|
1.
1.1
IDENTIFICATION
OF
THE
SUBSTANCE/MIXTURE
AND
OF
THE
COMPANY/UNDERTAKING
Product
identifiers
Product
name
Product
Number
Brand
Index-No.
CAS-No.
:
:
:
:
:
1,4-Butanediol
diglycidyl
ether
124192
Anonymous
603-072-00-7
2425-79-8
1.2
Relevant
identified
uses
of
the
substance
or
mixture
and
uses
advised
against
Identified
uses
:
Laboratory
chemicals,
Manufacture
of
substances 2.
2.1
2.2
HAZARDS
IDENTIFICATION
Classification
of
the
substance
or
mixture
Classification
according
to
Regulation
(EC)
No
1272/2008
[EU-GHS/CLP]
Acute
toxicity,
Inhalation
(Category
4)
Acute
toxicity,
Dermal
(Category
4)
Eye
irritation
(Category
2)
Skin
irritation
(Category
2)
Skin
sensitization
(Category
1)
Classification
according
to
EU
Directives
67/548/EEC
or
1999/45/EC
Harmful
by
inhalation
and
in
contact
with
skin.
Irritating
to
eyes
and
skin.
May
cause
sensitization
by
skin
contact.
Label
elements
Labelling
according
Regulation
(EC)
No
1272/2008
[CLP]
Pictogram
Signal
word
Hazard
statement(s)
H312
H315
H317
H319
H332
Warning
Harmful
in
contact
with
skin.
Causes
skin
irritation.
May
cause
an
allergic
skin
reaction.
Causes
serious
eye
irritation.
Harmful
if
inhaled.
Precautionary
statement(s)
P280
P305
+
P351
+
P338
Supplemental
Hazard
Wear
protective
gloves/
protective
clothing.
IF
IN
EYES:
Rinse
cautiously
with
water
for
several
minutes.
Remove
contact
lenses,
if
present
and
easy
to
do.
Continue
rinsing.
none
Statements
According
to
European
Directive
67/548/EEC
as
amended.
Hazard
symbol(s)
R-phrase(s)
R20/21
R36/38
R43
S-phrase(s)
S26
S28
S37/39
Harmful
by
inhalation
and
in
contact
with
skin.
Irritating
to
eyes
and
skin.
May
cause
sensitization
by
skin
contact.
In
case
of
contact
with
eyes,
rinse
immediately
with
plenty
of
water
and
seek
medical
advice.
After
contact
with
skin,
wash
immediately
with
plenty
of
soap
and
water.
Wear
suitable
gloves
and
eye/face
protection.
2.3
3.
3.1
Other
hazards
-
none
COMPOSITION/INFORMATION
ON
INGREDIENTS
Substances
Formula
Molecular
Weight
Component
Butanedioldiglycidyl
ether
:
:
C10H18O4
202,25
g/mol
Concentration
CAS-No.
EC-No.
Index-No.
2425-79-8
219-371-7
603-072-00-7
-
4.
4.1
4.2
4.3
FIRST
AID
MEASURES
Description
of
first
aid
measures
General
advice
Consult
a
physician.
Show
this
safety
data
sheet
to
the
doctor
in
attendance.
If
inhaled
If
breathed
in,
move
person
into
fresh
air.
If
not
breathing,
give
artificial
respiration.
Consult
a
physician.
In
case
of
skin
contact
Wash
off
with
soap
and
plenty
of
water.
Consult
a
physician.
In
case
of
eye
contact
Rinse
thoroughly
with
plenty
of
water
for
at
least
15
minutes
and
consult
a
physician.
If
swallowed
Never
give
anything
by
mouth
to
an
unconscious
person.
Rinse
mouth
with
water.
Consult
a
physician.
Most
important
symptoms
and
effects,
both
acute
and
delayed
To
the
best
of
our
knowledge,
the
chemical,
physical,
and
toxicological
properties
have
not
been
thoroughly
investigated.
Indication
of
any
immediate
medical
attention
and
special
treatment
needed
no
data
available
5.
5.1
5.2
5.3
5.4
6.
6.1
6.2
6.3
6.4
7.
7.1
7.2
7.3
8.
8.1
8.2
FIREFIGHTING
MEASURES
Extinguishing
media
Suitable
extinguishing
media
Use
water
spray,
alcohol-resistant
foam,
dry
chemical
or
carbon
dioxide.
Special
hazards
arising
from
the
substance
or
mixture
Carbon
oxides
Advice
for
firefighters
Wear
self
contained
breathing
apparatus
for
fire
fighting
if
necessary.
Further
information
no
data
available
ACCIDENTAL
RELEASE
MEASURES
Personal
precautions,
protective
equipment
and
emergency
procedures
Use
personal
protective
equipment.
Avoid
breathing
vapors,
mist
or
gas.
Ensure
adequate
ventilation.
Environmental
precautions
Prevent
further
leakage
or
spillage
if
safe
to
do
so.
Do
not
let
product
enter
drains.
Discharge
into
the
environment
must
be
avoided.
Methods
and
materials
for
containment
and
cleaning
up
Soak
up
with
inert
absorbent
material
and
dispose
of
as
hazardous
waste.
Keep
in
suitable,
closed
containers
for
disposal.
Reference
to
other
sections
For
disposal
see
section
13.
HANDLING
AND
STORAGE
Precautions
for
safe
handling
Avoid
contact
with
skin
and
eyes.
Avoid
inhalation
of
vapour
or
mist.
Conditions
for
safe
storage,
including
any
incompatibilities
Store
in
cool
place.
Keep
container
tightly
closed
in
a
dry
and
well-ventilated
place.
Specific
end
uses
no
data
available
EXPOSURE
CONTROLS/PERSONAL
PROTECTION
Control
parameters
Components
with
workplace
control
parameters
Exposure
controls
Appropriate
engineering
controls
Handle
in
accordance
with
good
industrial
hygiene
and
safety
practice.
Wash
hands
before
breaks
and
at
the
end
of
workday.
Personal
protective
equipment
Eye/face
protection
Face
shield
and
safety
glasses
Use
equipment
for
eye
protection
tested
and
approved
under
appropriate
government
standards
such
as
NIOSH
(US)
or
EN
166(EU).
Skin
protection
Handle
with
gloves.
Gloves
must
be
inspected
prior
to
use.
Use
proper
glove
removal
technique
(without
touching
glove's
outer
surface)
to
avoid
skin
contact
with
this
product.
Dispose
of
contaminated
gloves
after
use
in
accordance
with
applicable
laws
and
good
laboratory
practices.
Wash
and
dry
hands.
The
selected
protective
gloves
have
to
satisfy
the
specifications
of
EU
Directive
89/686/EEC
and
the
standard
EN
374
derived
from
it.
Body
Protection
Complete
suit
protecting
against
chemicals,
The
type
of
protective
equipment
must
be
selected
according
to
the
concentration
and
amount
of
the
dangerous
substance
at
the
specific
workplace.
Respiratory
protection
Where
risk
assessment
shows
air-purifying
respirators
are
appropriate
use
a
full-face
respirator
with
multi-purpose
combination
(US)
or
type
ABEK
(EN
14387)
respirator
cartridges
as
a
backup
to
engineering
controls.
If
the
respirator
is
the
sole
means
of
protection,
use
a
full-face
supplied
air
respirator.
Use
respirators
and
components
tested
and
approved
under
appropriate
government
standards
such
as
NIOSH
(US)
or
CEN
(EU).
9.
9.1
PHYSICAL
AND
CHEMICAL
PROPERTIES
Information
on
basic
physical
and
chemical
properties
a)
b)
c)
d)
e)
f)
g)
h)
Appearance
Odour
Odour
Threshold
pH
Melting
point/freezing
point
Initial
boiling
point
and
boiling
range
Flash
point
Evaporation
rate
Form:
clear,
viscous
liquid
Colour:
light
yellow
no
data
available
no
data
available
no
data
available
no
data
available
266
°C
-
lit.
110
°C
-
closed
cup
no
data
available
i)
Flammability
(solid,
gas)
no
data
available
j)
k)
l)
Upper/lower
flammability
or
explosive
limits
Vapour
pressure
Vapour
density
no
data
available
13
hPa
at
20
°C
no
data
available
m)
Relative
density
1,1
g/cm3
at
25
°C
n)
o)
p)
q)
r)
s)
t)
Water
solubility
Partition
coefficient:
n-
octanol/water
Autoignition
temperature
Decomposition
temperature
Viscosity
Explosive
properties
Oxidizing
properties
no
data
available
log
Pow:
-1,33
at
20
°C
no
data
available
no
data
available
no
data
available
no
data
available
no
data
available
9.2
10.
10.1
10.2
Other
safety
information
no
data
available
STABILITY
AND
REACTIVITY
Reactivity
no
data
available
Chemical
stability
no
data
available
10.3
10.4
10.5
10.6
11.
11.1
Possibility
of
hazardous
reactions
no
data
available
Conditions
to
avoid
no
data
available
Incompatible
materials
Strong
oxidizing
agents,
acids,
Bases
Hazardous
decomposition
products
Other
decomposition
products
-
no
data
available
TOXICOLOGICAL
INFORMATION
Information
on
toxicological
effects
Acute
toxicity
LD50
Oral
-
rat
-
1.134
mg/kg
Remarks:
Sense
Organs
and
Special
Senses
(Nose,
Eye,
Ear,
and
Taste):Eye:Other.
Behavioral:Somnolence
(general
depressed
activity).
Skin
and
Appendages:
Other:
Hair.
LD50
Dermal
-
rabbit
-
1.130
mg/kg
Skin
corrosion/irritation
Skin
-
rabbit
-
Skin
irritation
-
24
h
Serious
eye
damage/eye
irritation
Eyes
-
rabbit
-
Moderate
eye
irritation
Respiratory
or
skin
sensitization
May
cause
allergic
skin
reaction.
Germ
cell
mutagenicity
Genotoxicity
in
vitro
-
Hamster
-
Lungs
Sister
chromatid
exchange
Genotoxicity
in
vivo
-
rat
-
Intraperitoneal
Cytogenetic
analysis
Carcinogenicity
Carcinogenicity
-
mouse
-
Skin
Nutritional
and
Gross
Metabolic:Dehydration.
Skin
and
Appendages:
Other:
Tumors.
IARC:
No
component
of
this
product
present
at
levels
greater
than
or
equal
to
0.1%
is
identified
as
probable,
possible
or
confirmed
human
carcinogen
by
IARC.
Reproductive
toxicity
no
data
available
Specific
target
organ
toxicity
-
single
exposure
no
data
available
Specific
target
organ
toxicity
-
repeated
exposure
no
data
available
Aspiration
hazard
no
data
available
Potential
health
effects
Inhalation
Ingestion
Skin
Eyes
Harmful
if
inhaled.
Causes
respiratory
tract
irritation.
Harmful
if
swallowed.
Harmful
if
absorbed
through
skin.
Causes
skin
irritation.
Causes
serious
eye
irritation.
Signs
and
Symptoms
of
Exposure
To
the
best
of
our
knowledge,
the
chemical,
physical,
and
toxicological
properties
have
not
been
thoroughly
investigated.
Additional
Information
RTECS:
EJ5100000
12.
12.1
ECOLOGICAL
INFORMATION
Toxicity
Toxicity
to
fish
Toxicity
to
daphnia
and
other
aquatic
invertebrates
LC50
-
Danio
rerio
(zebra
fish)
-
24
mg/l
-
96
h
EC50
-
Daphnia
magna
(Water
flea)
-
75
mg/l
-
48
h
12.2
Persistence
and
degradability
Biodegradability
Biotic/Aerobic
Result:
<
40
%
-
Not
readily
biodegradable.
12.3
12.4
12.5
12.6
13.
13.1
14.
14.1
Bioaccumulative
potential
no
data
available
Mobility
in
soil
no
data
available
Results
of
PBT
and
vPvB
assessment
no
data
available
Other
adverse
effects
Harmful
to
aquatic
life
with
long
lasting
effects.
no
data
available
DISPOSAL
CONSIDERATIONS
Waste
treatment
methods
Product
Offer
surplus
and
non-recyclable
solutions
to
a
licensed
disposal
company.
Contaminated
packaging
Dispose
of
as
unused
product.
TRANSPORT
INFORMATION
UN
number
14.2
14.3
14.4
14.5
14.6
15.
ADR/RID:
-
UN
proper
shipping
name
ADR/RID:
Not
dangerous
goods
IMDG:
Not
dangerous
goods
IATA:
Not
dangerous
goods
Transport
hazard
class(es)
ADR/RID:
-
Packaging
group
ADR/RID:
-
Environmental
hazards
ADR/RID:
no
Special
precautions
for
user
no
data
available
REGULATORY
INFORMATION
IMDG:
-
IMDG:
-
IMDG:
-
IMDG
Marine
pollutant:
no
IATA:
-
IATA:
-
IATA:
-
IATA:
no
This
safety
datasheet
complies
with
the
requirements
of
Regulation
(EC)
No.
1907/2006.
15.1
Safety,
health
and
environmental
regulations/legislation
specific
for
the
substance
or
mixture
no
data
available
15.2
16.
Chemical
Safety
Assessment
no
data
available
OTHER
INFORMATION
Further
information
The above information is believed to be correct but does not purport to be all inclusive and
shall be used only as a guide. The information this document is based on the resent state
of our knowledge and is applicable to the product with regard to appropriate safety precautions.
It does not represent any guarantee of the properties of the product. Lookchem shall not be
held liable for any damage resulting from handling or from contact with the above product.
See reverse side of invoice or packing slip for additional terms and conditions of sale.
| 
1,4-Butanediol diglycidyl ether
China (Mainland)] 
Assessed
Premium
Assessed
Assessed
Assessed
Assessed
Assessed
Assessed
Assessed
Assessed
Assessed
Assessed
Assessed
Assessed
Assessed
United States] 
South Africa]