CHEMTREC Transporation
Emergency Phone: 800-424-
9300

Material Safety Pittsburgh Poison Control
Center
Health Emergency No.: 412-
Data Sheet 681-6669
NOTE: The CHEMTREC Transportation
Emergency Phone is to be used only in the
event of chemical emergencies involving a
spill, leak, fire, exposure or accident involving
chemicals


Section 1 - Chemical Product / Company Information

PLASITE 797 PART A Revision Date: 01/03/2008
Product Name:
Identification
PLMSDS 243PA1NL Supercedes : 01/03/2008
Number:
Epoxy Polyamine - FO Product
INDUSTRIAL USE ONLY
Use/Class:
Regulatory, Department
Preparer:
Manufacturer: Carboline Company
350 Hanley Industrial Ct.
St. Louis, MO 63144


Section 2 - Composition / Information On Ingredients

Chemical Name CAS Number Weight % Less Than ACGIH TLV-TWA ACGIH TLV-STEL OSHA PEL-TWA OSHA-CEIL
EPOXY RESIN 25068-38-6 45.0 NE NE NE NE
MICROCRYSTALLINE 14808-60-7 20.0 0.025 MG/M3 N/E 0.1 MG/M3 N/E
SILICA (respirable) (respirable)
ALKYL GLYCIDYL 68609-96-1 5.0 N/E N/E N/E N/E
ETHE CARBON BLACK 1333-86-4 0.2 N/E N/E N/E N/E



Section 3 - Hazards Identification

Emergency Overview: Warning! May cause allergic skin reactions. May cause irritation. Contains SILICA
which can cause cancer. Risk of Cancer depends on duration and level of exposure.

Effects Of Overexposure - Eye Contact: May cause eye irritation.

Effects Of Overexposure - Skin Contact: May cause skin irritation. May cause allergic skin reaction.

Effects Of Overexposure - Inhalation: May cause nose and throat irritation.

Effects Of Overexposure - Ingestion: May be harmful if swallowed.

Effects Of Overexposure - Chronic Hazards: Crystalline silica is known to cause silicosis. Crystalline silica
(Quartz) is classified as a known human carcinogen (Group 1) by IARC. Exposure is by route of inhalation. If
material is in a liquid matrix it is unlikely to be inhaled. However, when sanding or grinding the finished product,
there may be potential for crystalline silica to become airborne.




 Primary Route(s) Of Entry: Skin Contact, Eye Contact

Medical Conditions Prone to Aggravation by Exposure: If sensitized to amines, epoxies, or other
chemicals do not use. See a physician if a medical condition exists.


Section 4 - First Aid Measures

First Aid - Eye Contact: If material gets into eyes, flush with water immediately for 15 minutes. Consult a
physician.

First Aid - Skin Contact: In case of contact, wash skin immediately with soap and water.

First Aid - Inhalation: If inhaled, remove to fresh air. Administer oxygen if necessary. Consult a physician if
symptoms persist or exposure was severe.

First Aid - Ingestion: If swallowed do not induce vomiting. Seek immediate medical attention.


Section 5 - Fire Fighting Measures
Flash Point, F: 213F (100C) Lower Explosive Limit, %: 1.0
Upper Explosive Limit, %: 7.1
(Setaflash)

Extinguishing Media: Carbon Dioxide, Dry Chemical, Foam, Water Fog

Unusual Fire And Explosion Hazards: This product contains less than 1% volatile components. The amount
of vapors that could accumulate are minimal. However, vapors are heavier than air and could travel long
distances, ignite, and flashback. Eliminate all ignition sources. Keep away from sparks, open flames, and heat
sources. All electrical equipment and installations should be made and grounded in accordance with the
National Electrical Code. In areas where explosion hazards exist, workers should be required to use
nonferrous tools and to wear conductive and non-sparking shoes.

Special Firefighting Procedures: Evacuate hazard area of unprotected personnel. Use a NIOSH approved
self-contained breathing unit and complete body protection. Cool surrounding containers with water in case of
fire exposure.


Section 6 - Accidental Release Measures

Steps To Be Taken If Material Is Released Or Spilled: Eliminate all ignition sources. Handling equipment
must be grounded to prevent sparking. Evacuate the area of unprotected personnel. Wear appropriate
personal protection clothing and equipment. Follow exposure controls/personal protection guidelines in Section
8. Contain and soak up residual with an aborbent (clay or sand). Take up absorbant material and seal tightly
for proper disposal. Dispose of in accordance with local, state and federal regulations. Refer to Section 15 for
SARA Title III and CERCLA information.


Section 7 - Handling And Storage

Handling: Avoid breathing vapors or spray mist. Do not get in eyes, on skin, or on clothing. Keep container
tightly closed when not in use. Wear personal protection equipment. Do not breathe vapors. Wash thoroughly
after handling. If pouring or transferring materials, ground all containers and tools. Do not weld, heat, cut or drill
on full or empty containers. Use only in accordance with Carboline application instructions, container label and




 Product Data Sheet.

Storage: Keep away from heat, sparks, open flames and oxidizing agents. Keep containers closed. Store in a
cool, dry place with adequate ventilation.


Section 8 - Exposure Controls / Personal Protection

Engineering Controls: Use explosion-proof ventilation when required to keep below health exposure
guidelines and Lower Explosion Limit (LEL).

Respiratory Protection: Use only with ventilation to keep levels below exposure guidelines listed in Section 2.
User should test and monitor exposure levels to ensure all personnel are below guidelines. If not sure, or not
able to monitor, use MSHA/NIOSH approved supplied air respirator. Follow all current OSHA requirements for
respirator use. For silica containing coatings in a liquid state, and/or if no exposure limits are established in
Section 2 above, supplied air respirators are generally not required.

Skin Protection: Recommend impervious gloves and clothing to avoid skin contact. If material penetrates to
skin, change gloves and clothing. The use of protective creams may be beneficial to certain individuals.
Protective creams should be applied before exposure.

Eye Protection: Recommend safety glasses with side shields or chemical goggles to avoid eye contact.

Other protective equipment: Eye wash and safety showers should be readily available.

Hygienic Practices: Wash with soap and water before eating, drinking, smoking, applying cosmetics, or using
toilet facilities. Use of a hand cleaner is recommended. Launder contaminated clothing before reuse. Leather
shoes can absorb and allow hazardous materials to pass through. Check shoes carefully after soaking before
reuse.


Section 9 - Physical And Chemical Properties
176 F (80 C) - 500 F (260 C) Heavier than Air
Boiling Range: Vapor Density:
Aromatic N/ Odor: Odor Threshold:
Viscous Liquid, Various Colors Slower Than Ether
Appearance: Evaporation Rate:
N/ Solubility in H2O:
N/D app. 1.49
Freeze Point: Specific Gravity:
N/D N/ Vapor Pressure: PH:
Liquid
Physical State:

(See section 16 for abbreviation legend)



Section 10 - Stability And Reactivity

Conditions To Avoid: Heat, sparks and open flames.

Incompatibility: Avoid contact with strong oxidizing agents.

Hazardous Decomposition Products: Carbon monoxide, nitrogen oxides, and unidentified organic
compounds. Consider all smoke and fumes from burning material as very hazardous. Welding, cutting or
abrasive grinding can create smoke and fumes. Do not breathe any fumes or smoke from these operations.




 Hazardous Polymerization: Will not occur under normal conditions.

Stability: This product is stable under normal storage conditions.


Section 11 - Toxicological Information

Product LD50: N/D Product LC50: N/
Chemical Name CAS Number LD50 LC50
EPOXY RESIN 25068-38-6 11.4G/KG RAT,ORAL >20ML/KG SKIN,SENSITIZE MICROCRYSTALLINE SILICA 14808-60-7 NOT AVAILABLE NOT AVAILABLE
ALKYL GLYCIDYL ETHER 68609-96-1 >1.5 G/KG, INH, RAT 10.4 G/KG, ORAL, RAT
CARBON BLACK 1333-86-4 NOT AVAILABLE NOT AVAILABLE



Section 12 - Ecological Information

Ecological Information: No data


Section 13 - Disposal Information

Disposal Information: Dispose of in accordance with State, Local, and Federal Environmental regulations.
Responsibility for proper waste disposal is with the owner of the waste.


Section 14 - Transportation Information

Not Regulated Packing Group: N/A
DOT Proper Shipping
Name:
N/A Hazard Subclass:N/A
DOT Technical Name:
None N/A
DOT Hazard Class: Resp. Guide
None
DOT UN/NA Number:

Additional Notes: None.


Section 15 - Regulatory Information

CERCLA - SARA HAZARD CATEGORY

This product has been reviewed according to the EPA Hazard Categories promulgated under Sections 311and
312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under
applicable definitions, to meet the following categories:

IMMEDIATE HEALTH HAZARD, CHRONIC HEALTH HAZAR
SARA SECTION 313

This product contains the following substances subject to the reporting requirements of Section 313 of Title III
of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:




 No Section 313 Substances exist in this product

TOXIC SUBSTANCES CONTROL ACT

All components of this product are listed on the TSCA inventory.

This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if
exported from the United States:

No TSCA 12(B) Substances exist in this product

U.S. STATE REGULATIONS AS FOLLOWS:

NEW JERSEY RIGHT-TO-KNOW

The following materials are non-hazardous, but are among the top five components in this product.

Chemical Name CAS Number
GLASS OXIDE 65997-17-3
CLAY 1332-58-7
TITANIUM DIOXIDE 13463-67-7

PENNSYLVANIA RIGHT-TO-KNOW

The following non-hazardous ingredients are present in the product at greater than 3%.

Chemical Name CAS Number
GLASS OXIDE 65997-17-3
CLAY 1332-58-7
TITANIUM DIOXIDE 13463-67-7
MODIFIED EPOXY RESIN TRADE SECRET
BLACK IRON OXIDE 68186-94-7
IRON OXIDE 1332-37-2
ORGANIC PIGMENT 5567-15-7

CALIFORNIA PROPOSITION 65

Warning: The following ingredients present in the product are known to the state of California to cause
Cancer:

Chemical Name CAS Number
MICROCRYSTALLINE SILICA 14808-60-7
CARBON BLACK 1333-86-4
ETHYL BENZENE 100-41-4
ETHYL ACRYLATE 140-88-5

Warning: The following ingredients present in the product are known to the state of California to cause
birth defects, or other reproductive hazards:

No California Proposition 65 Reproductive Toxins exist

INTERNATIONAL REGULATIONS AS FOLLOWS:




 CANADIAN WHMIS

This MSDS has been prepared in compliance with Controlled Product Regulations except for the use of the 16
headings.

CANADIAN WHMIS CLASS: D2A, D2B


Section 16 - Other Information

HMIS Ratings
Health: 2 Flammability: 1 Reactivity: 2 Personal Protection: X

VOLATILE ORGANIC COMPOUNDS, GR/LTR MIXED (UNTHINNED): 0

REASON FOR REVISION: Replaces previous revision dated 11/24/03. New format

Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined


The information contained herein is, to the best of our knowledge and belief accurate. However, since the
conditions of handling and use are beyond our control, we make no guarantee of results, and assume no
liability for damages incurred by use of this material. It is the responsibility of the user to comply with all
applicable federal, state, and local laws and regulations






Manganese ferrite black spinel