PRIDE PLUS ADVANTAGE 10/30
MATERIAL SAFETY DATA SHEET FOR USA AN CANADA



SECTION 1: PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME: Pride Plus Advantage Engine Oil
Includes grades 5W-30, 10W-30, 10W-40, 15W-40, 20W-20, 20W-50, 10W, 20W, 30
AND 40.

SYNONYMS: Petroleum oil; Lube oil; Petroleum hydrocarbon; Lubricant.

PRODUCT CODE: Prefix 21

For lubricating passenger car motors.
If these products are used in combination with other products, refer to the Material
PRODUCT USE:
Safety Data Sheet for those products.


24-HOUR EMERGENCY PHONE NUMBERS
These numbers are for emergency use MEDICAL: TRANSPORTATION (SPILL):
only. If you desire non-emergency
product information, please call a 1-800-537-7433 1-800-537-7433
phone number listed below.


SUPPLIER: Hutchens Petroleum
22 Performance Drive
Stuart, VA 24171
www.hutchenspetro.com
1-276-694-7000

TECHNICAL INFORMATION: 1-276-694-7000

MSDS FORM NUMBER: 82479 ISSUE: March 4, 2005
ORIGINAL ISSUE: October 31, 1998 SUPERSEDES: April 4, 2003
PREPARED BY: Product MSDS Coordinator APPROVED BY: MSDS Task Force




1
 SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS

OSHA PEL** ACGIH TLV?
LDa LCb
STEL
WT%* NAME SYNONYM CAS NO. TWA STEL TWA
Mg/m3 Mg/m3 G/kg
Mg/m3
c c c
35-93 Lubricating oils, Hydrotreated 64742-58-1 N. Av. N. Av. N. Av.
5 5 10
petroleum, paraffinic base oil
hydrotreated
spent
c c c
0-60 Lubricating oils, N. Av. 72623-87-1 N. Av. N. Av. N. Av.
5 5 10
petroleum, C20-
50, hydrotreated
neutral oil-based
c c c
4-42 Petroleum N. Av. 64742-54-7 N. Av. >15 g/kg N. Av.
5 5 10 d
distillates,
(>5 g/kg)
hydrotreated
heavy paraffinic
c c c
0-30 Lubricating oils Bright stock 72623-83-7 N. Av. >5 g/kg N. Av.
5 5 10 d
(petroleum),
(>3 g/kg)
C>25,
hydrotreated
bright stock
c c c
0-30 Residual oils Bright stock 64742-62-7 N. Av. N. Av. N. Av.
5 5 10
(petroleum),
solvent dewaxed
c c c
0-30 Residual oils Bright stock 64742-57-0 N. Av. N. Av. N. Av.
5 5 10
(petroleum),
hydrotreated
c c c
0-30 Lubricating oils, N. Av. 72623-86-0 N. Av. N. Av. N. Av.
5 5 10
petroleum, C15-
30, hydrotreated
neutral oil-based
0-12 Polyolefin *** *** N. Av. N. Av. N. Av. N. Av. N. Av. N. Av.
1-10 Polyolefin *** *** N. Av. N. Av. N. Av. N. Av. N. Av. N. Av.
amide
alkeneamine
c c c
0-9 Mineral oil *** *** N. Av. N. Av. N. Av.
5 5 10
c c c
0-7 Petroleum N. Av. 64741-88-4 N. Av. N. Av. N. Av.
5 5 10
distillates,
solvent-refined
heavy paraffinic
0.5-6 Phosphorodithio Dialkyl (C1-C14) 68649-42-3 N. Av. N. Av. N. Av. N. Av. N. Av. N. Av.
ic acid, O,O-di- dithiophosphoric
C1-14-alkyl acid, zinc salt
esters, zinc salts
0.5-4 Calcium *** *** N. Av. N. Av. N. Av. N. Av. N. Av. N. Av.
sulfonate
0.5-2 Alkylamine *** *** N. Av. N. Av. N. Av. N. Av. N. Av. N. Av.
0-2 Polyolefin ester *** *** N. Av. N. Av. N. Av. N. Av. N. Av. N. Av.
0.5-3 Alkylated *** *** N. Av. N. Av. N. Av. N. Av. N. Av. N. Av.
phenol
0-2 Calcium phenate *** *** N. Av N. Av N. Av N. Av N. Av N. Av

**OSHA Final PEL value (enforceable). Some States have adopted more stringent values.
c
N. Av. = Not Available ***Supplier advises that this is a trade secret Based on Oil mist, mineral
a d
Oral-Rat LD50 Skin-Rabbit LD50
b
* Even though the concentration range does not fall under the ranges prescribed by Inhalation-Rat LC50
WHMIS, this is the actual range which varies with each batch of the product.




2
 SECTION 3: HAZARDS IDENTIFICATION


EMERGENCY OVERVIEW
APPEARANCE
Liquid, amber, petroleum odor.

CAUTION!

HEALTH HAZARDS
May be harmful if swallowed.
May irritate the respiratory tract (nose, throat, and lungs), eyes, and skin.

POTENTIAL HEALTH EFFECTS

These products are not likely to present an inhalation hazard at normal temperatures and
INHALATION
pressures. However, when aerosolizing, misting, or heating these products, high
(BREATHING):
concentrations of generated vapor or mist may irritate the respiratory tract (nose, throat,
and lungs).

May cause irritation.
EYES:
May cause irritation. Not likely to be absorbed through the skin in harmful amounts.
SKIN:



May be harmful if swallowed. May cause throat irritation, nausea, vomiting, and diarrhea.
INGESTION
Breathing product into the lungs during ingestion or vomiting may cause lung injury and
(SWALLOWING):
possible death.

Individuals with pre-existing respiratory tract (nose, throat, and lungs), eye, and/or skin
MEDICAL
disorders may have increased susceptibility to the effects of exposure.
CONDITIONS
AGGRAVATED BY
EXPOSURE:
Prolonged or repeated inhalation of oil mist may cause oil pneumonia, lung tissue
CHRONIC:
inflammation, and/or fibrous tissue formation. Prolonged or repeated eye contact may
cause inflammation of the membrane lining the eyelids and covering the eyeball
(conjunctivitis). Prolonged or repeated skin contact may cause drying, cracking, redness,
itching, and/or swelling (dermatitis).

No known carcinogenicity. For more information, see SECTION 11:
CANCE CARCINOGENICITY.
INFORMATION:
Also see SECTION 15: CALIFORNIA.

POTENTIAL ENVIRONMENTAL EFFECTS

Not available. Also see SECTION 12: ECOLOGICAL INFORMATION.

SECTION 4: FIRST AID MEASURES

Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult,
INHALATION
give oxygen. Oxygen should only be administered by qualified personnel. Someone
(BREATHING):
should stay with victim. Get medical attention if breathing difficulty persists.
If irritation or redness from exposure to vapor develops, move away from exposure into
EYES:
fresh air. Upon contact, immediately flush eyes with plenty of lukewarm water, holding
eyelids apart, for 15 minutes. Get medical attention.



3
 Remove affected clothing and shoes. Wash skin thoroughly with soap and water. Get
SKIN:
medical attention if irritation or pain develops or persists. If product is injected under
pressure into or under the skin, or into any part of the body, regardless of the appearance
of the wound or its size, a physician should immediately evaluate the individual as a
medical emergency.
Do NOT induce vomiting. Immediately get medical attention. Call 1-800-752-7869 for
INGESTION
additional information. If spontaneous vomiting occurs, keep head below hips to avoid
(SWALLOWING):
breathing the product into the lungs. Never give anything by mouth to an unconscious
person.
Treat symptomatically and supportively. Treatment may vary with condition of victim
NOTE TO
and specifics of incident. Call 1-800-752-7869 for additional information.
PHYSICIANS:

SECTION 5: FIRE FIGHTING MEASURES

383oF (195oC) (minimum) Cleveland Open Cup
FLASH POINT:
LOWER: Not available UPPER: Not available
FLAMMABLE
LIMITS IN AIR:
Not available
AUTOIGNITION
TEMPERATURE:
Decomposition and combustion materials may be toxic. Burning may produce aldehydes,
HAZARDOUS
hydrogen sulfide, alkyl mercaptans, sulfides, carbon monoxide, oxides of sulfur, calcium
COMBUSTION
and zinc and other unidentified organic compounds.
PRODUCTS:


Heat, sparks, or flame. Product may burn, but does not ignite readily.
CONDITIONS OF
FLAMMABILITY:
Carbon dioxide, regular foam, dry chemical, water spray, or water fog. Water or foam may
EXTINGUISHING
cause frothing.
MEDIA:
NFPA 704
This information is intended solely for the use by individuals trained in this system.
HAZAR IDENTIFICATION:
Health Hazard (Blue) 1 Fire Hazard (Red) 1

Specific Hazard (White) Reactivity (Yellow) 0


Keep storage containers cool with water spray. A positive-pressure, self-contained
FIRE FIGHTING
breathing apparatus (SCBA) and full-body protective equipment are required for fire
INSTRUCTIONS:
emergencies.
Heated containers may rupture. "Empty" containers may retain residue and can be
FIRE AN dangerous. Products are not sensitive to mechanical impact or static discharge.
EXPLOSION
HAZARDS:


SECTION 6: ACCIDENTAL RELEASE MEASURES

Remove all ignition sources. Do not touch or walk through spilled product. Stop leak if you can do it without risk.
Wear protective equipment and provide engineering controls as specified in SECTION 8: EXPOSURE
CONTROLS/PERSONAL PROTECTION. Isolate hazard area. Keep unnecessary and unprotected personnel from
entering. Ventilate area and avoid breathing vapor or mist. Contain spill away from surface water and sewers.
Contain spill as a liquid for possible recovery, or sorb with compatible sorbent material and shovel with a clean,
sparkproof tool into a sealable container for disposal. Additionally, for large spills: Dike far ahead of liquid spill for
collection and later disposal.




4
 SECTION 7: HANDLING AND STORAGE
Keep away from sparks or flame. Where flammable mixtures may be present, equipment safe
HANDLING:
for such locations should be used. Use clean tools. When transferring large volumes of product,
metal containers, including trucks and tank cars, should be grounded and bonded. These
products have a low vapor pressure and are not expected to present an inhalation hazard under
normal temperatures and pressures. However, when aerosolizing, misting, or heating these
products, do not breathe vapor or mist. Use in a well ventilated area. Avoid contact with eyes,
skin, clothing, and shoes.

Keep container tightly closed when not in use and during transport. Store containers in a cool,
SHIPPING AN dry place. Do not pressurize, cut, weld, braze, solder, drill, or grind containers. Keep containers
STORING:
away from flame, sparks, static electricity, or other sources of ignition. Empty product
containers may retain product residue and can be dangerous.


SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

Provide general ventilation needed to maintain concentration of vapor or mist below applicable
ENGINEERING
exposure limits. Where adequate general ventilation is unavailable, use process enclosures, local
CONTROLS:
exhaust ventilation, or other engineering controls to control airborne levels below applicable
exposure limits.

PERSONAL PROTECTIVE EQUIPMENT
RESPIRATORY No respiratory protection is normally required. Use NIOSH-certified P- or R- series
PROTECTION: particulate filter and organic vapor cartridges when concentration of vapor or mist exceeds
applicable exposure limits. Protection provided by air purifying respirators is limited. Do not
use N-rated respirators. Selection and use of respiratory protective equipment should be in
accordance in the USA with OSHA General Industry Standard 29 CFR 1910.134; or in
Canada with CSA Standard Z94.4.
Where eye contact is likely, wear safety glasses; contact lens use is not recommended.
EYE
PROTECTION:


Where skin contact is likely, wear neoprene, nitrile, or equivalent protective gloves; use of
SKIN
natural rubber or equivalent gloves is not recommended.
PROTECTION:
When products are heated and skin contact is likely, wear heat-resistant gloves, boots, and
other protective clothing.
To avoid prolonged or repeated contact where spills and splashes are likely, wear appropriate
chemical-resistant faceshield, boots, apron, coveralls, long sleeve shirts, or other protective
clothing.
Use good personal hygiene. Wash thoroughly with soap and water after handling product and
PERSONAL
before eating, drinking, or using tobacco products. Clean affected clothing, shoes, and
HYGIENE:
protective equipment before reuse. Discard leather articles, such as shoes, saturated with these
products.

Where spills and splashes are likely, facilities storing or using these products should be
OTHE equipped with an emergency eyewash and shower, both equipped with clean water, in the
PROTECTIVE
immediate work area.
EQUIPMENT:


SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

Liquid, amber, petroleum odor.
PHYSICAL STATE,
APPEARANCE, AND ODOR:
Not available
ODOR THRESHOLD:
Not applicable
MOLECULAR WEIGHT:
0.88 (water = 1) (approximately)
SPECIFIC GRAVITY:

5
 7.3 LB/US gal (880 g/l) (approximately)
DENSITY:
Not available
VAPOR DENSITY:
less than 0.1 mmHg at 68oF (20oC)
VAPOR PRESSURE:
475oF (246oC) (minimum)
BOILING POINT:
Not available [pour point 0oF (-18oC) (maximum)].
FREEZING/MELTING POINT:
Not applicable
pH:
Not available
EVAPORATION RATE:
Insoluble
SOLUBILITY IN WATER:
383oF (195oC) minimum Cleveland Open Cup
FLASH POINT:
LOWER: Not available UPPER: Not available
FLAMMABLE LIMITS IN AIR:
Not available
AUTOIGNITION TEMPERATURE:

SECTION 10: STABILITY AND REACTIVITY

Stable under normal temperatures and pressures. Avoid sparks or flame when not in
STABILITY:
use.
Avoid oxidizing agents, acids and reactive halogens.
INCOMPATIBILITY:
Polymerization is not known to occur under normal temperature and pressures. Not
REACTIVITY:
reactive with water.
None under normal temperatures and pressures. See also SECTION 5: HAZARDOUS
HAZARDOUS
COMBUSTION PRODUCTS.
DECOMPOSITION
PRODUCTS:


SECTION 11: TOXICOLOGICAL INFORMATION

Based on best current information, there is no known human sensitization associated
SENSITIZATION:
with these products.
Experimental evidence suggests that these products do not cause mutagenesis.
MUTAGENICITY:

Based on best current information, there is no known carcinogenicity as categorized
CARCINOGENICITY:
by ACGIH A1 or A2 substances; as categorized by IARC Group 1, Group 2A, or
Group 2B agents; or as listed by NTP as either known carcinogens or substances for
which there is limited evidence of carcinogenicity in humans or sufficient evidence
of carcinogenicity in experimental animals.
Also see SECTION 15: CALIFORNIA.

Based on best current information, there is no known reproductive toxicity associated
REPRODUCTIVE
with these products.
TOXICITY:
Also see SECTION 15: CALIFORNIA.
Based on best current information, there is no known teratogenicity associated with
TERATOGENICITY:
these products.
Based on best current information, there are no known toxicologically synergistic
TOXICOLOGICALLY
products associated with these products.
SYNERGISTIC
PRODUCT(S):


SECTION 12: ECOLOGICAL INFORMATION

Not available.
ECOTOXICITY:

6
 Not available
OCTANOL/WATE PARTITION
COEFFICIENT:
100 WT%; 7.3 LB/US gal; 880 g/l (approximately)
VOLATILE ORGANIC
As per 40 CFR Part 51.100(s).
COMPOUNDS:

SECTION 13: DISPOSAL CONSIDERATIONS

Dispose in accordance with federal, state, provincial, and local regulations. Regulations may
DISPOSAL:
also apply to empty containers. The responsibility for proper waste disposal lies with the
owner of the waste. Contact Hutchens Petroleum regarding proper recycling or disposal.
These products, if discarded, are not expected to be a characteristic or listed hazardous waste.
USEPA WASTE
If recycled in the USA, they must be managed in accordance with 40 CFR Part 279.
CODE(S):
Processing, use, or contamination by the user may change the waste code(s) applicable to the
disposal of these products.


SECTION 14: TRANSPORT INFORMATION

Not regulated
DOT:
Not regulated
TDG:
Not applicable.
EMERGENCY RESPONSE GUIDE NUMBER:
Reference North American Emergency Response Guidebook


SECTION 15: REGULATORY INFORMATION

USA REGULATIONS
SARA SECTIONS Based on the ingredient(s) listed in SECTION 2, these products do not contain any
"extremely hazardous substances" listed pursuant to Title III of the Superfund Amendments
302 AND 304:
and Reauthorization Act of 1986 (SARA) Section 302 or Section 304 as identified in 40
CFR Part 355, Appendix A and B.

These products pose the following health hazard(s) as defined in 40 CFR Part 370 and are
SARA SECTIONS
subject to the requirements of sections 311 and 312 of Title III of the Superfund
311 AND 312:
Amendments and Reauthorization Act of 1986 (SARA):
Immediate (Acute) Health Hazard
Delayed (Chronic) Health Hazard
These products contain "toxic" chemical(s) subject to the requirements of section 313 of
SARA SECTION
Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA) and 40
313:
CFR Part 372.
Material CAS
Phosphorodithioic acid, O,O-di-C1-14-alkyl esters, 68649-42-3
zinc salts (related to zinc compounds)
Based on the ingredient(s) listed in SECTION 2, this product does not contain any
CERCLA:
"hazardous substances" listed under the Comprehensive Environmental Response,
Compensation and Liability Act of 1980 (CERCLA) in 40 CFR Part 302, Table 302.4.

All the components of these products are listed on, or are automatically included as
TSCA:
"naturally occurring chemical substances" on, or are exempted from the requirement to be
listed on, the TSCA Inventory.




7
 These products may contain a detectable amount of arsenic CAS 7440-38-2, benzene CAS
CALIFORNIA:
71-43-2, cadmium CAS 7440-43-9 and lead CAS 7439-92-1 from additives. These products
may contain a detectable amount of benzo(a)anthracene CAS 56-55-3,
benzo(b)fluoranthene CAS 205-99-2, benzo(k)fluoranthene CAS 207-08-9, benzo(a)pyrene
CAS 50-32-8, chrysene CAS 218-01-9, dibenz(a,h)anthracene CAS 53-70-3 and
indeno(1,2,3-cd)pyrene CAS 193-39-5. WARNING: These chemicals are known to the
State of California to cause cancer. Our testing of these products indicates that these
chemicals are not always detectable.


These products may contain a detectable amount of arsenic CAS 7440-38-2, benzene CAS 71-43-2, cadmium CAS
7440-43-9 and lead CAS 7439-92-1from additives. WARNING: These chemicals are known to the State of
California to cause birth defects or other reproductive harm.



CANADIAN REGULATIONS
These products have been classified in accordance with the hazard criteria of the Controlled Products Regulations
(CPR) and the MSDS contains all information required by the CPR.
Not regulated
WHMIS:
All the components of these products are listed on, or are automatically included as
CANADIAN
"substance occurring in nature" on, or are exempted from the requirements to be
ENVIRONMENTAL
listed on, the Canadian Domestic Substances List (DSL).
PROTECTION ACT
(CEPA):


SECTION 16. OTHER INFORMATION

New formulation
REVISION INFORMATION:
Not available
LABEL/OTHER INFORMATION:

User assumes all risks incident to the use of this (these) product(s). To the best of our knowledge, the information contained herein is accurate.
However, Hutchens Petroleum assumes no liability whatsoever for the accuracy or completeness of the information contained herein. No
representations or warranties, either express or implied, or merchantability, fitness for a particular purpose or of any other nature are made
hereunder with respect to information or the product to which information refers. The data contained on this sheet apply to the product(s) as
supplied to the user.




8


Lubricating oils, (petroleum), hydrotreated spent