Material Safety Data Sheet chemec

Section 1. Chemical Product and Company Identification

MORFAX?
Product Name/ Code 29203
Trade Name
95-32-9
CAS#
Supplier R.T. VANDERBILT COMPANY, INC. Call (203)853-1400
In Case of
30 WINFIELD STREET Emergency
NORWALK, CT 06855
4-morpholinyl-2-benzothiazole disulfide
Synonym

Benzothiazole, 2-(4-morpholinyldithio)-
Chemical name

Chemical Family Not available.

C11H12N2OS3
Chemical Formula

Industrial applications: Accelerator.
Material Uses




Section 2. Composition, Information on Ingredients
EINECS # /
% by
CAS # Classification
Name
ELINCS #
Weight

4-morpholinyl-2-benzothiazole disulfide 95-32-9 99 Not available.
White mineral oil. 8042-47-5 1 Not available.
For additional information regarding European classification see sections 15 & 16.



Section 3. Hazards Identification
Cream to light yellow powder. May cause allergic skin reaction. May cause irritation to the eyes, skin and
Emergency Overview
upper respiratory tract. Dust suspended in air in critical proportions and in the presence of an ignition source
may present an explosion hazard.




Section 4. First Aid Measures
Check for and remove any contact lenses. Flush with running water for at least 15 minutes. Do not use an
Eye Contact
eye ointment. Seek medical attention.
After contact with skin, wash immediately with plenty of water. Gently and thoroughly wash the contaminated
Skin Contact
skin with running water and non-abrasive soap. Be particularly careful to clean folds, crevices, creases and
groin. Cover the irritated skin with an emollient. If irritation persists, seek medical attention. Wash
contaminated clothing before reusing.

Allow the victim to rest in a well ventilated area. Seek immediate medical attention
Inhalation


Do not induce vomiting. Immediately give two glasses of water, a little at a time. Never give anything by
Ingestion
mouth to an unconscious person. Call a physician. If vomiting occurs spontaneously, lower head below waist
to prevent fluid from entering the lungs.




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Section 5. Fire and Explosion Data
Not available.
Flammability of the Product

Not available.
Autoignition Temperature

Not available.
Flash point

Not available.
Flammable Limits

sulfur oxides (SO2, SO3...), nitrogen oxides (NO, NO2...), carbon oxides (CO, CO2), and morpholine.
Products of Combustion


Explosion Hazards in Presence Dust suspended in air in critical proportions and in the presence of an ignition source presents an explosion
hazard.
of Various Substances
SMALL FIRE: Use DRY chemicals, CO2, water spray or foam.
Fire Fighting Media
LARGE FIRE: CO2 may be ineffective on larger fires due to a lack of cooling capacity which may result in
and Instructions
reignition.

No additional remark.
Special Remarks on Fire
Hazards
Special Remarks on Explosion As with any dry material, pouring or allowing to free-fall or to be conveyed through chutes or pipes can
Hazards accumulate and generate electrostatic sparks, potentially causing ignition of the material itself, or of any
flammable materials which may come in contact with the material or its container.



Section 6. Accidental Release Measures
Put spilled solid in a waste disposal container. Finish cleaning by spreading water on the contaminated
Small Spill
surface and dispose of according to local and regional authority requirements.
Evacuate area of nonessential personnel. Use safety glasses and gloves. Respiratory protection is required
Large Spill
only if a dust is generated. Scoop or shovel spilled solids into containers. Avoid creating a dust. Prevent
spilled product or contaminated wash water from entering drinking water supplies or streams.



Section 7. Handling and Storage
Keep container dry. Keep in a cool place. Ground all equipment containing material. Keep container tightly
Storage
closed. Keep in a cool, well-ventilated place. Combustible materials should be stored away from extreme
heat and away from strong oxidizing agents.

Prolonged storage above 110 F will initiate chemical changes resulting in loss of purity.
DO NOT breathe dust. Do not ingest. Avoid contact with skin and eyes. DO NOT use in presence of
Handling Procedures and
electrostatic discharges. Ground all equipment containing material. Wash thoroughly after using.
Equipment




Section 8. Exposure Controls, Personal Protection
Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below
Engineering Controls
recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep
exposure to airborne contaminants below the exposure limit.
Splash goggles. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent.
Personal Precautions
Gloves.
White mineral oil.
TLV/PEL
TWA: 5 (mg/m3) from OSHA (PEL) [United States]
TWA: 5 (mg/m3) from ACGIH (TLV) [United States]




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Section 9. Physical and Chemical Properties
Cream to yellowish. Solid. (Powder)
Appearance

Not applicable.
Molecular Weight

Not applicable.
pH (1% soln/water)

Not available.
Boiling/Condensation Point

116??C (240.8??F)
Melting/Freezing Point

1.51 (Water = 1)
Specific Gravity

Not available.
Density

Not applicable.
Vapor Pressure

Not available.
Vapor Density

Not available.
Volatility

Not available.
Odor

Not available.
Evaporation Rate

Not available.
Viscosity

Not available.
Water/Oil Dist. Coeff.

Insoluble in cold water.
Solubility

Not available.
Flash Point




Section 10. Stability and Reactivity
The product is stable.
Stability

Prolonged storage above 110 F will initiate chemical changes.
Instability Temperature

Not available.
Conditions of Instability

Avoid contact with nitrosating agents. Combining with N-nitrosamines, nitrogen oxides, nitrates, or nitrites
Incompatibility with Various
and/or other nitrosating agents, such as N-nitrosodiphenylamine, may lead to the formation of nitrosamines,
Substances
which may cause cancer.

Reacts with strong oxidizing agents such as hydrogen peroxide, permanganates, and perchlorates. Contact
can result in intense heat, boiling, flame, development, explosion or toxic gas generation depending on the
amount and specific material involved.
Not available.
Corrosivity


Special Remarks on Reactivity Not available.




Section 11. Toxicological Information
Eye contact. Inhalation. Skin contact.
Routes of Entry

Acute oral toxicity (LD50): 11500 mg/kg [Rat].
Toxicity to Animals


Special Remarks on Toxicity to Not available.
Animals

Acute Effects

This product is an eye irritant.
Eye Contact


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This product may irritate skin upon contact.
Skin Contact

May cause skin sensitization in some individuals.
Sensitization

Ingestion May be an ingestion hazard.

Inhalation May cause upper respiratory tract irritation.

Remarks Not available.


CARCINOGENIC EFFECTS Not available.
:
Chronic Effects on
MUTAGENIC EFFECTS Not available.
:
Humans
TERATOGENIC EFFECTS Not available.
:
DEVELOPMENTAL TOXICITY Not available.
:
Not available.
Remarks




Section 12. Ecological Information
Not available.
Ecotoxicity

Not available.
BOD5 and CO
Possibly hazardous short term degradation products are not likely. However, long term degradation products
Products of Biodegradation
may arise.
Not available.
Biodegradability


Not available.
Special Remarks




Section 13. Disposal Considerations
Waste must be disposed according to applicable regulations.
Waste Information

Not available.
Waste Stream



Section 14. Transport Information
Not controlled under ADR (Europe).
ADR Classification




PIN Not applicable.



IMDG Classification.

Not available.


IATA Classification Not controlled under IATA.




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Section 15. Other Regulatory Information and Pictograms
Regulatory Lists EINECS: This product is on the European Inventory of Existing Commercial
Chemical Substances.
Not available.
Remark

R36- Irritating to eyes. S22- Do not breathe dust.
EC Classification /
R43- May cause S24/25- Avoid contact with skin and eyes.
Labelling
sensitization by skin
contact.




Flammability
1
Hazardous Material 2 National Fire Protection
Health Hazard
2 0 Reactivity
Health
Information System Association (U.S.A.)
1
Fire Hazard
(U.S.A.)
0
Physical Hazard Specific hazard

E
Personal Protection




TSCA 8(b) inventory: MORFAX?
Other Regulations

CEPA DSL: MORFAX?

Australia: MORFAX?

China: MORFAX?

Japan (MITI): MORFAX?

Korea (TCCL): MORFAX?

Philippines (RA6969): MORFAX?



Protective Clothing
(Pictograms)




Section 16. Other Information
R36- Irritating to eyes.
Relevant R phrases:
R43- May cause sensitization by skin contact.
References Not available.

Other Special Not available.
Considerations

Verified by Romana Uzar.
Validated by Romana Uzar on 2/8/2007.
Printed 2/8/2007.

Information Contact (203) 853-1400
Corporate Risk Management Department

Notice to Reader

Continued on Next
Information presented herein has been compiled from sources considered to be dependable and is accurate and reliable to the best of our knowledge
and belief but is not guaranteed to be so. Nothing herein is to be construed as recommending any practice or any product in violation of any patent or
in violation of any law or regulation. It is the user??s responsibility to determine for himself the suitability of any material for a specific purpose and to
adopt such safety precautions as may be necessary. We make no warranty as to the results to be obtained in using any material and, since conditions
of use are not under our control, we must necessarily disclaim all liability with respect to the use of any material supplied by us.


4-(2-BENZOTHIAZOLYLDITHIO)MORPHOLINE