Material Safety Data Sheet
MMI-TOF Tuning Mix PN: G1969-85020

1. Product and company identification
Product name : MMI-TOF Tuning Mix PN: G1969-85020
Part No. : G1969-85020
: Agilent Technologies, Inc.
Manufacturer / Supplier
Logistics Center - Americas
500 Ships Landing Way
New Castle, Delaware 19720
Emergency telephone number : 1-302-633-8777
1-877-4 Agilent (Information Telephone Number)

2. Hazards identification
: Liquid.
Physical state
OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
: Warning!
Emergency overview -
Signal Word
Emergency overview - : CONTAINS MATERIAL WHICH CAUSES DAMAGE TO THE FOLLOWING ORGANS:
KIDNEYS, LIVER, CARDIOVASCULAR SYSTEM, RESPIRATORY TRACT, SKIN,
Label Stalement
CENTRAL NERVOUS SYSTEM, EYE, LENS OR CORNEA.
Routes of entry : Eye contact.
Potential acute health effects
Eyes : No known significant effects or critical hazards.
: No known significant effects or critical hazards.
Skin
: No known significant effects or critical hazards.
Inhalation
Ingestion : No known significant effects or critical hazards.
: Repeated or prolonged exposure to the substance can produce target organs damage.
Medical conditions
aggravated by over-
exposure
See toxicological information (section 11)

3. Composition/information on ingredients
Name CAS number %
acetonitrile 75-05-8 95
water 7732-18-5 5
Hexakis(1H,1H,9H-perfluorononyloxy)phosphazene 186043-67-4 <0.01
Hexakis (1H,1H,8H-tetradecafluorooctyloxy) phosphazine 186406-49-5 <0.01
Hexakis(1H,1H,7H-dodecafluoroheptoxy)phosphazene 3830-74-8 <0.01
Hexakis (1H,1H,6H-Decafluorohexyloxy) phosphazine 186406-48-4 <0.01
Hexakis(1H,1H,5H-octafluoropentoxy)phospazine 16059-16-8 <0.01
Hexakis (1H,1H,4H-hexafluorobutyloxy) phosphazine 186406-47-3 <0.01
Hexakis(1H,1H,3H-tetrafluoropropoxy)phosphazine 58943-98-9 <0.01
Hexakis(2,2-difluoroethoxy)phosphazine 186817-57-2 <0.01
Hexamethoxyphosphine 957-13-1 <0.01
2,4,6-tris(heptafluoropropyl)-1,3,5-triazine 915-76-4 <0.01
Tris (trifluoromethyl)-1,3,5-triazine 368-66-1 <0.01
ammonium trifluoroacetate 3336-58-1 <0.01
purine 120-73-0 <0.01
: 1x100 ml
Use of the
substance/preparation
Synonyms : acetonitril (german, dutch); acetonitrile ; cyanomethane; cyanure de methyl (french);
ethanenitrile; ethyl nitrile; methanecarbonitrile; methane, cyano-; methyl cyanide; nci-
c60822; usaf ek-488.


1/26/2006. MMI-TOF Tuning Mix PN: G1969-85020

4. First aid measures
Eye contact : In case of contact, immediately flush eyes with plenty of water for at least 15 minutes.
Get medical attention if adverse health effects persist or are severe.
Skin contact : In case of contact, immediately flush skin with plenty of water. Remove contaminated
clothing and shoes. Wash clothing before reuse. Clean shoes thoroughly before reuse.
Get medical attention if adverse health effects persist or are severe.
Inhalation : If inhaled, remove to fresh air. If breathing is difficult, give oxygen. If not breathing, give
artificial respiration. Get medical attention if adverse health effects persist or are severe.
: Do not induce vomiting unless directed to do so by medical personnel. Never give
Ingestion
anything by mouth to an unconscious person. Get medical attention if adverse health
effects persist or are severe.

5. Fire-fighting measures
: Flammable.
Flammability of the product
: These products are carbon oxides (CO, CO 2), nitrogen oxides (NO, NO2 etc.).
Products of combustion
Extinguishing media
Suitable : Use an extinguishing agent suitable for the surrounding fire.
Special exposure hazards - : No specific hazard.
Explosibility
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
equipment for fire-fighters
Special remarks on fire : Vapor may travel a considerable distance to source of ignition and flash back. Container
explosion may occur under fire conditions or when heated.
hazards

6. Accidental release measures
Personal precautions : Avoid contact with eyes, skin and clothing.
Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers.
: If emergency personnel are unavailable, contain spilled material. For small spills, add
Methods for cleaning up
absorbent (soil may be used in the absence of other suitable materials), scoop up
material and place in a sealable, liquid-proof container for disposal. For large spills, dike
spilled material or otherwise contain it to ensure runoff does not reach a waterway.
Place spilled material in an appropriate container for disposal.

7. Handling and storage
: Wash thoroughly after handling.
Handling
: Keep container tightly closed. Keep container in a cool, well-ventilated area.
Storage

8. Exposure controls/personal protection
Product name Exposure limits
acetonitrile ACGIH TLV (United States, 1/2004). Skin
TWA: 20 ppm 8 hour/hours. Form: All forms
NIOSH REL (United States, 12/2001).
TWA: 34 mg/m3 10 hour/hours. Form: All forms
TWA: 20 ppm 10 hour/hours. Form: All forms
OSHA PEL (United States, 8/1997).
TWA: 70 mg/m3 8 hour/hours. Form: All forms
TWA: 40 ppm 8 hour/hours. Form: All forms
: No special ventilation requirements. Good general ventilation should be sufficient to
Engineering measures
control airborne levels. If this product contains ingredients with exposure limits, use
process enclosures, local exhaust ventilation or other engineering controls to keep
worker exposure below any recommended or statutory limits.
Personal protection


1/26/2006. MMI-TOF Tuning Mix PN: G1969-85020

8. Exposure controls/personal protection
Eyes : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists or
dusts.
Skin : Chemical resistant protective gloves and clothing are recommended. The choice of
protective gloves or clothing must be based on chemical resistance and other use
requirements. Generally, BUNA-N offers acceptable chemical resistance. Individuals
who are acutely and specifically sensitive to this chemical may require additional
protective clothing.
: Use a properly fitted, air-purifying or air-fed respirator complying with an approved
Respiratory
standard if a risk assessment indicates this is necessary. Respirator selection must be
based on known or anticipated exposure levels, the hazards of the product and the safe
working limits of the selected respirator.

Hands : Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary.

: Wash hands, forearms and face thoroughly after handling chemical products, before
Hygiene measures
eating, smoking and using the lavatory and at the end of the working period. Appropriate
techniques should be used to remove potentially contaminated clothing. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety showers
are close to the workstation location.

9. Physical and chemical properties
Liquid.
Physical state :
Flash point : The lowest known value is Closed cup: 5.85??C (42.5??F). (acetonitrile)
The lowest known value is 524??C (975.2??F) (acetonitrile).
Auto-ignition temperature :
Clear. Colorless.
Color :
Odor : Ether-like
pH : Not available.
Boiling/condensation point : The lowest known value is 81.67??C (179??F) (acetonitrile). Weighted average: 82.59??C
(180.7??F)
Melting/freezing point : May start to solidify at 0??C (32??F) based on data for: water. Weighted average: -39.8??C
(-39.6??F)
: The only known value is 0.787 (Water = 1) (acetonitrile).
Relative density
Vapor density : The highest known value is 1.42 (Air = 1) (acetonitrile).
: 2.33 (acetonitrile) compared with Butyl acetate.
Evaporation rate
: Soluble in cold water, hot water.
Solubility

10 . Stability and reactivity
Stability and reactivity : The product is stable.
Incompatibility with various : Highly reactive or incompatible with the following materials: oxidizing materials, reducing
substances materials, acids, alkalis and moisture.
Conditions of reactivity - : Highly flammable in the presence of the following materials or conditions: open flames,
sparks and static discharge and heat.
Flammability
Vapor may travel a considerable distance to source of ignition and flash back. Container
explosion may occur under fire conditions or when heated.




1/26/2006. MMI-TOF Tuning Mix PN: G1969-85020

11 . Toxicological information
Toxicity data
Product/ingredient name Test Result Route Species
acetonitrile LD50 2460 mg/kg Oral Rat
LD50 50 mg/kg Oral Rabbit
LD50 177 mg/kg Oral Guinea pig
Chronic effects on humans : CARCINOGENIC EFFECTS: Classified A4 (Not classifiable for humans or animals.) by
ACGIH [acetonitrile].
Contains material which causes damage to the following organs: kidneys, liver,
cardiovascular system, upper respiratory tract, skin, central nervous system (CNS), eye,
lens or cornea.

Other toxic effects on : Hazardous in case of eye contact (irritant).
humans
Specific effects
Carcinogenic effects : No known significant effects or critical hazards.
Mutagenic effects : No known significant effects or critical hazards.
Teratogenicity / : No known significant effects or critical hazards.
Reproductive toxicity
Sensitization
Ingestion : No known significant effects or critical hazards.
No known significant effects or critical hazards.
Inhalation :
Eyes : No known significant effects or critical hazards.
No known significant effects or critical hazards.
Skin :

12 . Ecological information
Ecotoxicity data
Product/ingredient name Species Period Result
acetonitrile Pimephales promelas (LC50) 96 hour/hours >100 mg/l
Daphnia magna (LC50) 96 hour/hours >100 mg/l
Pimephales promelas (LC50) 96 hour/hours 1640 mg/l
Environmental precautions : No known significant effects or critical hazards.
: These products are carbon oxides (CO, CO 2) and water, nitrogen oxides (NO, NO2 etc.).
Products of degradation
Toxicity of the products of : The products of degradation are less toxic than the product itself.
biodegradation

13 . Disposal considerations
Waste disposal : The generation of waste should be avoided or minimized wherever possible. Avoid
dispersal of spilled material and runoff and contact with soil, waterways, drains and
sewers. Disposal of this product, solutions and any by-products should at all times
comply with the requirements of environmental protection and waste disposal legislation
and any regional local authority requirements.
Disposal should be in accordance with applicable regional, national and local laws and regulations. Local
regulations may be more stringent than regional or national requirements.

The information presented below only applies to the material as supplied. The identification based on
characteristic(s) or listing may not apply if the material has been used or otherwise contaminated. It is the
responsibility of the waste generator to determine the toxicity and physical properties of the material generated to
determine the proper waste identification and disposal methods in compliance with applicable regulations.

Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
for additional handling information and protection of employees.




1/26/2006. MMI-TOF Tuning Mix PN: G1969-85020

14 . Transport information
Regulatory UN number Proper shipping Class PG* Label Additional
information name information
DOT Classification Packaging
3316 Chemical Kits 9 II
instruction
Passenger aircraft
9


Quantity limitation: 10
kg

Cargo aircraft
Quantity limitation: 10
kg

Remarks
Requires Dangerous
Goods BOL
3316 Chemical Kit 9 II -
TDG Classification

9




3316 Chemical Kit 9 II -
Mexico
Classification
9




3316 Chemical Kit 9 II
IATA Class Quantity limitation -
Passenger aircraft
10 kg
9




Quantity limitation -
Cargo aircraft
10 kg

Packaging
instruction
915

RemarksRequires
Shipper's Declaration
of Dangerous Goods
PG* : Packing group

15 . Regulatory information
HCS Classification : Target organ effects
: TSCA 8(a) PAIR: acetonitrile
U.S. Federal regulations
TSCA 8(b) inventory: water; acetonitrile
SARA 302/304/311/312 extremely hazardous substances: No products were found.
SARA 302/304 emergency planning and notification: No products were found.
SARA 302/304/311/312 hazardous chemicals: acetonitrile
SARA 311/312 MSDS distribution - chemical inventory - hazard identification:
acetonitrile: Fire hazard, Immediate (acute) health hazard, Delayed (chronic) health
hazard
Clean Water Act (CWA) 307: acetonitrile
Clean Water Act (CWA) 311: No products were found.
Clean Air Act (CAA) 112 accidental release prevention: No products were found.
Clean Air Act (CAA) 112 regulated flammable substances: No products were found.
Clean Air Act (CAA) 112 regulated toxic substances: No products were found.

1/26/2006. MMI-TOF Tuning Mix PN: G1969-85020

15 . Regulatory information
SARA 313
Product name CAS number Concentration
Form R - Reporting : acetonitrile 75-05-8 95
requirements
: acetonitrile 75-05-8 95
Supplier notification
SARA 313 notifications must not be detached from the MSDS and any copying and redistribution of the MSDS shall
include copying and redistribution of the notice attached to copies of the MSDS subsequently redistributed.

State regulations : Pennsylvania RTK: acetonitrile: (environmental hazard, generic environmental hazard)
Massachusetts RTK: acetonitrile
New Jersey: acetonitrile
EU regulations
: Harmful
Hazard symbol/symbols
Risk phrases : R20/21/22- Harmful by inhalation, in contact with skin and if swallowed.
R36- Irritating to eyes.
: S36/37- Wear suitable protective clothing and gloves.
Safety phrases
International regulations
: Australia (NICNAS): water; acetonitrile
International lists

China: water; acetonitrile

Germany water class: acetonitrile

Japan (METI): water; acetonitrile

Japan (MOL): ammonium trifluoroacetate

Korea (TCCL): water; acetonitrile

Philippines (RA6969): ammonium trifluoroacetate; water; acetonitrile

16 . Other information
Label requirements : CONTAINS MATERIAL WHICH CAUSES DAMAGE TO THE FOLLOWING ORGANS:
KIDNEYS, LIVER, CARDIOVASCULAR SYSTEM, RESPIRATORY TRACT, SKIN,
CENTRAL NERVOUS SYSTEM, EYE, LENS OR CORNEA.
Date of printing : 1/26/2006.
Date of issue : 1/26/2006.
Version : 0.01
Notice to reader
DISCLAIMER: This Material Safety Data Sheet is offered without charge to the clients of Agilent Technologies.
Data is the most current available to Agilent Technologies at the time of preparation and is issued as a matter of
information only, no warranty as to its accuracy or completeness is expressed or implied.




Indicates information that has changed from previously issued version.




1/26/2006. 

HEXAKIS(2,2-DIFLUOROETHOXY)PHOSPHAZENE