CAS : 9016-91-5
MATERIAL SAFETY DATA SHEET
Revision Date: 01/18/2005
Z17000000549/Version: 1.0
Print Date: 12/28/2005
1. Identification of the substance/preparation and of the company/undertaking
Product name: KODAK EKTACOLOR RA Developer Replenisher RT, Part A
Product code: 8477184 - Part A
Manufacturer: EASTMAN KODAK COMPANY, 343 State Street, Rochester, New York, 14650
Supplier: EASTMAN KODAK COMPANY, 343 State Street, Rochester, New York, 14650
For Emergency Health, Safety & Environmental Information, call (585) 722-5151 (USA)
For other information or to request an MSDS, call (800) 242-2424.
Synonyms: PCD 6076
2. Hazards identification
CONTAINS: Triethanolamine (102-71-6), N,N-diethylhydroxylamine (3710-84-7)
WARNING!
MAY CAUSE KIDNEY DAMAGE BASED ON ANIMAL DATA
MAY CAUSE LIVER DAMAGE BASED ON ANIMAL DATA
HARMFUL IF ABSORBED THROUGH SKIN OR SWALLOWE CAUSES SKIN AND EYE IRRITATION
MAY BE HARMFUL IF INHALE COMBUSTIBLE LIQUID AND VAPO HEAT SENSITIVE - CAN DECOMPOSE IF HEATE
HMIS II Hazard Ratings:
Health - 2*, Flammability - 2, Reactivity (Stability) - 1
NFPA Hazard Ratings:
Health - 2, Flammability - 2, Instability - 1
NOTE: HMIS II and NFPA hazard indexes involve data review and interpretation that may vary among
companies. They are intended only for rapid, general identification of the magnitude of the potential
hazards. An asterisk (*), in the HMIS II health field, designates potential chronic or target organ hazards.
To adequately address safe handling, ALL information in this MSDS must be considered.
3. Composition/information on ingredients
Weight % Components (CAS-No.)
60 - 65 Water (7732-18-5)
20 - 25 Triethanolamine (102-71-6)
10 - 15 N,N-diethylhydroxylamine (3710-84-7)
1- 5 Substituted stilbene (82640-05-9)
MATERIAL SAFETY DATA SHEET
Revision Date: 01/18/2005
Z17000000549/Version: 1.0
Print Date: 12/28/2005
<1 Lithium polystyrenesulphonate (9016-91-5)
4. First aid measures
Inhalation: If inhaled, move to fresh air. Treat symptomatically. Get medical attention.
Eyes: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical
attention.
Skin: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical attention if symptoms occur. Wash contaminated
clothing before reuse. Destroy or thoroughly clean contaminated shoes.
Ingestion: Only induce vomiting at the instruction of medical personnel. Never give anything by mouth to
an unconscious person. Call a physician or poison control center immediately.
5. Fire-fighting measures
Extinguishing Media: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special Fire-Fighting Procedures: Wear self-contained breathing apparatus and protective clothing.
Fire or excessive heat may produce hazardous decomposition products. Use water spray to cool
unopened containers.
Hazardous Combustion Products: Carbon oxides, nitrogen oxides (NOx), sulfur oxides
Unusual Fire and Explosion Hazards: Classified as combustible. Material contains a combustible
solvent that may accumulate in the container headspace. Elevated temperature can cause
decomposition.
6. Accidental release measures
Methods for cleaning up: Remove all sources of ignition. Flush into sewer with plenty of water.
Otherwise, absorb spill with vermiculite or other inert material, then place in a container for chemical
waste. Clean surface thoroughly to remove residual contamination.
7. Handling and storage
Personal precautions: Avoid breathing mist or vapour at concentrations greater than the exposure
limits. Avoid contact with eyes, skin, and clothing. Ensure adequate ventilation. Wash thoroughly after
handling.
Prevention of Fire and Explosion: Keep away from heat and sources of ignition. Ensure adequate
ventilation. Keep from contact with oxidizing materials.
Storage: Store in cool place. Keep container tightly closed. Keep away from incompatible substances
(see Incompatibility section.)
8. Exposure controls / personal protection
MATERIAL SAFETY DATA SHEET
Revision Date: 01/18/2005
Z17000000549/Version: 1.0
Print Date: 12/28/2005
Occupational exposure controls
Chemical Name Regulatory List Value Type Value
Triethanolamine ACGIH Time Weighted Average (TWA): 5 mg/m3
Ventilation: Good general ventilation should be used. Ventilation should be sufficient so that applicable
occupational exposure limits are not exceeded. Ventilation rates should be matched to conditions.
Supplementary local exhaust ventilation, closed systems, or respiratory protection may be needed in
special circumstances.
Respiratory protection: If engineering controls do not maintain airborne concentrations below
recommended exposure limits, an approved respirator must be worn. Respirator type: organic vapour. If
respirators are used, a program should be instituted to assure compliance with OSHA Standard 29CF 1910.134 and 29CFR1910.1048.
Eye protection: Wear safety glasses with side shields (or goggles).
Skin and body protection: Wear impervious gloves and protective clothing appropriate for the risk of
exposure.
Recommended Decontamination Facilities: Safety shower, eye wash, washing facilities as
appropriate to condition of use.
9. Physical and Chemical Properties
Physical form: liquid
Colour: yellow
Odour: amine
Specific gravity: 1.05
Vapour pressure (at 20.0 ??C (68.0 ??F)) : 24 mbar (18.0 mm Hg)
Vapor density (air = 1): 0.6
Volatile fraction by weight: 60 - 65 %
Boiling point/range: > 100.0 ??C (> 212.0 ??F)
Water solubility: complete
pH: 10.9
Flash point: 60.0 ??C (140.0 ??F) (Setaflash closed cup)
10. Stability and reactivity
MATERIAL SAFETY DATA SHEET
Revision Date: 01/18/2005
Z17000000549/Version: 1.0
Print Date: 12/28/2005
Stability: Safe handling temperatures are dependent on specific conditions of use and are typically
substantially below the onset temperature. Consult your technical safety experts.
Exotherm onset temperature: 169 ??C by DSC.
Incompatibility: Strong oxidizing agents.
Hazardous decomposition products: None under normal conditions of use.
Hazardous Polymerization: Hazardous polymerisation does not occur.
11. Toxicological information
Effects of Exposure
General advice:
Contains: Triethanolamine. Based on animal data, may cause adverse effects on the following
organs/systems: kidney, liver.
Inhalation: May be harmful if inhaled.
Eyes: Causes eye irritation.
Skin: Causes skin irritation. Harmful if absorbed through skin.
Ingestion: Harmful if swallowed.
12. Ecological information
The following properties are ESTIMATED from the components of the preparations.
Potential Toxicity:
Fish LC50: > 100 mg/l
Daphnid EC50: > 100 mg/l
Algal IC50: > 100 mg/l
Waste treatment organisms EC50: > 100 mg/l
Organics Readily Degradable: Readily biodegradable
Potential Bioaccumulation: log Pow < 1
COD (approximate): 760 g/l
BOD (approximate): 360 g/l
13. Disposal considerations
MATERIAL SAFETY DATA SHEET
Revision Date: 01/18/2005
Z17000000549/Version: 1.0
Print Date: 12/28/2005
Discharge, treatment, or disposal is subject to national, state, provincial, or municipal laws. Consult state
or local regulatory authorities before flushing to sewer with large amounts of water. Since emptied
containers retain product residue, follow label warnings even after container is emptied.
14. Transport information
Not regulated for all modes of transportation.
For transportation information regarding this product call the Kodak Worldwide Transportation Hazmat
Hot Line: (585) 722-2400 between 8 a.m. and 5 p.m. (Eastern Standard Time), Monday through Friday.
In Canada: General Shipping Information, call: (416) 766-8233.
15. Regulatory information
U.S. California Prop. 65: none
Carcinogenicity Classification (components present at 0.1% or more):
International Agency for Research on Cancer (IARC): Triethanolamine: 3 (not classifiable as to
carcinogenicity to humans)
American Conference of Governmental Industrial Hygienists (ACGIH): none
U.S. National Toxicology Program (NTP): none
U.S. Occupational Safety and Health Administration (OSHA): none
Chemical(s) subject to the reporting requirements of U.S. Section 313 or Title III of the Superfund
Amendments and Reauthorization Act (SARA) of 1986 and 40 CFR Part 372: none
16. Other information
US/Canadian Label Statements:
CONTAINS: Triethanolamine (102-71-6), N,N-diethylhydroxylamine (3710-84-7)
WARNING!
MAY CAUSE KIDNEY DAMAGE BASED ON ANIMAL DATA
MAY CAUSE LIVER DAMAGE BASED ON ANIMAL DATA
HARMFUL IF ABSORBED THROUGH SKIN OR SWALLOWE CAUSES SKIN AND EYE IRRITATION
MAY BE HARMFUL IF INHALE COMBUSTIBLE LIQUID AND VAPO HEAT SENSITIVE - CAN DECOMPOSE IF HEATE
Avoid breathing mist or vapour.
Avoid contact with eyes, skin, and clothing.
Ensure adequate ventilation.
Wash thoroughly after handling.
Store in cool place.
Keep away from heat and sources of ignition.
Keep container tightly closed.
MATERIAL SAFETY DATA SHEET
Revision Date: 01/18/2005
Z17000000549/Version: 1.0
Print Date: 12/28/2005
FIRST AID: If swallowed, only induce vomiting as directed by medical personnel. Never give
anything by mouth to an unconscious person. Call a physician or poison control center immediately. If
inhaled, move to fresh air. Treat symptomatically. In case of eye contact, immediately flush eyes with
plenty of water for at least 15 minutes. Get medical attention. In case of skin contact, immediately
flush with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Get medical attention if symptoms occur. Wash contaminated clothing before re-use. Destroy or
thoroughly clean contaminated shoes.
Keep out of reach of children.
For additional information, see Material Safety Data Sheet (MSDS) for this material.
Additional hazard precautions for containers greater than 1 gallon of liquid or 5 pounds of solid:
Since emptied containers retain product residue, follow label warnings even after container is
emptied.
IN CASE OF FIRE: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Use
water spray to cool unopened containers.
IN CASE OF SPILL: Remove all sources of ignition.
The information contained herein is furnished without warranty of any kind. Users should consider these
data only as a supplement to other information gathered by them and must make independent
determinations of suitability and completeness of information from all sources to assure proper use and
disposal of these materials and the safety and health of employees and customers and the protection of
the environment. The information relating to the working solution is for guidance purposes only, and is
based on correct mixing and use of the product according to instructions.
R-1, S-2, F-2, C-1HT
MATERIAL SAFETY DATA SHEET
Revision Date: 01/14/2005
Z17000000255/Version: 1.0
Print Date: 12/28/2005
1. Identification of the substance/preparation and of the company/undertaking
Product name: KODAK EKTACOLOR RA Developer Replenisher RT, Part B
Product code: 8477184 - Part B
Manufacturer: EASTMAN KODAK COMPANY, 343 State Street, Rochester, New York, 14650
Supplier: EASTMAN KODAK COMPANY, 343 State Street, Rochester, New York, 14650
For Emergency Health, Safety & Environmental Information, call (585) 722-5151 (USA)
For other information or to request an MSDS, call (800) 242-2424.
Synonyms: PCD 6157
2. Hazards identification
CONTAINS: 4-(N-ethyl-N-2-methanesulphonylaminoethyl)-2-methylphenylenediamine sesquisulphate
monohydrate (25646-71-3), Potassium sulphite (10117-38-1), Lithium sulphate (10377-48-7)
WARNING!
MAY CAUSE KIDNEY DAMAGE BASED ON ANIMAL DATA
HARMFUL IF SWALLOWE CAUSES SKIN AND EYE IRRITATION
MAY CAUSE ALLERGIC SKIN REACTION
THE TOXICOLOGICAL PROPERTIES OF THIS MATERIAL HAVE NOT BEEN FULLY INVESTIGATE
HMIS II Hazard Ratings:
Health - 2*, Flammability - 1, Reactivity (Stability) - 0
NFPA Hazard Ratings:
Health - 2, Flammability - 1, Instability - 0
NOTE: HMIS II and NFPA hazard indexes involve data review and interpretation that may vary among
companies. They are intended only for rapid, general identification of the magnitude of the potential
hazards. An asterisk (*), in the HMIS II health field, designates potential chronic or target organ hazards.
To adequately address safe handling, ALL information in this MSDS must be considered.
3. Composition/information on ingredients
Weight % Components (CAS-No.)
70 - 75 Water (7732-18-5)
15 - 20 4-(N-ethyl-N-2-methanesulphonylaminoethyl)-2-methylphenylenediamine
sesquisulphate monohydrate (25646-71-3)
5 - 10 Lithium sulphate (10377-48-7)
<1 Potassium sulphite (10117-38-1)
<1 Magnesium sulphate (7487-88-9)
MATERIAL SAFETY DATA SHEET
Revision Date: 01/14/2005
Z17000000255/Version: 1.0
Print Date: 12/28/2005
4. First aid measures
Inhalation: If symptomatic, move to fresh air. Treat symptomatically. Get medical attention if symptoms
occur.
Eyes: Immediately flush with plenty of water for at least 15 minutes. Get medical attention.
Skin: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical attention if symptoms occur. Wash contaminated
clothing before re-use. Destroy or thoroughly clean contaminated shoes.
Ingestion: Only induce vomiting at the instruction of medical personnel. Call a physician or poison
control center immediately. Never give anything by mouth to an unconscious person.
5. Fire-fighting measures
Extinguishing Media: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special Fire-Fighting Procedures: Wear self-contained breathing apparatus and protective clothing.
Fire or excessive heat may produce hazardous decomposition products.
Hazardous Combustion Products: Carbon oxides, nitrogen oxides (NOx), sulfur oxides
Unusual Fire and Explosion Hazards: None.
6. Accidental release measures
Methods for cleaning up: Absorb spill with vermiculite or other inert material, then place in a container
for chemical waste. Clean surface thoroughly to remove residual contamination.
7. Handling and storage
Personal precautions: Avoid breathing mist or vapour at concentrations greater than the exposure
limits. Do not get in eyes, on skin, or on clothing. Ensure adequate ventilation. Wash thoroughly after
handling.
Prevention of Fire and Explosion: Keep from contact with oxidizing materials.
Storage: Keep container tightly closed. Keep away from incompatible substances (see Incompatibility
section.)
8. Exposure controls / personal protection
Occupational exposure controls
Chemical Name Regulatory List Value Type Value
4-(N-ethyl-N-2- EK HPG Time Weighted Average (TWA): 1.0 mg/m3
methanesulphonylamin
oethyl)-2-
MATERIAL SAFETY DATA SHEET
Revision Date: 01/14/2005
Z17000000255/Version: 1.0
Print Date: 12/28/2005
methylphenylenediami
ne sesquisulphate
monohydrate
Ventilation: Good general ventilation should be used. Ventilation should be sufficient so that applicable
occupational exposure limits are not exceeded. Ventilation rates should be matched to conditions.
Supplementary local exhaust ventilation, closed systems, or respiratory protection may be needed in
special circumstances.
Respiratory protection: If engineering controls do not maintain airborne concentrations below
recommended exposure limits, an approved respirator must be worn. Respirator type: Acid gas. If
respirators are used, a program should be instituted to assure compliance with OSHA Standard 29CF 1910.134 and 29CFR1910.1048.
Eye protection: Wear safety glasses with side shields (or goggles).
Skin and body protection: Wear impervious gloves and protective clothing appropriate for the risk of
exposure.
Recommended Decontamination Facilities: Safety shower, eye wash, washing facilities as
appropriate to condition of use.
9. Physical and Chemical Properties
Physical form: liquid
Colour: tan
Odour: sharp sulphur dioxide
Specific gravity: 1.14
Vapour pressure (at 20.0 ??C (68.0 ??F)) : 24 mbar (18.0 mm Hg)
Vapor density (air = 1): 0.6
Volatile fraction by weight: 70 - 75 %
Boiling point/range: > 100.0 ??C (> 212.0 ??F)
Water solubility: complete
pH: 1.4
Flash point: > 93.3 ??C (> 200.0 ??F) (estimated)
10. Stability and reactivity
Stability: Stable
Incompatibility: strong oxidizing agents.
MATERIAL SAFETY DATA SHEET
Revision Date: 01/14/2005
Z17000000255/Version: 1.0
Print Date: 12/28/2005
Hazardous decomposition products: None under normal conditions of use.
Hazardous Polymerization: Hazardous polymerisation does not occur.
11. Toxicological information
Effects of Exposure
General advice:
Contains: 4-(N-ethyl-N-2-methanesulphonylaminoethyl)-2-methylphenylenediamine
sesquisulphate monohydrate. May cause kidney damage based on animal data.
Contains: Lithium sulphate. The toxicological properties of this material have not been fully
investigated and its handling and use may present additional hazards. This material is
pharmacologically active. Can cause CNS effects.
Inhalation: Expected to be a low hazard for recommended handling.
Eyes: Causes irritation.
Skin: Causes irritation. May cause allergic skin reaction.
Ingestion: Harmful if swallowed. May cause irritation of the gastrointestinal tract if swallowed. Some
asthmatics or sulfite-sensitive individuals may experience wheezing, chest tightness, stomach upset,
hives, faintness, weakness and diarrhea.
Data for 4-(N-ethyl-N-2-methanesulphonylaminoethyl)-2-methylphenylenediamine
sesquisulphate monohydrate:
Acute Toxicity Data:
?? Oral LD50 (male rat): 400 mg/kg (target organ effects: kidney)
?? Oral LD50 (female rat): 246 mg/kg
?? Dermal LD50: > 1,000 mg/kg (highest dose tested)
?? Skin irritation: slight
?? Skin irritation: moderate (repeated skin application)
?? Skin Sensitization: moderate
?? Skin Sensitization (human): positive
?? Eye irritation (unwashed eyes): Moderate eye irritation
?? Eye irritation (washed eyes): slight
Definitions for the following section(s): LOEL =lowest-observed-effect level, LOAEL = lowest-
observed-adverse-effect, NOAEL = no observed-adverse-effect level, NOEL =no-observed-effect
level.
Carcinogenicity:
?? Oral study (hamster, 2 years): NOEL; 0.04 % in diet (highest dose tested)
?? Dermal study (mouse, 2 years): NOEL; 62 mg/kg (only dose tested)
MATERIAL SAFETY DATA SHEET
Revision Date: 01/14/2005
Z17000000255/Version: 1.0
Print Date: 12/28/2005
12. Ecological information
Potential Toxicity:
Fish LC50: 1 - 10 mg/l
Daphnid EC50: 10 - 100 mg/l
Algal IC50: 10 - 100 mg/l
Waste treatment organisms EC50: > 100 mg/l
Organics Readily Degradable: Readily biodegradable
Potential Bioaccumulation: log Pow < 1
COD (approximate): 186 g/l
BOD (approximate): 22 g/l
13. Disposal considerations
Discharge, treatment, or disposal is subject to national, state, provincial, or municipal laws. Contract with
a licensed chemical disposal agency. Since emptied containers retain product residue, follow label
warnings even after container is emptied.
14. Transport information
The information given below is provided to assist in documentation. It may supplement the information on
the package. The package in your possession may carry a different version of the label depending on the
date of manufacture. Depending on inner packaging quantities and packaging instructions, it may be
subject to specific regulatory exceptions. Please consult the product packaging for further details.
UN Number: UN3265
US DOT:
Proper shipping name: Corrosive liquid, acidic, organic, n.o.s. (4-(N-ethyl-N-2-
methanesulphonylaminoethyl)-2-methylphenylenediamine
sesquisulphate monohydrate)
Class: 8
Packaging group: III
UN Number: UN3265
IMDG:
Proper shipping name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. (4-(N-
ethyl-N-2-methanesulphonylaminoethyl)-2-
methylphenylenediamine sesquisulphate monohydrate)
Class: 8
Packaging group: III
UN Number: UN3265
IATA:
Proper shipping name: Corrosive liquid, acidic, organic, n.o.s. (4-(N-ethyl-N-2-
methanesulphonylaminoethyl)-2-methylphenylenediamine
MATERIAL SAFETY DATA SHEET
Revision Date: 01/14/2005
Z17000000255/Version: 1.0
Print Date: 12/28/2005
sesquisulphate monohydrate)
Class: 8
Packaging group: III
For transportation information regarding this product call the Kodak Worldwide Transportation Hazmat
Hot Line: (585) 722-2400 between 8 a.m. and 5 p.m. (Eastern Standard Time), Monday through Friday.
In Canada: General Shipping Information, call: (416) 766-8233.
15. Regulatory information
U.S. California Prop. 65: none
Carcinogenicity Classification (components present at 0.1% or more):
International Agency for Research on Cancer (IARC): Potassium sulphite: 3 (not classifiable as to
carcinogenicity to humans)
American Conference of Governmental Industrial Hygienists (ACGIH): none
U.S. National Toxicology Program (NTP): none
U.S. Occupational Safety and Health Administration (OSHA): none
Chemical(s) subject to the reporting requirements of U.S. Section 313 or Title III of the Superfund
Amendments and Reauthorization Act (SARA) of 1986 and 40 CFR Part 372: none
16. Other information
US/Canadian Label Statements:
CONTAINS: 4-(N-ethyl-N-2-methanesulphonylaminoethyl)-2-methylphenylenediamine
sesquisulphate monohydrate (25646-71-3), Potassium sulphite (10117-38-1), Lithium sulphate
(10377-48-7)
WARNING!
MAY CAUSE KIDNEY DAMAGE BASED ON ANIMAL DATA
HARMFUL IF SWALLOWE CAUSES SKIN AND EYE IRRITATION
MAY CAUSE ALLERGIC SKIN REACTION
THE TOXICOLOGICAL PROPERTIES OF THIS MATERIAL HAVE NOT BEEN FULLY
INVESTIGATE
Avoid prolonged or repeated breathing of mist or vapour.
Do not get in eyes, on skin, or on clothing.
Keep container closed.
Ensure adequate ventilation.
Wash thoroughly after handling.
FIRST AID: If swallowed, only induce vomiting as directed by medical personnel. Never give
anything by mouth to an unconscious person. Call a physician or poison control center immediately.
In case of eye contact, immediately flush eyes with plenty of water for at least 15 minutes. Get
medical attention. In case of skin contact, immediately flush with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Get medical attention if symptoms occur.
Wash contaminated clothing before re-use. Destroy or thoroughly clean contaminated shoes.
Keep out of reach of children.
MATERIAL SAFETY DATA SHEET
Revision Date: 01/14/2005
Z17000000255/Version: 1.0
Print Date: 12/28/2005
For additional information, see Material Safety Data Sheet (MSDS) for this material.
Additional hazard precautions for containers greater than 1 gallon of liquid or 5 pounds of solid:
Since emptied containers retain product residue, follow label warnings even after container is
emptied.
IN CASE OF FIRE: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
The information contained herein is furnished without warranty of any kind. Users should consider these
data only as a supplement to other information gathered by them and must make independent
determinations of suitability and completeness of information from all sources to assure proper use and
disposal of these materials and the safety and health of employees and customers and the protection of
the environment. The information relating to the working solution is for guidance purposes only, and is
based on correct mixing and use of the product according to instructions.
R-1, S-3, F-1, C-0
MATERIAL SAFETY DATA SHEET
Revision Date: 01/19/2005
Z17000000551/Version: 1.0
Print Date: 12/28/2005
1. Identification of the substance/preparation and of the company/undertaking
Product name: KODAK EKTACOLOR RA Developer Replenisher RT, Part C
Product code: 8477184 - Part C
Manufacturer: EASTMAN KODAK COMPANY, 343 State Street, Rochester, New York, 14650
Supplier: EASTMAN KODAK COMPANY, 343 State Street, Rochester, New York, 14650
For Emergency Health, Safety & Environmental Information, call (585) 722-5151 (USA)
For other information or to request an MSDS, call (800) 242-2424.
Synonyms: PCD 6087
2. Hazards identification
CONTAINS: Potassium hydroxide (1310-58-3), Potassium carbonate (584-08-7)
DANGER!
CAUSES SEVERE EYE BURNS
DUST, MIST OR VAPOUR EXTREMELY IRRITATING TO THE EYES AND RESPIRATORY TRACT
HARMFUL IF SWALLOWE
HMIS II Hazard Ratings:
Health - 3, Flammability - 0, Reactivity (Stability) - 0
NFPA Hazard Ratings:
Health - 2, Flammability - 0, Instability - 0
NOTE: HMIS II and NFPA hazard indexes involve data review and interpretation that may vary among
companies. They are intended only for rapid, general identification of the magnitude of the potential
hazards. An asterisk (*), in the HMIS II health field, designates potential chronic or target organ hazards.
To adequately address safe handling, ALL information in this MSDS must be considered.
3. Composition/information on ingredients
Weight % Components (CAS-No.)
60 - 65 Water (7732-18-5)
30 - 35 Potassium carbonate (584-08-7)
1- 3 Potassium hydroxide (1310-58-3)
1- 5 Potassium chloride (7447-40-7)
<1 Substituted phosphonate (2809-21-4)
4. First aid measures
MATERIAL SAFETY DATA SHEET
Revision Date: 01/19/2005
Z17000000551/Version: 1.0
Print Date: 12/28/2005
Inhalation: Move to fresh air. Treat symptomatically. Get medical attention if symptoms occur.
Eyes: Rinse immediately with plenty of water for at least 15 minutes. Get medical attention immediately.
Skin: Wash off with soap and water. Get medical attention if symptoms occur.
Ingestion: Do NOT induce vomiting. Give victim a glass of water. Call a physician or poison control
center immediately. Never give anything by mouth to an unconscious person.
Notes to physician:
Treatment: Strong alkalis bind tissue protein. Following initial flushing of the eye with water,
continued irrigation of the eye with saline is recommended. Treatment should be continued until pH
of tears reaches neutral.
5. Fire-fighting measures
Extinguishing Media: Use extinguishing measures that are appropriate to local circumstances and the
surrounding environment.
Special Fire-Fighting Procedures: Wear self-contained breathing apparatus and protective clothing.
Hazardous Combustion Products: None (noncombustible)
Unusual Fire and Explosion Hazards: None.
6. Accidental release measures
Methods for cleaning up: Absorb spill with vermiculite or other inert material, then place in a container
for chemical waste. Clean surface thoroughly to remove residual contamination.
7. Handling and storage
Personal precautions: Avoid breathing mist or vapour at concentrations greater than the exposure
limits. Do not get in eyes and avoid contact with skin and clothing. Ensure adequate ventilation. Wash
thoroughly after handling.
Prevention of Fire and Explosion: No special technical protective measures required.
Storage: Keep container tightly closed. Keep away from incompatible substances (see Incompatibility
section.)
8. Exposure controls / personal protection
Occupational exposure controls
Chemical Name Regulatory List Value Type Value
Potassium hydroxide ACGIH Ceiling Limit Value: 2 mg/m3
Ventilation: Good general ventilation should be used. Ventilation should be sufficient so that applicable
MATERIAL SAFETY DATA SHEET
Revision Date: 01/19/2005
Z17000000551/Version: 1.0
Print Date: 12/28/2005
occupational exposure limits are not exceeded. Ventilation rates should be matched to conditions.
Supplementary local exhaust ventilation, closed systems, or respiratory protection may be needed in
special circumstances.
Respiratory protection: If engineering controls do not maintain airborne concentrations below
recommended exposure limits, an approved respirator must be worn. Respirator type: N95 Particulate
Filter. If respirators are used, a program should be instituted to assure compliance with OSHA Standard
29CFR 1910.134 and 29CFR1910.1048.
Eye protection: Wear safety glasses with side shields (or goggles) and a face shield.
Skin and body protection: It is a good industrial hygiene practice to minimize skin contact. Wear
impervious gloves and protective clothing appropriate for the risk of exposure.
Recommended Decontamination Facilities: Safety shower, eye wash, washing facilities as
appropriate to condition of use.
9. Physical and Chemical Properties
Physical form: liquid
Colour: colourless
Odour: odourless
Specific gravity: 1.37
Vapour pressure (at 20.0 ??C (68.0 ??F)) : 24 mbar (18.0 mm Hg)
Vapor density (air = 1): 0.6
Volatile fraction by weight: 60 - 65 %
Boiling point/range: > 100.0 ??C (> 212.0 ??F)
Water solubility: complete
pH: > 14
Flash point: none, noncombustible liquid
10. Stability and reactivity
Stability: Stable.
Incompatibility: Acids.
Hazardous decomposition products: None under normal conditions of use.
Hazardous Polymerization: Hazardous polymerisation does not occur.
MATERIAL SAFETY DATA SHEET
Revision Date: 01/19/2005
Z17000000551/Version: 1.0
Print Date: 12/28/2005
11. Toxicological information
Effects of Exposure
Inhalation: Airborne dust/mist/vapor extremely irritating.
Eyes: Causes eye burns. Airborne dust/mist/vapor extremely irritating.
Skin: Expected to be a low hazard for recommended handling.
Ingestion: Harmful if swallowed. May cause burns of the gastrointestinal tract if swallowed.
Acute Toxicity Data:
?? Skin irritation: none
?? Eye irritation: severe
12. Ecological information
The following properties are ESTIMATED from the components of the preparations.
Potential Toxicity:
Fish LC50: > 100 mg/l
Daphnid EC50: > 100 mg/l
Algal IC50: > 100 mg/l
Waste treatment organisms EC50: > 100 mg/l
Organics Readily Degradable: Not readily biodegradable.
Potential Bioaccumulation: log Pow < 1
COD (approximate): < 1 g/l
BOD (approximate): < 1 g/l
13. Disposal considerations
Discharge, treatment, or disposal is subject to national, state, provincial, or municipal laws. Contract with
a licensed chemical disposal agency. Since emptied containers retain product residue, follow label
warnings even after container is emptied.
14. Transport information
The information given below is provided to assist in documentation. It may supplement the information on
the package. The package in your possession may carry a different version of the label depending on the
date of manufacture. Depending on inner packaging quantities and packaging instructions, it may be
subject to specific regulatory exceptions. Please consult the product packaging for further details.
MATERIAL SAFETY DATA SHEET
Revision Date: 01/19/2005
Z17000000551/Version: 1.0
Print Date: 12/28/2005
UN Number: UN1814
US DOT:
Proper shipping name: Potassium hydroxide, solution
Class: 8
Packaging group: III
UN Number: UN1814
IMDG:
Proper shipping name: POTASSIUM HYDROXIDE SOLUTION
Class: 8
Packaging group: III
UN Number: UN1814
IATA:
Proper shipping name: Potassium hydroxide solution
Class: 8
Packaging group: III
For transportation information regarding this product call the Kodak Worldwide Transportation Hazmat
Hot Line: (585) 722-2400 between 8 a.m. and 5 p.m. (Eastern Standard Time), Monday through Friday.
In Canada: General Shipping Information, call: (416) 766-8233.
15. Regulatory information
U.S. California Prop. 65: none
Carcinogenicity Classification (components present at 0.1% or more):
International Agency for Research on Cancer (IARC): none
American Conference of Governmental Industrial Hygienists (ACGIH): none
U.S. National Toxicology Program (NTP): none
U.S. Occupational Safety and Health Administration (OSHA): none
Chemical(s) subject to the reporting requirements of U.S. Section 313 or Title III of the Superfund
Amendments and Reauthorization Act (SARA) of 1986 and 40 CFR Part 372: none
16. Other information
US/Canadian Label Statements:
CONTAINS: Potassium hydroxide (1310-58-3), Potassium carbonate (584-08-7)
DANGER!
CAUSES SEVERE EYE BURNS
DUST, MIST OR VAPOUR EXTREMELY IRRITATING TO THE EYES AND RESPIRATORY TRACT
HARMFUL IF SWALLOWE
Do not get in eyes and avoid contact with skin and clothing.
Avoid breathing mist or vapour.
Ensure adequate ventilation.
Wash thoroughly after handling.
FIRST AID: If inhaled, move to fresh air. Treat symptomatically. Get medical attention if symptoms
occur. If swallowed, do NOT induce vomiting. Give victim a glass of water. Never give anything by
mouth to an unconscious person. Call a physician or poison control center immediately. In case of
MATERIAL SAFETY DATA SHEET
Revision Date: 01/19/2005
Z17000000551/Version: 1.0
Print Date: 12/28/2005
eye contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention
immediately.
Notes to physician: Strong alkalis bind tissue protein. Following initial flushing of the eye with water,
continued irrigation of the eye with saline is recommended. Treatment should be continued until pH of
tears reaches neutral.
Keep out of reach of children.
Do not handle or use until safety precautions in Material Safety Data Sheet (MSDS) have been read
and understood.
Additional hazard precautions for containers greater than 1 gallon of liquid or 5 pounds of solid:
Since emptied containers retain product residue, follow label warnings even after container is
emptied.
The information contained herein is furnished without warranty of any kind. Users should consider these
data only as a supplement to other information gathered by them and must make independent
determinations of suitability and completeness of information from all sources to assure proper use and
disposal of these materials and the safety and health of employees and customers and the protection of
the environment. The information relating to the working solution is for guidance purposes only, and is
based on correct mixing and use of the product according to instructions.
R-1, S-3, F-0, C-0
MATERIAL SAFETY DATA SHEET
Revision Date: 01/19/2005
000000012235/Version: 1.0
Print Date: 12/28/2005
1. Identification of the substance/preparation and of the company/undertaking
Product name: KODAK EKTACOLOR RA Developer Replenisher RT, Working solution
Product code: 8477184 - Working solution
Manufacturer: EASTMAN KODAK COMPANY, 343 State Street, Rochester, New York, 14650
Supplier: EASTMAN KODAK COMPANY, 343 State Street, Rochester, New York, 14650
For Emergency Health, Safety & Environmental Information, call (585) 722-5151 (USA)
For other information or to request an MSDS, call (800) 242-2424.
Synonyms: None.
2. Hazards identification
CONTAINS: 4-(N-ethyl-N-2-methanesulphonylaminoethyl)-2-methylphenylenediamine sesquisulphate
monohydrate (25646-71-3), Potassium hydroxide (1310-58-3), Triethanolamine (102-71-6)
WARNING!
MAY CAUSE LIVER DAMAGE BASED ON ANIMAL DATA
MAY CAUSE KIDNEY DAMAGE BASED ON ANIMAL DATA
HARMFUL IF SWALLOWE MAY BE HARMFUL IF ABSORBED THROUGH SKIN
MAY BE HARMFUL IF INHALE CAUSES SKIN AND EYE IRRITATION
MAY CAUSE ALLERGIC SKIN REACTION
HMIS II Hazard Ratings:
Health - 2*, Flammability - 0, Reactivity (Stability) - 0
NFPA Hazard Ratings:
Health - 1, Flammability - 0, Instability - 0
NOTE: HMIS II and NFPA hazard indexes involve data review and interpretation that may vary among
companies. They are intended only for rapid, general identification of the magnitude of the potential
hazards. An asterisk (*), in the HMIS II health field, designates potential chronic or target organ hazards.
To adequately address safe handling, ALL information in this MSDS must be considered.
3. Composition/information on ingredients
Weight % Components (CAS-No.)
90 - 95 Water (7732-18-5)
1- 5 Potassium carbonate (584-08-7)
1- 5 Triethanolamine (102-71-6)
<1 4-(N-ethyl-N-2-methanesulphonylaminoethyl)-2-methylphenylenediamine
MATERIAL SAFETY DATA SHEET
Revision Date: 01/19/2005
000000012235/Version: 1.0
Print Date: 12/28/2005
sesquisulphate monohydrate (25646-71-3)
<1 N,N-diethylhydroxylamine (3710-84-7)
< 0.5 Potassium hydroxide (1310-58-3)
4. First aid measures
Inhalation: If inhaled, move to fresh air. Treat symptomatically. Get medical attention.
Eyes: Immediately flush with plenty of water for at least 15 minutes. Get medical attention.
Skin: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical attention if symptoms occur. Wash contaminated
clothing before reuse. Destroy or thoroughly clean contaminated shoes.
Ingestion: Only induce vomiting at the instruction of medical personnel. Call a physician or poison
control center immediately. Never give anything by mouth to an unconscious person.
5. Fire-fighting measures
Extinguishing Media: Use extinguishing measures that are appropriate to local circumstances and the
surrounding environment.
Special Fire-Fighting Procedures: None (noncombustible)
Hazardous Combustion Products: None (noncombustible)
Unusual Fire and Explosion Hazards: None.
6. Accidental release measures
Methods for cleaning up: Flush into sewer with plenty of water. Otherwise, absorb spill with vermiculite
or other inert material, then place in a container for chemical waste. Clean surface thoroughly to remove
residual contamination.
7. Handling and storage
Personal precautions: Avoid breathing mist or vapour at concentrations greater than the exposure
limits. Avoid contact with eyes, skin, and clothing. Ensure adequate ventilation. Wash thoroughly after
handling.
Prevention of Fire and Explosion: No special technical protective measures required.
Storage: Keep container tightly closed.
8. Exposure controls / personal protection
Occupational exposure controls
MATERIAL SAFETY DATA SHEET
Revision Date: 01/19/2005
000000012235/Version: 1.0
Print Date: 12/28/2005
Chemical Name Regulatory List Value Type Value
Potassium hydroxide ACGIH Ceiling Limit Value: 2 mg/m3
Triethanolamine ACGIH Time Weighted Average (TWA): 5 mg/m3
4-(N-ethyl-N-2- EK HPG Time Weighted Average (TWA): 1.0 mg/m3
methanesulphonylamin
oethyl)-2-
methylphenylenediami
ne sesquisulphate
monohydrate
Ventilation: Good general ventilation should be used. Ventilation should be sufficient so that applicable
occupational exposure limits are not exceeded. Ventilation rates should be matched to conditions.
Supplementary local exhaust ventilation, closed systems, or respiratory protection may be needed in
special circumstances.
Respiratory protection: If engineering controls do not maintain airborne concentrations below
recommended exposure limits, an approved respirator must be worn. Respirator type: organic vapour. If
respirators are used, a program should be instituted to assure compliance with OSHA Standard 29CF 1910.134 and 29CFR1910.1048.
Eye protection: Wear safety glasses with side shields (or goggles).
Skin and body protection: Wear impervious gloves and protective clothing appropriate for the risk of
exposure.
Recommended Decontamination Facilities: Safety shower, eye wash, washing facilities as
appropriate to condition of use.
9. Physical and Chemical Properties
Physical form: liquid
Colour: light yellow
Odour: strong amine
Specific gravity: 1.03
Vapour pressure: 24 mbar (18.0 mm Hg)
Vapor density (air = 1): 0.6
Volatile fraction by weight: 90 - 95 %
Boiling point/range: > 100.0 ??C (> 212.0 ??F)
Water solubility: complete
pH: 10.7 - 10.8
Flash point: none, noncombustible liquid
MATERIAL SAFETY DATA SHEET
Revision Date: 01/19/2005
000000012235/Version: 1.0
Print Date: 12/28/2005
10. Stability and reactivity
Stability: Stable
Incompatibility: None with common materials and contaminants with which the material may reasonably
come into contact.
Hazardous decomposition products: None under normal conditions of use.
Hazardous Polymerization: Hazardous polymerisation does not occur.
11. Toxicological information
Effects of Exposure
General advice:
Contains: Triethanolamine. Based on animal data, may cause adverse effects on the following
organs/systems: kidney, liver.
Inhalation: May be harmful if inhaled.
Eyes: Causes irritation.
Skin: Causes irritation. May cause allergic skin reaction. May be harmful if absorbed through skin.
Ingestion: Harmful if swallowed. May cause irritation of the gastrointestinal tract if swallowed.
12. Ecological information
The following properties are ESTIMATED from the components of the preparations.
Potential Toxicity:
Fish LC50: > 100 mg/l
Daphnid EC50: > 100 mg/l
Algal IC50: > 100 mg/l
Waste treatment organisms EC50: > 100 mg/l
Organics Readily Degradable: Readily biodegradable
Potential Bioaccumulation: log Pow < 1
COD (approximate): 40 g/l
BOD (approximate): 19 g/l
MATERIAL SAFETY DATA SHEET
Revision Date: 01/19/2005
000000012235/Version: 1.0
Print Date: 12/28/2005
13. Disposal considerations
Discharge, treatment, or disposal may be subject to national, state, or local laws. Consult state or local
regulatory authorities before flushing to sewer with large amounts of water. Since emptied containers
retain product residue, follow label warnings even after container is emptied.
14. Transport information
For transportation information regarding this product call the Kodak Worldwide Transportation Hazmat
Hot Line: (585) 722-2400 between 8 a.m. and 5 p.m. (Eastern Standard Time), Monday through Friday.
In Canada: General Shipping Information, call: (416) 766-8233.
15. Regulatory information
U.S. California Prop. 65: none
Carcinogenicity Classification (components present at 0.1% or more):
International Agency for Research on Cancer (IARC): Triethanolamine: 3 (not classifiable as to
carcinogenicity to humans)
American Conference of Governmental Industrial Hygienists (ACGIH): none
U.S. National Toxicology Program (NTP): none
U.S. Occupational Safety and Health Administration (OSHA): none
Chemical(s) subject to the reporting requirements of U.S. Section 313 or Title III of the Superfund
Amendments and Reauthorization Act (SARA) of 1986 and 40 CFR Part 372: none
16. Other information
US/Canadian Label Statements:
CONTAINS: 4-(N-ethyl-N-2-methanesulphonylaminoethyl)-2-methylphenylenediamine
sesquisulphate monohydrate (25646-71-3), Potassium hydroxide (1310-58-3), Triethanolamine
(102-71-6)
WARNING!
MAY CAUSE LIVER DAMAGE BASED ON ANIMAL DATA
MAY CAUSE KIDNEY DAMAGE BASED ON ANIMAL DATA
HARMFUL IF SWALLOWE MAY BE HARMFUL IF ABSORBED THROUGH SKIN
MAY BE HARMFUL IF INHALE CAUSES SKIN AND EYE IRRITATION
MAY CAUSE ALLERGIC SKIN REACTION
Avoid prolonged or repeated breathing of mist or vapour.
Avoid contact with eyes, skin, and clothing.
Use with adequate ventilation.
Wash thoroughly after handling.
FIRST AID: If swallowed, only induce vomiting as directed by medical personnel. Never give
anything by mouth to an unconscious person. Call a physician or poison control center immediately. If
MATERIAL SAFETY DATA SHEET
Revision Date: 01/19/2005
000000012235/Version: 1.0
Print Date: 12/28/2005
inhaled, move to fresh air. Treat symptomatically. In case of eye contact, immediately flush eyes with
plenty of water for at least 15 minutes. Get medical attention. In case of skin contact, immediately
flush with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Get medical attention if symptoms occur. Wash contaminated clothing before re-use. Destroy or
thoroughly clean contaminated shoes.
Keep out of reach of children.
For additional information, see Material Safety Data Sheet (MSDS) for this material.
Additional hazard precautions for containers greater than 1 gallon of liquid or 5 pounds of solid:
Since emptied containers retain product residue, follow label warnings even after container is
emptied.
The information contained herein is furnished without warranty of any kind. Users should consider these
data only as a supplement to other information gathered by them and must make independent
determinations of suitability and completeness of information from all sources to assure proper use and
disposal of these materials and the safety and health of employees and customers and the protection of
the environment. The information relating to the working solution is for guidance purposes only, and is
based on correct mixing and use of the product according to instructions.
R-1, S-2, F-0, C-0
Revision Date: 01/18/2005
Z17000000549/Version: 1.0
Print Date: 12/28/2005
1. Identification of the substance/preparation and of the company/undertaking
Product name: KODAK EKTACOLOR RA Developer Replenisher RT, Part A
Product code: 8477184 - Part A
Manufacturer: EASTMAN KODAK COMPANY, 343 State Street, Rochester, New York, 14650
Supplier: EASTMAN KODAK COMPANY, 343 State Street, Rochester, New York, 14650
For Emergency Health, Safety & Environmental Information, call (585) 722-5151 (USA)
For other information or to request an MSDS, call (800) 242-2424.
Synonyms: PCD 6076
2. Hazards identification
CONTAINS: Triethanolamine (102-71-6), N,N-diethylhydroxylamine (3710-84-7)
WARNING!
MAY CAUSE KIDNEY DAMAGE BASED ON ANIMAL DATA
MAY CAUSE LIVER DAMAGE BASED ON ANIMAL DATA
HARMFUL IF ABSORBED THROUGH SKIN OR SWALLOWE CAUSES SKIN AND EYE IRRITATION
MAY BE HARMFUL IF INHALE COMBUSTIBLE LIQUID AND VAPO HEAT SENSITIVE - CAN DECOMPOSE IF HEATE
HMIS II Hazard Ratings:
Health - 2*, Flammability - 2, Reactivity (Stability) - 1
NFPA Hazard Ratings:
Health - 2, Flammability - 2, Instability - 1
NOTE: HMIS II and NFPA hazard indexes involve data review and interpretation that may vary among
companies. They are intended only for rapid, general identification of the magnitude of the potential
hazards. An asterisk (*), in the HMIS II health field, designates potential chronic or target organ hazards.
To adequately address safe handling, ALL information in this MSDS must be considered.
3. Composition/information on ingredients
Weight % Components (CAS-No.)
60 - 65 Water (7732-18-5)
20 - 25 Triethanolamine (102-71-6)
10 - 15 N,N-diethylhydroxylamine (3710-84-7)
1- 5 Substituted stilbene (82640-05-9)
MATERIAL SAFETY DATA SHEET
Revision Date: 01/18/2005
Z17000000549/Version: 1.0
Print Date: 12/28/2005
<1 Lithium polystyrenesulphonate (9016-91-5)
4. First aid measures
Inhalation: If inhaled, move to fresh air. Treat symptomatically. Get medical attention.
Eyes: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical
attention.
Skin: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical attention if symptoms occur. Wash contaminated
clothing before reuse. Destroy or thoroughly clean contaminated shoes.
Ingestion: Only induce vomiting at the instruction of medical personnel. Never give anything by mouth to
an unconscious person. Call a physician or poison control center immediately.
5. Fire-fighting measures
Extinguishing Media: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special Fire-Fighting Procedures: Wear self-contained breathing apparatus and protective clothing.
Fire or excessive heat may produce hazardous decomposition products. Use water spray to cool
unopened containers.
Hazardous Combustion Products: Carbon oxides, nitrogen oxides (NOx), sulfur oxides
Unusual Fire and Explosion Hazards: Classified as combustible. Material contains a combustible
solvent that may accumulate in the container headspace. Elevated temperature can cause
decomposition.
6. Accidental release measures
Methods for cleaning up: Remove all sources of ignition. Flush into sewer with plenty of water.
Otherwise, absorb spill with vermiculite or other inert material, then place in a container for chemical
waste. Clean surface thoroughly to remove residual contamination.
7. Handling and storage
Personal precautions: Avoid breathing mist or vapour at concentrations greater than the exposure
limits. Avoid contact with eyes, skin, and clothing. Ensure adequate ventilation. Wash thoroughly after
handling.
Prevention of Fire and Explosion: Keep away from heat and sources of ignition. Ensure adequate
ventilation. Keep from contact with oxidizing materials.
Storage: Store in cool place. Keep container tightly closed. Keep away from incompatible substances
(see Incompatibility section.)
8. Exposure controls / personal protection
MATERIAL SAFETY DATA SHEET
Revision Date: 01/18/2005
Z17000000549/Version: 1.0
Print Date: 12/28/2005
Occupational exposure controls
Chemical Name Regulatory List Value Type Value
Triethanolamine ACGIH Time Weighted Average (TWA): 5 mg/m3
Ventilation: Good general ventilation should be used. Ventilation should be sufficient so that applicable
occupational exposure limits are not exceeded. Ventilation rates should be matched to conditions.
Supplementary local exhaust ventilation, closed systems, or respiratory protection may be needed in
special circumstances.
Respiratory protection: If engineering controls do not maintain airborne concentrations below
recommended exposure limits, an approved respirator must be worn. Respirator type: organic vapour. If
respirators are used, a program should be instituted to assure compliance with OSHA Standard 29CF 1910.134 and 29CFR1910.1048.
Eye protection: Wear safety glasses with side shields (or goggles).
Skin and body protection: Wear impervious gloves and protective clothing appropriate for the risk of
exposure.
Recommended Decontamination Facilities: Safety shower, eye wash, washing facilities as
appropriate to condition of use.
9. Physical and Chemical Properties
Physical form: liquid
Colour: yellow
Odour: amine
Specific gravity: 1.05
Vapour pressure (at 20.0 ??C (68.0 ??F)) : 24 mbar (18.0 mm Hg)
Vapor density (air = 1): 0.6
Volatile fraction by weight: 60 - 65 %
Boiling point/range: > 100.0 ??C (> 212.0 ??F)
Water solubility: complete
pH: 10.9
Flash point: 60.0 ??C (140.0 ??F) (Setaflash closed cup)
10. Stability and reactivity
MATERIAL SAFETY DATA SHEET
Revision Date: 01/18/2005
Z17000000549/Version: 1.0
Print Date: 12/28/2005
Stability: Safe handling temperatures are dependent on specific conditions of use and are typically
substantially below the onset temperature. Consult your technical safety experts.
Exotherm onset temperature: 169 ??C by DSC.
Incompatibility: Strong oxidizing agents.
Hazardous decomposition products: None under normal conditions of use.
Hazardous Polymerization: Hazardous polymerisation does not occur.
11. Toxicological information
Effects of Exposure
General advice:
Contains: Triethanolamine. Based on animal data, may cause adverse effects on the following
organs/systems: kidney, liver.
Inhalation: May be harmful if inhaled.
Eyes: Causes eye irritation.
Skin: Causes skin irritation. Harmful if absorbed through skin.
Ingestion: Harmful if swallowed.
12. Ecological information
The following properties are ESTIMATED from the components of the preparations.
Potential Toxicity:
Fish LC50: > 100 mg/l
Daphnid EC50: > 100 mg/l
Algal IC50: > 100 mg/l
Waste treatment organisms EC50: > 100 mg/l
Organics Readily Degradable: Readily biodegradable
Potential Bioaccumulation: log Pow < 1
COD (approximate): 760 g/l
BOD (approximate): 360 g/l
13. Disposal considerations
MATERIAL SAFETY DATA SHEET
Revision Date: 01/18/2005
Z17000000549/Version: 1.0
Print Date: 12/28/2005
Discharge, treatment, or disposal is subject to national, state, provincial, or municipal laws. Consult state
or local regulatory authorities before flushing to sewer with large amounts of water. Since emptied
containers retain product residue, follow label warnings even after container is emptied.
14. Transport information
Not regulated for all modes of transportation.
For transportation information regarding this product call the Kodak Worldwide Transportation Hazmat
Hot Line: (585) 722-2400 between 8 a.m. and 5 p.m. (Eastern Standard Time), Monday through Friday.
In Canada: General Shipping Information, call: (416) 766-8233.
15. Regulatory information
U.S. California Prop. 65: none
Carcinogenicity Classification (components present at 0.1% or more):
International Agency for Research on Cancer (IARC): Triethanolamine: 3 (not classifiable as to
carcinogenicity to humans)
American Conference of Governmental Industrial Hygienists (ACGIH): none
U.S. National Toxicology Program (NTP): none
U.S. Occupational Safety and Health Administration (OSHA): none
Chemical(s) subject to the reporting requirements of U.S. Section 313 or Title III of the Superfund
Amendments and Reauthorization Act (SARA) of 1986 and 40 CFR Part 372: none
16. Other information
US/Canadian Label Statements:
CONTAINS: Triethanolamine (102-71-6), N,N-diethylhydroxylamine (3710-84-7)
WARNING!
MAY CAUSE KIDNEY DAMAGE BASED ON ANIMAL DATA
MAY CAUSE LIVER DAMAGE BASED ON ANIMAL DATA
HARMFUL IF ABSORBED THROUGH SKIN OR SWALLOWE CAUSES SKIN AND EYE IRRITATION
MAY BE HARMFUL IF INHALE COMBUSTIBLE LIQUID AND VAPO HEAT SENSITIVE - CAN DECOMPOSE IF HEATE
Avoid breathing mist or vapour.
Avoid contact with eyes, skin, and clothing.
Ensure adequate ventilation.
Wash thoroughly after handling.
Store in cool place.
Keep away from heat and sources of ignition.
Keep container tightly closed.
MATERIAL SAFETY DATA SHEET
Revision Date: 01/18/2005
Z17000000549/Version: 1.0
Print Date: 12/28/2005
FIRST AID: If swallowed, only induce vomiting as directed by medical personnel. Never give
anything by mouth to an unconscious person. Call a physician or poison control center immediately. If
inhaled, move to fresh air. Treat symptomatically. In case of eye contact, immediately flush eyes with
plenty of water for at least 15 minutes. Get medical attention. In case of skin contact, immediately
flush with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Get medical attention if symptoms occur. Wash contaminated clothing before re-use. Destroy or
thoroughly clean contaminated shoes.
Keep out of reach of children.
For additional information, see Material Safety Data Sheet (MSDS) for this material.
Additional hazard precautions for containers greater than 1 gallon of liquid or 5 pounds of solid:
Since emptied containers retain product residue, follow label warnings even after container is
emptied.
IN CASE OF FIRE: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Use
water spray to cool unopened containers.
IN CASE OF SPILL: Remove all sources of ignition.
The information contained herein is furnished without warranty of any kind. Users should consider these
data only as a supplement to other information gathered by them and must make independent
determinations of suitability and completeness of information from all sources to assure proper use and
disposal of these materials and the safety and health of employees and customers and the protection of
the environment. The information relating to the working solution is for guidance purposes only, and is
based on correct mixing and use of the product according to instructions.
R-1, S-2, F-2, C-1HT
MATERIAL SAFETY DATA SHEET
Revision Date: 01/14/2005
Z17000000255/Version: 1.0
Print Date: 12/28/2005
1. Identification of the substance/preparation and of the company/undertaking
Product name: KODAK EKTACOLOR RA Developer Replenisher RT, Part B
Product code: 8477184 - Part B
Manufacturer: EASTMAN KODAK COMPANY, 343 State Street, Rochester, New York, 14650
Supplier: EASTMAN KODAK COMPANY, 343 State Street, Rochester, New York, 14650
For Emergency Health, Safety & Environmental Information, call (585) 722-5151 (USA)
For other information or to request an MSDS, call (800) 242-2424.
Synonyms: PCD 6157
2. Hazards identification
CONTAINS: 4-(N-ethyl-N-2-methanesulphonylaminoethyl)-2-methylphenylenediamine sesquisulphate
monohydrate (25646-71-3), Potassium sulphite (10117-38-1), Lithium sulphate (10377-48-7)
WARNING!
MAY CAUSE KIDNEY DAMAGE BASED ON ANIMAL DATA
HARMFUL IF SWALLOWE CAUSES SKIN AND EYE IRRITATION
MAY CAUSE ALLERGIC SKIN REACTION
THE TOXICOLOGICAL PROPERTIES OF THIS MATERIAL HAVE NOT BEEN FULLY INVESTIGATE
HMIS II Hazard Ratings:
Health - 2*, Flammability - 1, Reactivity (Stability) - 0
NFPA Hazard Ratings:
Health - 2, Flammability - 1, Instability - 0
NOTE: HMIS II and NFPA hazard indexes involve data review and interpretation that may vary among
companies. They are intended only for rapid, general identification of the magnitude of the potential
hazards. An asterisk (*), in the HMIS II health field, designates potential chronic or target organ hazards.
To adequately address safe handling, ALL information in this MSDS must be considered.
3. Composition/information on ingredients
Weight % Components (CAS-No.)
70 - 75 Water (7732-18-5)
15 - 20 4-(N-ethyl-N-2-methanesulphonylaminoethyl)-2-methylphenylenediamine
sesquisulphate monohydrate (25646-71-3)
5 - 10 Lithium sulphate (10377-48-7)
<1 Potassium sulphite (10117-38-1)
<1 Magnesium sulphate (7487-88-9)
MATERIAL SAFETY DATA SHEET
Revision Date: 01/14/2005
Z17000000255/Version: 1.0
Print Date: 12/28/2005
4. First aid measures
Inhalation: If symptomatic, move to fresh air. Treat symptomatically. Get medical attention if symptoms
occur.
Eyes: Immediately flush with plenty of water for at least 15 minutes. Get medical attention.
Skin: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical attention if symptoms occur. Wash contaminated
clothing before re-use. Destroy or thoroughly clean contaminated shoes.
Ingestion: Only induce vomiting at the instruction of medical personnel. Call a physician or poison
control center immediately. Never give anything by mouth to an unconscious person.
5. Fire-fighting measures
Extinguishing Media: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special Fire-Fighting Procedures: Wear self-contained breathing apparatus and protective clothing.
Fire or excessive heat may produce hazardous decomposition products.
Hazardous Combustion Products: Carbon oxides, nitrogen oxides (NOx), sulfur oxides
Unusual Fire and Explosion Hazards: None.
6. Accidental release measures
Methods for cleaning up: Absorb spill with vermiculite or other inert material, then place in a container
for chemical waste. Clean surface thoroughly to remove residual contamination.
7. Handling and storage
Personal precautions: Avoid breathing mist or vapour at concentrations greater than the exposure
limits. Do not get in eyes, on skin, or on clothing. Ensure adequate ventilation. Wash thoroughly after
handling.
Prevention of Fire and Explosion: Keep from contact with oxidizing materials.
Storage: Keep container tightly closed. Keep away from incompatible substances (see Incompatibility
section.)
8. Exposure controls / personal protection
Occupational exposure controls
Chemical Name Regulatory List Value Type Value
4-(N-ethyl-N-2- EK HPG Time Weighted Average (TWA): 1.0 mg/m3
methanesulphonylamin
oethyl)-2-
MATERIAL SAFETY DATA SHEET
Revision Date: 01/14/2005
Z17000000255/Version: 1.0
Print Date: 12/28/2005
methylphenylenediami
ne sesquisulphate
monohydrate
Ventilation: Good general ventilation should be used. Ventilation should be sufficient so that applicable
occupational exposure limits are not exceeded. Ventilation rates should be matched to conditions.
Supplementary local exhaust ventilation, closed systems, or respiratory protection may be needed in
special circumstances.
Respiratory protection: If engineering controls do not maintain airborne concentrations below
recommended exposure limits, an approved respirator must be worn. Respirator type: Acid gas. If
respirators are used, a program should be instituted to assure compliance with OSHA Standard 29CF 1910.134 and 29CFR1910.1048.
Eye protection: Wear safety glasses with side shields (or goggles).
Skin and body protection: Wear impervious gloves and protective clothing appropriate for the risk of
exposure.
Recommended Decontamination Facilities: Safety shower, eye wash, washing facilities as
appropriate to condition of use.
9. Physical and Chemical Properties
Physical form: liquid
Colour: tan
Odour: sharp sulphur dioxide
Specific gravity: 1.14
Vapour pressure (at 20.0 ??C (68.0 ??F)) : 24 mbar (18.0 mm Hg)
Vapor density (air = 1): 0.6
Volatile fraction by weight: 70 - 75 %
Boiling point/range: > 100.0 ??C (> 212.0 ??F)
Water solubility: complete
pH: 1.4
Flash point: > 93.3 ??C (> 200.0 ??F) (estimated)
10. Stability and reactivity
Stability: Stable
Incompatibility: strong oxidizing agents.
MATERIAL SAFETY DATA SHEET
Revision Date: 01/14/2005
Z17000000255/Version: 1.0
Print Date: 12/28/2005
Hazardous decomposition products: None under normal conditions of use.
Hazardous Polymerization: Hazardous polymerisation does not occur.
11. Toxicological information
Effects of Exposure
General advice:
Contains: 4-(N-ethyl-N-2-methanesulphonylaminoethyl)-2-methylphenylenediamine
sesquisulphate monohydrate. May cause kidney damage based on animal data.
Contains: Lithium sulphate. The toxicological properties of this material have not been fully
investigated and its handling and use may present additional hazards. This material is
pharmacologically active. Can cause CNS effects.
Inhalation: Expected to be a low hazard for recommended handling.
Eyes: Causes irritation.
Skin: Causes irritation. May cause allergic skin reaction.
Ingestion: Harmful if swallowed. May cause irritation of the gastrointestinal tract if swallowed. Some
asthmatics or sulfite-sensitive individuals may experience wheezing, chest tightness, stomach upset,
hives, faintness, weakness and diarrhea.
Data for 4-(N-ethyl-N-2-methanesulphonylaminoethyl)-2-methylphenylenediamine
sesquisulphate monohydrate:
Acute Toxicity Data:
?? Oral LD50 (male rat): 400 mg/kg (target organ effects: kidney)
?? Oral LD50 (female rat): 246 mg/kg
?? Dermal LD50: > 1,000 mg/kg (highest dose tested)
?? Skin irritation: slight
?? Skin irritation: moderate (repeated skin application)
?? Skin Sensitization: moderate
?? Skin Sensitization (human): positive
?? Eye irritation (unwashed eyes): Moderate eye irritation
?? Eye irritation (washed eyes): slight
Definitions for the following section(s): LOEL =lowest-observed-effect level, LOAEL = lowest-
observed-adverse-effect, NOAEL = no observed-adverse-effect level, NOEL =no-observed-effect
level.
Carcinogenicity:
?? Oral study (hamster, 2 years): NOEL; 0.04 % in diet (highest dose tested)
?? Dermal study (mouse, 2 years): NOEL; 62 mg/kg (only dose tested)
MATERIAL SAFETY DATA SHEET
Revision Date: 01/14/2005
Z17000000255/Version: 1.0
Print Date: 12/28/2005
12. Ecological information
Potential Toxicity:
Fish LC50: 1 - 10 mg/l
Daphnid EC50: 10 - 100 mg/l
Algal IC50: 10 - 100 mg/l
Waste treatment organisms EC50: > 100 mg/l
Organics Readily Degradable: Readily biodegradable
Potential Bioaccumulation: log Pow < 1
COD (approximate): 186 g/l
BOD (approximate): 22 g/l
13. Disposal considerations
Discharge, treatment, or disposal is subject to national, state, provincial, or municipal laws. Contract with
a licensed chemical disposal agency. Since emptied containers retain product residue, follow label
warnings even after container is emptied.
14. Transport information
The information given below is provided to assist in documentation. It may supplement the information on
the package. The package in your possession may carry a different version of the label depending on the
date of manufacture. Depending on inner packaging quantities and packaging instructions, it may be
subject to specific regulatory exceptions. Please consult the product packaging for further details.
UN Number: UN3265
US DOT:
Proper shipping name: Corrosive liquid, acidic, organic, n.o.s. (4-(N-ethyl-N-2-
methanesulphonylaminoethyl)-2-methylphenylenediamine
sesquisulphate monohydrate)
Class: 8
Packaging group: III
UN Number: UN3265
IMDG:
Proper shipping name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. (4-(N-
ethyl-N-2-methanesulphonylaminoethyl)-2-
methylphenylenediamine sesquisulphate monohydrate)
Class: 8
Packaging group: III
UN Number: UN3265
IATA:
Proper shipping name: Corrosive liquid, acidic, organic, n.o.s. (4-(N-ethyl-N-2-
methanesulphonylaminoethyl)-2-methylphenylenediamine
MATERIAL SAFETY DATA SHEET
Revision Date: 01/14/2005
Z17000000255/Version: 1.0
Print Date: 12/28/2005
sesquisulphate monohydrate)
Class: 8
Packaging group: III
For transportation information regarding this product call the Kodak Worldwide Transportation Hazmat
Hot Line: (585) 722-2400 between 8 a.m. and 5 p.m. (Eastern Standard Time), Monday through Friday.
In Canada: General Shipping Information, call: (416) 766-8233.
15. Regulatory information
U.S. California Prop. 65: none
Carcinogenicity Classification (components present at 0.1% or more):
International Agency for Research on Cancer (IARC): Potassium sulphite: 3 (not classifiable as to
carcinogenicity to humans)
American Conference of Governmental Industrial Hygienists (ACGIH): none
U.S. National Toxicology Program (NTP): none
U.S. Occupational Safety and Health Administration (OSHA): none
Chemical(s) subject to the reporting requirements of U.S. Section 313 or Title III of the Superfund
Amendments and Reauthorization Act (SARA) of 1986 and 40 CFR Part 372: none
16. Other information
US/Canadian Label Statements:
CONTAINS: 4-(N-ethyl-N-2-methanesulphonylaminoethyl)-2-methylphenylenediamine
sesquisulphate monohydrate (25646-71-3), Potassium sulphite (10117-38-1), Lithium sulphate
(10377-48-7)
WARNING!
MAY CAUSE KIDNEY DAMAGE BASED ON ANIMAL DATA
HARMFUL IF SWALLOWE CAUSES SKIN AND EYE IRRITATION
MAY CAUSE ALLERGIC SKIN REACTION
THE TOXICOLOGICAL PROPERTIES OF THIS MATERIAL HAVE NOT BEEN FULLY
INVESTIGATE
Avoid prolonged or repeated breathing of mist or vapour.
Do not get in eyes, on skin, or on clothing.
Keep container closed.
Ensure adequate ventilation.
Wash thoroughly after handling.
FIRST AID: If swallowed, only induce vomiting as directed by medical personnel. Never give
anything by mouth to an unconscious person. Call a physician or poison control center immediately.
In case of eye contact, immediately flush eyes with plenty of water for at least 15 minutes. Get
medical attention. In case of skin contact, immediately flush with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Get medical attention if symptoms occur.
Wash contaminated clothing before re-use. Destroy or thoroughly clean contaminated shoes.
Keep out of reach of children.
MATERIAL SAFETY DATA SHEET
Revision Date: 01/14/2005
Z17000000255/Version: 1.0
Print Date: 12/28/2005
For additional information, see Material Safety Data Sheet (MSDS) for this material.
Additional hazard precautions for containers greater than 1 gallon of liquid or 5 pounds of solid:
Since emptied containers retain product residue, follow label warnings even after container is
emptied.
IN CASE OF FIRE: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
The information contained herein is furnished without warranty of any kind. Users should consider these
data only as a supplement to other information gathered by them and must make independent
determinations of suitability and completeness of information from all sources to assure proper use and
disposal of these materials and the safety and health of employees and customers and the protection of
the environment. The information relating to the working solution is for guidance purposes only, and is
based on correct mixing and use of the product according to instructions.
R-1, S-3, F-1, C-0
MATERIAL SAFETY DATA SHEET
Revision Date: 01/19/2005
Z17000000551/Version: 1.0
Print Date: 12/28/2005
1. Identification of the substance/preparation and of the company/undertaking
Product name: KODAK EKTACOLOR RA Developer Replenisher RT, Part C
Product code: 8477184 - Part C
Manufacturer: EASTMAN KODAK COMPANY, 343 State Street, Rochester, New York, 14650
Supplier: EASTMAN KODAK COMPANY, 343 State Street, Rochester, New York, 14650
For Emergency Health, Safety & Environmental Information, call (585) 722-5151 (USA)
For other information or to request an MSDS, call (800) 242-2424.
Synonyms: PCD 6087
2. Hazards identification
CONTAINS: Potassium hydroxide (1310-58-3), Potassium carbonate (584-08-7)
DANGER!
CAUSES SEVERE EYE BURNS
DUST, MIST OR VAPOUR EXTREMELY IRRITATING TO THE EYES AND RESPIRATORY TRACT
HARMFUL IF SWALLOWE
HMIS II Hazard Ratings:
Health - 3, Flammability - 0, Reactivity (Stability) - 0
NFPA Hazard Ratings:
Health - 2, Flammability - 0, Instability - 0
NOTE: HMIS II and NFPA hazard indexes involve data review and interpretation that may vary among
companies. They are intended only for rapid, general identification of the magnitude of the potential
hazards. An asterisk (*), in the HMIS II health field, designates potential chronic or target organ hazards.
To adequately address safe handling, ALL information in this MSDS must be considered.
3. Composition/information on ingredients
Weight % Components (CAS-No.)
60 - 65 Water (7732-18-5)
30 - 35 Potassium carbonate (584-08-7)
1- 3 Potassium hydroxide (1310-58-3)
1- 5 Potassium chloride (7447-40-7)
<1 Substituted phosphonate (2809-21-4)
4. First aid measures
MATERIAL SAFETY DATA SHEET
Revision Date: 01/19/2005
Z17000000551/Version: 1.0
Print Date: 12/28/2005
Inhalation: Move to fresh air. Treat symptomatically. Get medical attention if symptoms occur.
Eyes: Rinse immediately with plenty of water for at least 15 minutes. Get medical attention immediately.
Skin: Wash off with soap and water. Get medical attention if symptoms occur.
Ingestion: Do NOT induce vomiting. Give victim a glass of water. Call a physician or poison control
center immediately. Never give anything by mouth to an unconscious person.
Notes to physician:
Treatment: Strong alkalis bind tissue protein. Following initial flushing of the eye with water,
continued irrigation of the eye with saline is recommended. Treatment should be continued until pH
of tears reaches neutral.
5. Fire-fighting measures
Extinguishing Media: Use extinguishing measures that are appropriate to local circumstances and the
surrounding environment.
Special Fire-Fighting Procedures: Wear self-contained breathing apparatus and protective clothing.
Hazardous Combustion Products: None (noncombustible)
Unusual Fire and Explosion Hazards: None.
6. Accidental release measures
Methods for cleaning up: Absorb spill with vermiculite or other inert material, then place in a container
for chemical waste. Clean surface thoroughly to remove residual contamination.
7. Handling and storage
Personal precautions: Avoid breathing mist or vapour at concentrations greater than the exposure
limits. Do not get in eyes and avoid contact with skin and clothing. Ensure adequate ventilation. Wash
thoroughly after handling.
Prevention of Fire and Explosion: No special technical protective measures required.
Storage: Keep container tightly closed. Keep away from incompatible substances (see Incompatibility
section.)
8. Exposure controls / personal protection
Occupational exposure controls
Chemical Name Regulatory List Value Type Value
Potassium hydroxide ACGIH Ceiling Limit Value: 2 mg/m3
Ventilation: Good general ventilation should be used. Ventilation should be sufficient so that applicable
MATERIAL SAFETY DATA SHEET
Revision Date: 01/19/2005
Z17000000551/Version: 1.0
Print Date: 12/28/2005
occupational exposure limits are not exceeded. Ventilation rates should be matched to conditions.
Supplementary local exhaust ventilation, closed systems, or respiratory protection may be needed in
special circumstances.
Respiratory protection: If engineering controls do not maintain airborne concentrations below
recommended exposure limits, an approved respirator must be worn. Respirator type: N95 Particulate
Filter. If respirators are used, a program should be instituted to assure compliance with OSHA Standard
29CFR 1910.134 and 29CFR1910.1048.
Eye protection: Wear safety glasses with side shields (or goggles) and a face shield.
Skin and body protection: It is a good industrial hygiene practice to minimize skin contact. Wear
impervious gloves and protective clothing appropriate for the risk of exposure.
Recommended Decontamination Facilities: Safety shower, eye wash, washing facilities as
appropriate to condition of use.
9. Physical and Chemical Properties
Physical form: liquid
Colour: colourless
Odour: odourless
Specific gravity: 1.37
Vapour pressure (at 20.0 ??C (68.0 ??F)) : 24 mbar (18.0 mm Hg)
Vapor density (air = 1): 0.6
Volatile fraction by weight: 60 - 65 %
Boiling point/range: > 100.0 ??C (> 212.0 ??F)
Water solubility: complete
pH: > 14
Flash point: none, noncombustible liquid
10. Stability and reactivity
Stability: Stable.
Incompatibility: Acids.
Hazardous decomposition products: None under normal conditions of use.
Hazardous Polymerization: Hazardous polymerisation does not occur.
MATERIAL SAFETY DATA SHEET
Revision Date: 01/19/2005
Z17000000551/Version: 1.0
Print Date: 12/28/2005
11. Toxicological information
Effects of Exposure
Inhalation: Airborne dust/mist/vapor extremely irritating.
Eyes: Causes eye burns. Airborne dust/mist/vapor extremely irritating.
Skin: Expected to be a low hazard for recommended handling.
Ingestion: Harmful if swallowed. May cause burns of the gastrointestinal tract if swallowed.
Acute Toxicity Data:
?? Skin irritation: none
?? Eye irritation: severe
12. Ecological information
The following properties are ESTIMATED from the components of the preparations.
Potential Toxicity:
Fish LC50: > 100 mg/l
Daphnid EC50: > 100 mg/l
Algal IC50: > 100 mg/l
Waste treatment organisms EC50: > 100 mg/l
Organics Readily Degradable: Not readily biodegradable.
Potential Bioaccumulation: log Pow < 1
COD (approximate): < 1 g/l
BOD (approximate): < 1 g/l
13. Disposal considerations
Discharge, treatment, or disposal is subject to national, state, provincial, or municipal laws. Contract with
a licensed chemical disposal agency. Since emptied containers retain product residue, follow label
warnings even after container is emptied.
14. Transport information
The information given below is provided to assist in documentation. It may supplement the information on
the package. The package in your possession may carry a different version of the label depending on the
date of manufacture. Depending on inner packaging quantities and packaging instructions, it may be
subject to specific regulatory exceptions. Please consult the product packaging for further details.
MATERIAL SAFETY DATA SHEET
Revision Date: 01/19/2005
Z17000000551/Version: 1.0
Print Date: 12/28/2005
UN Number: UN1814
US DOT:
Proper shipping name: Potassium hydroxide, solution
Class: 8
Packaging group: III
UN Number: UN1814
IMDG:
Proper shipping name: POTASSIUM HYDROXIDE SOLUTION
Class: 8
Packaging group: III
UN Number: UN1814
IATA:
Proper shipping name: Potassium hydroxide solution
Class: 8
Packaging group: III
For transportation information regarding this product call the Kodak Worldwide Transportation Hazmat
Hot Line: (585) 722-2400 between 8 a.m. and 5 p.m. (Eastern Standard Time), Monday through Friday.
In Canada: General Shipping Information, call: (416) 766-8233.
15. Regulatory information
U.S. California Prop. 65: none
Carcinogenicity Classification (components present at 0.1% or more):
International Agency for Research on Cancer (IARC): none
American Conference of Governmental Industrial Hygienists (ACGIH): none
U.S. National Toxicology Program (NTP): none
U.S. Occupational Safety and Health Administration (OSHA): none
Chemical(s) subject to the reporting requirements of U.S. Section 313 or Title III of the Superfund
Amendments and Reauthorization Act (SARA) of 1986 and 40 CFR Part 372: none
16. Other information
US/Canadian Label Statements:
CONTAINS: Potassium hydroxide (1310-58-3), Potassium carbonate (584-08-7)
DANGER!
CAUSES SEVERE EYE BURNS
DUST, MIST OR VAPOUR EXTREMELY IRRITATING TO THE EYES AND RESPIRATORY TRACT
HARMFUL IF SWALLOWE
Do not get in eyes and avoid contact with skin and clothing.
Avoid breathing mist or vapour.
Ensure adequate ventilation.
Wash thoroughly after handling.
FIRST AID: If inhaled, move to fresh air. Treat symptomatically. Get medical attention if symptoms
occur. If swallowed, do NOT induce vomiting. Give victim a glass of water. Never give anything by
mouth to an unconscious person. Call a physician or poison control center immediately. In case of
MATERIAL SAFETY DATA SHEET
Revision Date: 01/19/2005
Z17000000551/Version: 1.0
Print Date: 12/28/2005
eye contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention
immediately.
Notes to physician: Strong alkalis bind tissue protein. Following initial flushing of the eye with water,
continued irrigation of the eye with saline is recommended. Treatment should be continued until pH of
tears reaches neutral.
Keep out of reach of children.
Do not handle or use until safety precautions in Material Safety Data Sheet (MSDS) have been read
and understood.
Additional hazard precautions for containers greater than 1 gallon of liquid or 5 pounds of solid:
Since emptied containers retain product residue, follow label warnings even after container is
emptied.
The information contained herein is furnished without warranty of any kind. Users should consider these
data only as a supplement to other information gathered by them and must make independent
determinations of suitability and completeness of information from all sources to assure proper use and
disposal of these materials and the safety and health of employees and customers and the protection of
the environment. The information relating to the working solution is for guidance purposes only, and is
based on correct mixing and use of the product according to instructions.
R-1, S-3, F-0, C-0
MATERIAL SAFETY DATA SHEET
Revision Date: 01/19/2005
000000012235/Version: 1.0
Print Date: 12/28/2005
1. Identification of the substance/preparation and of the company/undertaking
Product name: KODAK EKTACOLOR RA Developer Replenisher RT, Working solution
Product code: 8477184 - Working solution
Manufacturer: EASTMAN KODAK COMPANY, 343 State Street, Rochester, New York, 14650
Supplier: EASTMAN KODAK COMPANY, 343 State Street, Rochester, New York, 14650
For Emergency Health, Safety & Environmental Information, call (585) 722-5151 (USA)
For other information or to request an MSDS, call (800) 242-2424.
Synonyms: None.
2. Hazards identification
CONTAINS: 4-(N-ethyl-N-2-methanesulphonylaminoethyl)-2-methylphenylenediamine sesquisulphate
monohydrate (25646-71-3), Potassium hydroxide (1310-58-3), Triethanolamine (102-71-6)
WARNING!
MAY CAUSE LIVER DAMAGE BASED ON ANIMAL DATA
MAY CAUSE KIDNEY DAMAGE BASED ON ANIMAL DATA
HARMFUL IF SWALLOWE MAY BE HARMFUL IF ABSORBED THROUGH SKIN
MAY BE HARMFUL IF INHALE CAUSES SKIN AND EYE IRRITATION
MAY CAUSE ALLERGIC SKIN REACTION
HMIS II Hazard Ratings:
Health - 2*, Flammability - 0, Reactivity (Stability) - 0
NFPA Hazard Ratings:
Health - 1, Flammability - 0, Instability - 0
NOTE: HMIS II and NFPA hazard indexes involve data review and interpretation that may vary among
companies. They are intended only for rapid, general identification of the magnitude of the potential
hazards. An asterisk (*), in the HMIS II health field, designates potential chronic or target organ hazards.
To adequately address safe handling, ALL information in this MSDS must be considered.
3. Composition/information on ingredients
Weight % Components (CAS-No.)
90 - 95 Water (7732-18-5)
1- 5 Potassium carbonate (584-08-7)
1- 5 Triethanolamine (102-71-6)
<1 4-(N-ethyl-N-2-methanesulphonylaminoethyl)-2-methylphenylenediamine
MATERIAL SAFETY DATA SHEET
Revision Date: 01/19/2005
000000012235/Version: 1.0
Print Date: 12/28/2005
sesquisulphate monohydrate (25646-71-3)
<1 N,N-diethylhydroxylamine (3710-84-7)
< 0.5 Potassium hydroxide (1310-58-3)
4. First aid measures
Inhalation: If inhaled, move to fresh air. Treat symptomatically. Get medical attention.
Eyes: Immediately flush with plenty of water for at least 15 minutes. Get medical attention.
Skin: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical attention if symptoms occur. Wash contaminated
clothing before reuse. Destroy or thoroughly clean contaminated shoes.
Ingestion: Only induce vomiting at the instruction of medical personnel. Call a physician or poison
control center immediately. Never give anything by mouth to an unconscious person.
5. Fire-fighting measures
Extinguishing Media: Use extinguishing measures that are appropriate to local circumstances and the
surrounding environment.
Special Fire-Fighting Procedures: None (noncombustible)
Hazardous Combustion Products: None (noncombustible)
Unusual Fire and Explosion Hazards: None.
6. Accidental release measures
Methods for cleaning up: Flush into sewer with plenty of water. Otherwise, absorb spill with vermiculite
or other inert material, then place in a container for chemical waste. Clean surface thoroughly to remove
residual contamination.
7. Handling and storage
Personal precautions: Avoid breathing mist or vapour at concentrations greater than the exposure
limits. Avoid contact with eyes, skin, and clothing. Ensure adequate ventilation. Wash thoroughly after
handling.
Prevention of Fire and Explosion: No special technical protective measures required.
Storage: Keep container tightly closed.
8. Exposure controls / personal protection
Occupational exposure controls
MATERIAL SAFETY DATA SHEET
Revision Date: 01/19/2005
000000012235/Version: 1.0
Print Date: 12/28/2005
Chemical Name Regulatory List Value Type Value
Potassium hydroxide ACGIH Ceiling Limit Value: 2 mg/m3
Triethanolamine ACGIH Time Weighted Average (TWA): 5 mg/m3
4-(N-ethyl-N-2- EK HPG Time Weighted Average (TWA): 1.0 mg/m3
methanesulphonylamin
oethyl)-2-
methylphenylenediami
ne sesquisulphate
monohydrate
Ventilation: Good general ventilation should be used. Ventilation should be sufficient so that applicable
occupational exposure limits are not exceeded. Ventilation rates should be matched to conditions.
Supplementary local exhaust ventilation, closed systems, or respiratory protection may be needed in
special circumstances.
Respiratory protection: If engineering controls do not maintain airborne concentrations below
recommended exposure limits, an approved respirator must be worn. Respirator type: organic vapour. If
respirators are used, a program should be instituted to assure compliance with OSHA Standard 29CF 1910.134 and 29CFR1910.1048.
Eye protection: Wear safety glasses with side shields (or goggles).
Skin and body protection: Wear impervious gloves and protective clothing appropriate for the risk of
exposure.
Recommended Decontamination Facilities: Safety shower, eye wash, washing facilities as
appropriate to condition of use.
9. Physical and Chemical Properties
Physical form: liquid
Colour: light yellow
Odour: strong amine
Specific gravity: 1.03
Vapour pressure: 24 mbar (18.0 mm Hg)
Vapor density (air = 1): 0.6
Volatile fraction by weight: 90 - 95 %
Boiling point/range: > 100.0 ??C (> 212.0 ??F)
Water solubility: complete
pH: 10.7 - 10.8
Flash point: none, noncombustible liquid
MATERIAL SAFETY DATA SHEET
Revision Date: 01/19/2005
000000012235/Version: 1.0
Print Date: 12/28/2005
10. Stability and reactivity
Stability: Stable
Incompatibility: None with common materials and contaminants with which the material may reasonably
come into contact.
Hazardous decomposition products: None under normal conditions of use.
Hazardous Polymerization: Hazardous polymerisation does not occur.
11. Toxicological information
Effects of Exposure
General advice:
Contains: Triethanolamine. Based on animal data, may cause adverse effects on the following
organs/systems: kidney, liver.
Inhalation: May be harmful if inhaled.
Eyes: Causes irritation.
Skin: Causes irritation. May cause allergic skin reaction. May be harmful if absorbed through skin.
Ingestion: Harmful if swallowed. May cause irritation of the gastrointestinal tract if swallowed.
12. Ecological information
The following properties are ESTIMATED from the components of the preparations.
Potential Toxicity:
Fish LC50: > 100 mg/l
Daphnid EC50: > 100 mg/l
Algal IC50: > 100 mg/l
Waste treatment organisms EC50: > 100 mg/l
Organics Readily Degradable: Readily biodegradable
Potential Bioaccumulation: log Pow < 1
COD (approximate): 40 g/l
BOD (approximate): 19 g/l
MATERIAL SAFETY DATA SHEET
Revision Date: 01/19/2005
000000012235/Version: 1.0
Print Date: 12/28/2005
13. Disposal considerations
Discharge, treatment, or disposal may be subject to national, state, or local laws. Consult state or local
regulatory authorities before flushing to sewer with large amounts of water. Since emptied containers
retain product residue, follow label warnings even after container is emptied.
14. Transport information
For transportation information regarding this product call the Kodak Worldwide Transportation Hazmat
Hot Line: (585) 722-2400 between 8 a.m. and 5 p.m. (Eastern Standard Time), Monday through Friday.
In Canada: General Shipping Information, call: (416) 766-8233.
15. Regulatory information
U.S. California Prop. 65: none
Carcinogenicity Classification (components present at 0.1% or more):
International Agency for Research on Cancer (IARC): Triethanolamine: 3 (not classifiable as to
carcinogenicity to humans)
American Conference of Governmental Industrial Hygienists (ACGIH): none
U.S. National Toxicology Program (NTP): none
U.S. Occupational Safety and Health Administration (OSHA): none
Chemical(s) subject to the reporting requirements of U.S. Section 313 or Title III of the Superfund
Amendments and Reauthorization Act (SARA) of 1986 and 40 CFR Part 372: none
16. Other information
US/Canadian Label Statements:
CONTAINS: 4-(N-ethyl-N-2-methanesulphonylaminoethyl)-2-methylphenylenediamine
sesquisulphate monohydrate (25646-71-3), Potassium hydroxide (1310-58-3), Triethanolamine
(102-71-6)
WARNING!
MAY CAUSE LIVER DAMAGE BASED ON ANIMAL DATA
MAY CAUSE KIDNEY DAMAGE BASED ON ANIMAL DATA
HARMFUL IF SWALLOWE MAY BE HARMFUL IF ABSORBED THROUGH SKIN
MAY BE HARMFUL IF INHALE CAUSES SKIN AND EYE IRRITATION
MAY CAUSE ALLERGIC SKIN REACTION
Avoid prolonged or repeated breathing of mist or vapour.
Avoid contact with eyes, skin, and clothing.
Use with adequate ventilation.
Wash thoroughly after handling.
FIRST AID: If swallowed, only induce vomiting as directed by medical personnel. Never give
anything by mouth to an unconscious person. Call a physician or poison control center immediately. If
MATERIAL SAFETY DATA SHEET
Revision Date: 01/19/2005
000000012235/Version: 1.0
Print Date: 12/28/2005
inhaled, move to fresh air. Treat symptomatically. In case of eye contact, immediately flush eyes with
plenty of water for at least 15 minutes. Get medical attention. In case of skin contact, immediately
flush with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Get medical attention if symptoms occur. Wash contaminated clothing before re-use. Destroy or
thoroughly clean contaminated shoes.
Keep out of reach of children.
For additional information, see Material Safety Data Sheet (MSDS) for this material.
Additional hazard precautions for containers greater than 1 gallon of liquid or 5 pounds of solid:
Since emptied containers retain product residue, follow label warnings even after container is
emptied.
The information contained herein is furnished without warranty of any kind. Users should consider these
data only as a supplement to other information gathered by them and must make independent
determinations of suitability and completeness of information from all sources to assure proper use and
disposal of these materials and the safety and health of employees and customers and the protection of
the environment. The information relating to the working solution is for guidance purposes only, and is
based on correct mixing and use of the product according to instructions.
R-1, S-2, F-0, C-0
POLYSTYRENE SULFONATE, LITHIUM SALT
China (Mainland)] 
Assessed
Assessed
Assessed