|
1.
1.1
IDENTIFICATION
OF
THE
SUBSTANCE/MIXTURE
AND
OF
THE
COMPANY/UNDERTAKING
Product
identifiers
Product
name
Product
Number
Brand
CAS-No.
:
:
:
:
Sodium
amide
291587
Anonymous
7782-92-5
1.2
Relevant
identified
uses
of
the
substance
or
mixture
and
uses
advised
against
Identified
uses
:
Laboratory
chemicals,
Manufacture
of
substances 2.
2.1
2.2
HAZARDS
IDENTIFICATION
Classification
of
the
substance
or
mixture
Classification
according
to
Regulation
(EC)
No
1272/2008
[EU-GHS/CLP]
Flammable
liquids
(Category
2)
Substances,
which
in
contact
with
water,
emit
flammable
gases
(Category
2)
Skin
corrosion
(Category
1B)
Reproductive
toxicity
(Category
2)
Specific
target
organ
toxicity
-
single
exposure
(Category
3)
Specific
target
organ
toxicity
-
repeated
exposure
(Category
2)
Aspiration
hazard
(Category
1)
Acute
aquatic
toxicity
(Category
1)
Classification
according
to
EU
Directives
67/548/EEC
or
1999/45/EC
Highly
flammable.
Contact
with
water
liberates
extremely
flammable
gases.
Causes
burns.
Harmful:
may
cause
lung
damage
if
swallowed.
Harmful:
danger
of
serious
damage
to
health
by
prolonged
exposure
through
inhalation.
Possible
risk
of
harm
to
the
unborn
child.
Very
toxic
to
aquatic
organisms.
Vapours
may
cause
drowsiness
and
dizziness.
May
form
explosive
peroxides.
Contact
with
water
liberates
toxic
gas.
Reacts
violently
with
water.
Label
elements
Labelling
according
Regulation
(EC)
No
1272/2008
[CLP]
Pictogram
Signal
word
Hazard
statement(s)
H225
Danger
Highly
flammable
liquid
and
vapour.
H261
H304
H314
H336
H361d
H373
H400
Precautionary
statement(s)
P210
P231
+
P232
P261
P273
P280
P422
In
contact
with
water
releases
flammable
gases.
May
be
fatal
if
swallowed
and
enters
airways.
Causes
severe
skin
burns
and
eye
damage.
May
cause
drowsiness
or
dizziness.
Suspected
of
damaging
the
unborn
child.
May
cause
damage
to
organs
through
prolonged
or
repeated
exposure.
Very
toxic
to
aquatic
life.
Keep
away
from
heat/sparks/open
flames/hot
surfaces.
-
No
smoking.
Handle
under
inert
gas.
Protect
from
moisture.
Avoid
breathing
vapours.
Avoid
release
to
the
environment.
Wear
protective
gloves/
protective
clothing/
eye
protection/
face
protection.
Store
contents
under
inert
gas.
Supplemental
Hazard
information
(EU)
EUH019
EUH029
May
form
explosive
peroxides.
Contact
with
water
liberates
toxic
gas.
According
to
European
Directive
67/548/EEC
as
amended.
Hazard
symbol(s)
R-phrase(s)
R11
R14/15
R19
R29
R34
R48/20
R50
R63
R65
R67
S-phrase(s)
S26
S36/37/39
S43
S45
S61
S62
Highly
flammable.
Reacts
violently
with
water,
liberating
extremely
flammable
gases.
May
form
explosive
peroxides.
Contact
with
water
liberates
toxic
gas.
Causes
burns.
Harmful:
danger
of
serious
damage
to
health
by
prolonged
exposure
through
inhalation.
Very
toxic
to
aquatic
organisms.
Possible
risk
of
harm
to
the
unborn
child.
Harmful:
may
cause
lung
damage
if
swallowed.
Vapours
may
cause
drowsiness
and
dizziness.
In
case
of
contact
with
eyes,
rinse
immediately
with
plenty
of
water
and
seek
medical
advice.
Wear
suitable
protective
clothing,
gloves
and
eye/face
protection.
In
case
of
fire,
use
sand,
dry
chemical
or
alcohol-resistant
foam.
In
case
of
accident
or
if
you
feel
unwell,
seek
medical
advice
immediately
(show
the
label
where
possible).
Avoid
release
to
the
environment.
Refer
to
special
instructions/
Safety
data
sheets.
If
swallowed,
do
not
induce
vomiting:
seek
medical
advice
immediately
and
show
this
container
or
label.
2.3
3.
3.2
Other
hazards
May
form
explosive
peroxides.
COMPOSITION/INFORMATION
ON
INGREDIENTS
Mixtures
Formula
Molecular
Weight
:
:
H2NNa
39,01
g/mol
Component
Toluene
Classification
Concentration
CAS-No.
EC-No.
108-88-3
203-625-9
Flam.
Liq.
2;
Skin
Irrit.
2;
Repr.
50
-
100
%
2;
STOT
SE
3;
STOT
RE
2;
Index-No.
601-021-00-3
Asp.
Tox.
1;
H225,
H304,
H315,
H336,
H361d,
H373
F,
Xn,
Repr.Cat.3,
R11
-
R38
-
R48/20
-
R63
-
R65
-
R67
Sodium
amide
CAS-No.
EC-No.
7782-92-5
231-971-0
Water-react.
2;
Skin
Corr.
1B;
Aquatic
Acute
1;
H261,
H314,
50
-
100
%
H400,
H261,
H314,
H400,
EUH019
F,
C,
N,
R14/15
-
R19
-
R29
-
For
the
full
text
of
the
H-Statements
and
R-Phrases
mentioned
in
this
Section,
see
Section
16
4.
4.1
4.2
4.3
5.
5.1
5.2
5.3
5.4
6.
6.1
FIRST
AID
MEASURES
Description
of
first
aid
measures
General
advice
Consult
a
physician.
Show
this
safety
data
sheet
to
the
doctor
in
attendance.
If
inhaled
If
breathed
in,
move
person
into
fresh
air.
If
not
breathing,
give
artificial
respiration.
Consult
a
physician.
In
case
of
skin
contact
Take
off
contaminated
clothing
and
shoes
immediately.
Wash
off
with
soap
and
plenty
of
water.
Consult
a
physician.
In
case
of
eye
contact
Rinse
thoroughly
with
plenty
of
water
for
at
least
15
minutes
and
consult
a
physician.
If
swallowed
Do
NOT
induce
vomiting.
Never
give
anything
by
mouth
to
an
unconscious
person.
Rinse
mouth
with
water.
Consult
a
physician.
Most
important
symptoms
and
effects,
both
acute
and
delayed
Inhalation
studies
on
toluene
have
demonstrated
the
development
of
inflammatory
and
ulcerous
lesions
of
the
penis,
prepuce,
and
scrotum
in
animals.,
Material
is
extremely
destructive
to
tissue
of
the
mucous
membranes
and
upper
respiratory
tract,
eyes,
and
skin.,
spasm,
inflammation
and
edema
of
the
larynx,
spasm,
inflammation
and
edema
of
the
bronchi,
pneumonitis,
pulmonary
edema,
burning
sensation,
Cough,
wheezing,
laryngitis,
Shortness
of
breath,
Headache
Indication
of
any
immediate
medical
attention
and
special
treatment
needed
no
data
available
FIREFIGHTING
MEASURES
Extinguishing
media
Suitable
extinguishing
media
Dry
powder
Special
hazards
arising
from
the
substance
or
mixture
Carbon
oxides,
Sodium
oxides
Advice
for
firefighters
Wear
self
contained
breathing
apparatus
for
fire
fighting
if
necessary.
Further
information
no
data
available
ACCIDENTAL
RELEASE
MEASURES
Personal
precautions,
protective
equipment
and
emergency
procedures
Wear
respiratory
protection.
Avoid
breathing
vapors,
mist
or
gas.
Ensure
adequate
ventilation.
Remove
all
sources
of
ignition.
Evacuate
personnel
to
safe
areas.
Beware
of
vapours
accumulating
to
form
explosive
concentrations.
Vapours
can
accumulate
in
low
areas.
6.2
6.3
6.4
7.
7.1
7.2
7.3
8.
8.1
8.2
Environmental
precautions
Prevent
further
leakage
or
spillage
if
safe
to
do
so.
Do
not
let
product
enter
drains.
Discharge
into
the
environment
must
be
avoided.
Methods
and
materials
for
containment
and
cleaning
up
Contain
spillage,
and
then
collect
with
an
electrically
protected
vacuum
cleaner
or
by
wet-brushing
and
place
in
container
for
disposal
according
to
local
regulations
(see
section
13).
Do
not
flush
with
water.
Reference
to
other
sections
For
disposal
see
section
13.
HANDLING
AND
STORAGE
Precautions
for
safe
handling
Avoid
contact
with
skin
and
eyes.
Avoid
inhalation
of
vapour
or
mist.
Keep
away
from
sources
of
ignition
-
No
smoking.Take
measures
to
prevent
the
build
up
of
electrostatic
charge.
Conditions
for
safe
storage,
including
any
incompatibilities
Store
in
cool
place.
Keep
container
tightly
closed
in
a
dry
and
well-ventilated
place.
Containers
which
are
opened
must
be
carefully
resealed
and
kept
upright
to
prevent
leakage.
Never
allow
product
to
get
in
contact
with
water
during
storage.
Air
sensitive.
Handle
and
store
under
inert
gas.
Specific
end
uses
no
data
available
EXPOSURE
CONTROLS/PERSONAL
PROTECTION
Control
parameters
Components
with
workplace
control
parameters
Exposure
controls
Appropriate
engineering
controls
Handle
in
accordance
with
good
industrial
hygiene
and
safety
practice.
Wash
hands
before
breaks
and
at
the
end
of
workday.
Personal
protective
equipment
Eye/face
protection
Tightly
fitting
safety
goggles.
Faceshield
(8-inch
minimum).
Use
equipment
for
eye
protection
tested
and
approved
under
appropriate
government
standards
such
as
NIOSH
(US)
or
EN
166(EU).
Skin
protection
Handle
with
gloves.
Gloves
must
be
inspected
prior
to
use.
Use
proper
glove
removal
technique
(without
touching
glove's
outer
surface)
to
avoid
skin
contact
with
this
product.
Dispose
of
contaminated
gloves
after
use
in
accordance
with
applicable
laws
and
good
laboratory
practices.
Wash
and
dry
hands.
The
selected
protective
gloves
have
to
satisfy
the
specifications
of
EU
Directive
89/686/EEC
and
the
standard
EN
374
derived
from
it.
Body
Protection
Complete
suit
protecting
against
chemicals,
Flame
retardant
antistatic
protective
clothing,
The
type
of
protective
equipment
must
be
selected
according
to
the
concentration
and
amount
of
the
dangerous
substance
at
the
specific
workplace.
Respiratory
protection
Where
risk
assessment
shows
air-purifying
respirators
are
appropriate
use
a
full-face
respirator
with
multi-purpose
combination
(US)
or
type
ABEK
(EN
14387)
respirator
cartridges
as
a
backup
to
engineering
controls.
If
the
respirator
is
the
sole
means
of
protection,
use
a
full-face
supplied
air
respirator.
Use
respirators
and
components
tested
and
approved
under
appropriate
government
standards
such
as
NIOSH
(US)
or
CEN
(EU).
9.
9.1
PHYSICAL
AND
CHEMICAL
PROPERTIES
Information
on
basic
physical
and
chemical
properties
a)
b)
c)
d)
e)
f)
g)
h)
Appearance
Odour
Odour
Threshold
pH
Melting
point/freezing
point
Initial
boiling
point
and
boiling
range
Flash
point
Evaporation
rate
Form:
liquid
no
data
available
no
data
available
no
data
available
Melting
point/range:
210
°C
-
lit.
400
°C
-
lit.
4
°C
-
closed
cup
no
data
available
i)
Flammability
(solid,
gas)
no
data
available
j)
k)
l)
Upper/lower
flammability
or
explosive
limits
Vapour
pressure
Vapour
density
no
data
available
no
data
available
no
data
available
m)
Relative
density
no
data
available
n)
o)
p)
q)
r)
s)
t)
Water
solubility
Partition
coefficient:
n-
octanol/water
Autoignition
temperature
Decomposition
temperature
Viscosity
Explosive
properties
Oxidizing
properties
no
data
available
no
data
available
no
data
available
no
data
available
no
data
available
no
data
available
no
data
available
9.2
10.
10.1
10.2
10.3
10.4
10.5
10.6
Other
safety
information
no
data
available
STABILITY
AND
REACTIVITY
Reactivity
no
data
available
Chemical
stability
no
data
available
Possibility
of
hazardous
reactions
Reacts
violently
with
water.
Conditions
to
avoid
Heat,
flames
and
sparks.
Extremes
of
temperature
and
direct
sunlight.
Exposure
to
moisture.
Incompatible
materials
Water,
Oxidizing
agents,
Strong
oxidizing
agents,
acids,
Reacts
violently
with:,
Nitrites
Hazardous
decomposition
products
Other
decomposition
products
-
no
data
available
11.
11.1
TOXICOLOGICAL
INFORMATION
Information
on
toxicological
effects
Acute
toxicity
no
data
available
Skin
corrosion/irritation
no
data
available
Serious
eye
damage/eye
irritation
no
data
available
Respiratory
or
skin
sensitization
no
data
available
Germ
cell
mutagenicity
no
data
available
Carcinogenicity
IARC:
3
-
Group
3:
Not
classifiable
as
to
its
carcinogenicity
to
humans
(Toluene)
Reproductive
toxicity
no
data
available
Specific
target
organ
toxicity
-
single
exposure
no
data
available
Specific
target
organ
toxicity
-
repeated
exposure
no
data
available
Aspiration
hazard
no
data
available
Potential
health
effects
Inhalation
Ingestion
Skin
Eyes
Harmful
if
inhaled.
Material
is
extremely
destructive
to
the
tissue
of
the
mucous
membranes
and
upper
respiratory
tract.
Vapours
may
cause
drowsiness
and
dizziness.
Harmful
if
swallowed.
Causes
burns.
Aspiration
hazard
if
swallowed
-
can
enter
lungs
and
cause
damage.
Harmful
if
absorbed
through
skin.
Causes
skin
burns.
Causes
eye
burns.
Signs
and
Symptoms
of
Exposure
Inhalation
studies
on
toluene
have
demonstrated
the
development
of
inflammatory
and
ulcerous
lesions
of
the
penis,
prepuce,
and
scrotum
in
animals.,
Material
is
extremely
destructive
to
tissue
of
the
mucous
membranes
and
upper
respiratory
tract,
eyes,
and
skin.,
spasm,
inflammation
and
edema
of
the
larynx,
spasm,
inflammation
and
edema
of
the
bronchi,
pneumonitis,
pulmonary
edema,
burning
sensation,
Cough,
wheezing,
laryngitis,
Shortness
of
breath,
Headache
Additional
Information
RTECS:
Not
available
12.
12.1
12.2
12.3
12.4
ECOLOGICAL
INFORMATION
Toxicity
no
data
available
Persistence
and
degradability
no
data
available
Bioaccumulative
potential
no
data
available
Mobility
in
soil
no
data
available
12.5
12.6
13.
13.1
14.
14.1
Results
of
PBT
and
vPvB
assessment
no
data
available
Other
adverse
effects
Very
toxic
to
aquatic
life.
DISPOSAL
CONSIDERATIONS
Waste
treatment
methods
Product
Burn
in
a
chemical
incinerator
equipped
with
an
afterburner
and
scrubber
but
exert
extra
care
in
igniting
as
this
material
is
highly
flammable.
Offer
surplus
and
non-recyclable
solutions
to
a
licensed
disposal
company.
Contaminated
packaging
Dispose
of
as
unused
product.
TRANSPORT
INFORMATION
UN
number
14.2
ADR/RID:
3129
UN
proper
shipping
name
IMDG:
3129
IATA:
3129
ADR/RID:
IMDG:
IATA:
WATER-REACTIVE
LIQUID,
CORROSIVE,
N.O.S.
(Sodium
amide,
Toluene)
WATER-REACTIVE
LIQUID,
CORROSIVE,
N.O.S.
(Toluene,
Sodium
amide)
Water-reactive
liquid,
corrosive,
n.o.s.
(Toluene,
Sodium
amide)
14.3
Transport
hazard
class(es)
14.4
14.5
14.6
15.
ADR/RID:
4.3
(8)
Packaging
group
ADR/RID:
II
Environmental
hazards
ADR/RID:
no
Special
precautions
for
user
no
data
available
REGULATORY
INFORMATION
IMDG:
4.3
(8)
IMDG:
II
IMDG
Marine
pollutant:
no
IATA:
4.3
(8)
IATA:
II
IATA:
no
This
safety
datasheet
complies
with
the
requirements
of
Regulation
(EC)
No.
1907/2006.
15.1
15.2
16.
Safety,
health
and
environmental
regulations/legislation
specific
for
the
substance
or
mixture
no
data
available
Chemical
Safety
Assessment
no
data
available
OTHER
INFORMATION
Text
of
H-code(s)
and
R-phrase(s)
mentioned
in
Section
3
Aquatic
Acute
Asp.
Tox.
EUH019
Flam.
Liq.
H225
H261
H304
H314
H315
H336
H361d
H373
H400
Repr.
Acute
aquatic
toxicity
Aspiration
hazard
May
form
explosive
peroxides.
Flammable
liquids
Highly
flammable
liquid
and
vapour.
In
contact
with
water
releases
flammable
gases.
May
be
fatal
if
swallowed
and
enters
airways.
Causes
severe
skin
burns
and
eye
damage.
Causes
skin
irritation.
May
cause
drowsiness
or
dizziness.
Suspected
of
damaging
the
unborn
child.
May
cause
damage
to
organs
through
prolonged
or
repeated
exposure.
Very
toxic
to
aquatic
life.
Reproductive
toxicity
Skin
Corr.
Skin
Irrit.
STOT
RE
STOT
SE
Water-react.
C
F
R11
R14/15
R19
R29
R34
R38
R48/20
R50
R63
R65
R67
Repr.Cat.3
N
Xn
Skin
corrosion
Skin
irritation
Specific
target
organ
toxicity
-
repeated
exposure
Specific
target
organ
toxicity
-
single
exposure
Substances,
which
in
contact
with
water,
emit
flammable
gases
Corrosive
Highly
flammable
Highly
flammable.
Reacts
violently
with
water,
liberating
extremely
flammable
gases.
May
form
explosive
peroxides.
Contact
with
water
liberates
toxic
gas.
Causes
burns.
Irritating
to
skin.
Harmful:
danger
of
serious
damage
to
health
by
prolonged
exposure
through
inhalation.
Very
toxic
to
aquatic
organisms.
Possible
risk
of
harm
to
the
unborn
child.
Harmful:
may
cause
lung
damage
if
swallowed.
Vapours
may
cause
drowsiness
and
dizziness.
Toxic
to
Reproduction
Category
3
Dangerous
for
the
environment
Harmful
Further
information
The above information is believed to be correct but does not purport to be all inclusive and
shall be used only as a guide. The information this document is based on the resent state
of our knowledge and is applicable to the product with regard to appropriate safety precautions.
It does not represent any guarantee of the properties of the product. Lookchem shall not be
held liable for any damage resulting from handling or from contact with the above product.
See reverse side of invoice or packing slip for additional terms and conditions of sale.
| 
Sodium amide
China (Mainland)] 
Assessed
Assessed
Assessed
Assessed
Assessed
Assessed
Assessed
Assessed
Assessed
Assessed
Assessed
Assessed
Assessed
Assessed
United States]