
no data available
Results of PBT and vPvB assessment
no data available
Other adverse effects
Harmful to aquatic life.
Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
DISPOSAL CONSIDERATIONS
Waste treatment methods
Product
Burn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting
as this material is highly flammable. Offer surplus and non-recyclable solutions to a licensed disposal
company.
Contaminated packaging
Dispose of as unused product.
TRANSPORT INFORMATION
UN number
14.2
ADR/RID: 1037
UN proper shipping name
ADR/RID:
ETHYL CHLORIDE
IMDG:
ETHYL CHLORIDE
IATA:
Ethyl chloride
IMDG: 1037
IATA: 1037
Passenger Aircraft: Not permitted for transport
14.3
Transport hazard class(es)
ADR/RID: 2.1
IMDG: 2.1
IATA: 2.1
14.4
Packaging group
14.5
14.6
15.
ADR/RID: -
Environmental hazards
ADR/RID: no
Special precautions for user
no data available
REGULATORY INFORMATION
IMDG: -
IMDG Marine pollutant: no
IATA: -
IATA: no
This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
15.1
15.2
16.
Safety, health and environmental regulations/legislation specific for the substance or mixture
no data available
Chemical Safety Assessment
no data available
OTHER INFORMATION
Further information
The above information is believed to be correct but does not purport to be all inclusive and
shall be used only as a guide. The information this document is based on the resent state
of our knowledge and is applicable to the product with regard to appropriate safety precautions.
It does not represent any guarantee of the properties of the product. Lookchem shall not be
held liable for any damage resulting from handling or from contact with the above product.
See reverse side of invoice or packing slip for additional terms and conditions of sale.


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