Material Safety Data Sheet chemusa

Section I. Chemical Product and Company Identification

VANOX? 945
Product Name/ 53682
Code
Trade Name
Mixture
CAS#
Supplier R.T. VANDERBILT COMPANY, INC.
In Case of Call: (203) 853-1400
30 WINFIELD STREET Emergency
NORWALK, CT 06855
Not available.
Synonym

Mixture of phenols, alkylated diphenylamines and phenothiazine.
Chemical name

(Petrochemical.)
Chemical Family

Chemical Formula Not applicable.

Industrial applications: Polyurethane stabilizer.
Material Uses


TSCA 8(b) inventory: VANOX? 945
TSCA Status



Section II. Composition and Information on Ingredients
Name CAS # % by Weight

benzeneamine,-N-phenyl-, reaction product with 2,4,4-trimethylpentene 184378-08-3 60-70
and 2-methylpropene
tetrakis(methylene(3,5-di-t-butyl-4-hydroxyhydrocinnamate))methane 6683-19-8 20-25
petroleum process oil, <3.0% DMSO extractable material 64742-52-5 9
diphenylamine 122-39-4 <1
phenothiazine 92-84-2 1



Section III. Hazards Identification
Amber liquid with a slight amine odor. Slight eye irritant. Ingestion, especially in large quantities, may be
Emergency Overview
hazardous. Heating may generate vapors which can irritate eyes and respiratory passages.



Section IV. First Aid Measures
Flush with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Seek
Eye Contact
medical attention if irritation persits.
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing
Skin Contact
contaminated clothing and shoes. Cover the irritated skin with an emollient. Wash clothing before reuse.
Thoroughly clean shoes before reuse. Get medical attention immediately.

If inhaled, remove victim to fresh air. If not breathing, give artificial respiration, preferably mouth-to-mouth.
Inhalation
Get medical attention.

Do not induce vomiting. Immediately give two glasses of water, a little at a time. Never give anything by
Ingestion
mouth to an unconscious person. Call a physician. If vomiting occurs spontaneously, lower head below waist
to prevent fluid from entering the lungs.




Continued on Next
Section V. Fire and Explosion Data
Combustible.
Flammability of the Product

Not available.
Autoignition Temperature

OPEN CUP: 201.6??C (394.9??F) (Cleveland.).
Flash Point

Not available.
Flammable Limits

Oxides of carbon, nitrogen, sulfur, small amounts of phosphoric acid and possible traces of phosphine.
Products of Combustion


Explosion Hazards in Presence Risks of explosion of the product in presence of mechanical impact: Not available.
Risks of explosion of the product in presence of static discharge: Not available.
of Various Substances


SMALL FIRE: Use DRY chemical powder.
Fire Fighting Media
LARGE FIRE: Use water spray, fog or foam. Do not use water jet.
and Instructions

Heated containers may explode. Vapors may ignite in an enclosed space.
Special Remarks on Fire
Hazards
Special Remarks on Explosion Not available.
Hazards




Section VI. Accidental Release Measures
Absorb with an inert material and put the spilled material in an appropriate waste disposal
Small Spill

Keep away from heat. Keep away from sources of ignition. Stop leak if without risk. DO NOT get water
Large Spill
inside container. DO NOT touch spilled material. Use water spray to reduce vapors. Prevent entry into
sewers, basements or confined areas; dike if needed. Eliminate all sources of ignition. Call for assistance on
disposal. Be careful that the product is not present at a concentration level above TLV. Check TLV on the
MSDS and with local authorities.



Section VII. Handling and Storage
Keep container tightly closed in a cool, well-ventilated place.
Storage


Avoid contact with skin and eyes. Avoid breathing vapors or spray mists. Do not ingest. Keep away from
Handling Procedures and
heat, sparks and flame. After handling, always wash hands thoroughly with soap and water.
Equipment



Section VIII. Exposure Controls/Personal Protection
Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below
Engineering Controls
their respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the
work-station location.
Splash goggles. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent.
Personal Protection
Gloves.
Process oil
TLV / PEL
TWA: 5 (mg/m3) from OSHA
TWA: 5 STEL: 10 (mg/m3) from ACGIH
Diphenylamine
TWA: 10 (mg/m3) from ACGIH
TWA: 10 (mg/m3) from OSHA
phenothiazine
TWA: 5 (mg/m3) from OSHA SKIN
TWA: 5 (mg/m3) from ACGIH SKIN

Consult local authorities for acceptable exposure limits.




Continued on Next
Section IX. Physical and Chemical Properties
Amber. (Light.) Liquid.
Appearance

Not applicable.
Molecular Weight
Not applicable.
pH (1% soln/water)
Not available.
Boiling/Condensation Point
Not available.
Melting Point
0.99 (Water = 1)
Specific Gravity
Not available.
Density
The highest known value is <0 kPa (@ 20??C) (petroleum process oil, <3.0% DMSO extractable material).
Vapor Pressure
The highest known value is 5 (Air = 1) (petroleum process oil, <3.0% DMSO extractable material).
Vapor Density
Not available.
Volatility
Amine like.
Odor
0.01 (petroleum process oil, <3.0% DMSO extractable material) compared to Butyl acetate.
Evaporation Rate

Not available.
Viscosity

Not available.
Water/Oil Dist. Coeff.
Insoluble in water.
Solubility




Section X. Stability and Reactivity Data
The product is stable.
Stability
Not available.
Instability Temperature
Not available.
Conditions of Instability

Reactive with oxidizing agents, acids.
Incompatibility with Various
Substances
Not available.
Corrosivity


Special Remarks on Reactivity Not available.




Section XI. Toxicological Information
Absorbed through skin. Dermal contact. Eye contact. Inhalation. Ingestion
Routes of Entry

Acute oral toxicity (LD50): >2000 mg/kg [Rat].
Toxicity to Animals
Acute dermal toxicity (LD50): >2000 mg/kg [Rabbit]

Special Remarks on Toxicity to Skin Irritation (Rabbit): Non-irritant.
Eye Irritation (Rabbit): Slight Irritant.
Animals

Acute Effects

This product has been found to be an irritant in rabbits.
Eye Contact

Not expected to be a skin irritant based on animal data.
Skin Contact

Not expected to be a skin sensitizer based on animal data.
Sensitization

Not expected to be a significant hazard based on animal data.
Ingestion

No data available. Based on component testing, heating may cause vapors that can irritate the respiratory
Inhalation
system.

Continued on Next
Phenothiazine - Hyperpigmentation of the skin with direct sunlight can develop upon repeated ingestion.
Remarks
Irritation and allergic dermatitis may develop upon repeated or prolonged contact with skin. May be absorbed
through skin. Slightly irritating to eyes.

CARCINOGENIC EFFECTS Not available.
:
Chronic Effects on
MUTAGENIC EFFECTS Not available.
:
Humans
TERATOGENIC EFFECTS Not available.
:
DEVELOPMENTAL TOXICITY Not available.
:

EFFECTS OF OVEREXPOSURE:
Remarks
Diphenylamines may be irritating to mucous membranes. Heating may generate vapors which can irritate the
eyes and respiratory passages. Dust may be irrritating to the upper respiratory tract. Drying of skin and
mucous membranes leading to irritation may be possible from prolonged or repeated contact. Overexposure
to vapors from heating the product may cause eye and/or skin irritation and respiratory tract irritation with
symptoms such as, but not limited to, dizziness and flu-like symptoms.

Phenothiazine is irritating to the skin and can cause skin sensitization and photosensitization following
repeated and prolonged contact. Slightly irritating to the eyes. Ingestion of large doses can cause toxic
hepatitis, hemolytic annemia associated with abdominal cramps, tachycardia, gastrointestinal irritation, kidney
injury, inflamed cornea and itching. Red tinted oxidation products can appear in the urine.




Section XII. Ecological Information
Not available.
Ecotoxicity

Not available.
BOD and CO
Possibly hazardous short term degradation products are not likely. However, long term degradation products
Products of Biodegradation
may arise.
Biodegradability


Not available.
Special Remarks on the
Products of Biodegradation



Section XIII. Disposal Considerations
Waste must be disposed of in accordance with federal, state and local environmental control regulations.
Waste Information
Not available.
Waste Stream



Section XIV. Transport Information
Not a DOT controlled material (United States).
DOT




Not applicable.
Remarks



Not available.
Maritime transportation




Continued on Next
Section XV. Other Regulatory Information and Pictograms
HCS Class: Irritating substance.
Classification HCS (USA)
OSHA: Hazardous by definition of Hazard Communication Standard (29 CF 1910.1200).
Illinois chemical safety act: diphenylamine
Federal and State
Rhode Island RTK hazardous substances: diphenylamine
Regulations
Pennsylvania RTK: diphenylamine; phenothiazine
Florida: diphenylamine; phenothiazine
Minnesota: diphenylamine; phenothiazine
Massachusetts RTK: diphenylamine; phenothiazine
Massachusetts spill list: diphenylamine
New Jersey: diphenylamine; phenothiazine
TSCA 8(b) inventory: VANOX? 945
TSCA 8(a) IUR: diphenylamine
TSCA 8(d) H and S data reporting: diphenylamine
SARA 311/312 MSDS distribution - chemical inventory - hazard identification:
petroleum process oil, <3.0% DMSO extractable material: fire; phenothiazine: delayed
health hazard
SARA 313 toxic chemical notification and release reporting: diphenylamine: 1%


Not available.
Remarks

National Fire Protection
Hazardous Material Flammability
1
* 2
Health Hazard
Association (U.S.A.)
Information System
1 2 0
Fire Hazard Reactivity
(U.S.A.) Health
0
Reactivity
Specific hazard
h
Personal Protection



Other regulatory EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances.
specifications



Australia: VANOX? 945



Protective Clothing
(Pictograms)




Section XVI. Other Information
Not available.
References

Not available.
Other Special
Considerations

Validated by Romana Uzar on 11/17/2006. Verified by Romana Uzar.
Previous Validation Date: 10/1/2002. Printed 11/17/2006.


Information Contact (203) 853-1400
Corporate Risk Management Department

Notice to Reader
Information presented herein has been compiled from sources considered to be dependable and is accurate and reliable to the best of our knowledge
and belief but is not guaranteed to be so. Nothing herein is to be construed as recommending any practice or any product in violation of any patent or
in violation of any law or regulation. It is the user??s responsibility to determine for himself the suitability of any material for a specific purpose and to
adopt such safety precautions as may be necessary. We make no warranty as to the results to be obtained in using any material and, since conditions
of use are not under our control, we must necessarily disclaim all liability with respect to the use of any material supplied by us.


Benzenamine, N-phenyl-, reaction products with isobutylene and 2,4,4-trimethylpentene