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p-(2-Naphthylamino)phenol

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Name

p-(2-Naphthylamino)phenol

EINECS N/A
CAS No. 93-45-8 Density 1.251g/cm3
PSA 32.26000 LogP 4.36200
Solubility N/A Melting Point 139-142 °C(lit.)
Formula C16H13 N O Boiling Point 424.4°C at 760 mmHg
Molecular Weight 235.285 Flash Point 173.1°C
Transport Information N/A Appearance N/A
Safety Moderately toxic by ingestion. When heated to decomposition it emits toxic fumes of NOx. See also AROMATIC AMINES. Risk Codes 20/21/22-36/37/38-40
Molecular Structure Molecular Structure of 93-45-8 (N-(4-HYDROXYPHENYL)-2-NAPHTHYLAMINE, 97) Hazard Symbols
Synonyms

Phenol,p-(2-naphthylamino)- (7CI,8CI); 4-(2-Naphthylamino)phenol; 4-Hydroxyphenyl-b-naphthylamine;N-(4-Hydroxyphenyl)-2-naphthylamine; N-(p-Hydroxyphenyl)-2-naphthylamine;N-(p-Hydroxyphenyl)-b-naphthylamine; NSC 15372; NSC 21065; Paraoxyneozone;p-(2-Naphthylamino)phenol; p-(b-Naphthylamino)phenol; p-Hydroxyneozon; p-Hydroxyneozone;p-Hydroxyphenyl-2-naphthylamine; p-Hydroxyphenyl-b-naphthylamine

Article Data 12

p-(2-Naphthylamino)phenol Chemical Properties

IUPAC Name: 4-(Naphthalen-2-ylamino)phenol
Synonyms of p-(2-Naphthylamino)phenol (CAS NO.93-45-8): 4-(2-Naftylamino)fenol ; 4-(2-Naphthalenylamino)phenol ; 4-(2-Naphthylamino)phenol ; 4-Hydroxyphenyl-beta-naphthylamine ; N-p-Hydroxyphenyl-2-naphthylamine ; N-p-Hydroxyphenyl-beta-naphthylamine ; p-(beta-Naphthylamino)phenol ; p-Hydroxyneozon ; p-Hydroxyphenyl-2-naphthylamine ; p-Oxyneozone ; Phenol, 4-(2-naphthalenylamino)- ; Phenol, p-(2-naphthylamino)-
Product Categories: Intermediates of Dyes and Pigments
CAS NO: 93-45-8
Molecular Formula: C16H13NO
Molecular Weight: 235.2805
Molecular Structure :
EINECS: 202-248-7
H bond acceptors: 2
H bond donors: 2
Freely Rotating Bonds: 3
Polar Surface Area: 12.47 Å2
Index of Refraction: 1.733
Molar Refractivity: 75.35 cm3
Molar Volume: 188 cm3
Surface Tension: 58.2 dyne/cm
Density: 1.251 g/cm3
Flash Point: 173.1 °C
Enthalpy of Vaporization: 70.52 kJ/mol
Boiling Point: 424.4 °C at 760 mmHg
Vapour Pressure: 8.37E-08 mmHg at 25°C
Melting Point: 139-142 °C(lit.)
Stability: Stable. Incompatible with strong oxidizing agents.
Appearance: P-(2-Naphthylamino)phenol (CAS NO.93-45-8) is purple solid.
Water solubility: Insoluble in water.

p-(2-Naphthylamino)phenol Uses

 P-(2-Naphthylamino)phenol (CAS NO.93-45-8) is used for dyeing of cotton and Victoria / cotton blended fabric.

p-(2-Naphthylamino)phenol Production

 P-(2-Naphthylamino)phenol (CAS NO.93-45-8) can be derived from condensation of 2-Naphthol and p-Aminophenol .

p-(2-Naphthylamino)phenol Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LD50 oral 2200mg/kg (2200mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) Hygiene and Sanitation Vol. 31(1-3), Pg. 183, 1966.
rat LD50 oral 5200mg/kg (5200mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) Hygiene and Sanitation Vol. 31(1-3), Pg. 183, 1966.

p-(2-Naphthylamino)phenol Consensus Reports

Reported in EPA TSCA Inventory.

p-(2-Naphthylamino)phenol Safety Profile

Hazard Codes: HarmfulXn
Risk Statements: 20/21/22-36/37/38-40
R20/21/22: Harmful by inhalation, in contact with skin and if swallowed. 
R36/37/38: Irritating to eyes, respiratory system and skin. 
R40: Limited evidence of a carcinogenic effect.
Safety Statements: 26-36/37/39-45
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection. 
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
RTECS: SM1750000

 
Moderately toxic by ingestion. When heated to decomposition it emits toxic fumes of NOx. See also AROMATIC AMINES.

p-(2-Naphthylamino)phenol Specification

Phenols and cresols are much weaker as acids than common carboxylic acids ,which are incompatible with strong reducing substances such as hydrides, nitrides, alkali metals, and sulfides. Flammable gas (H2) is often generated, and the heat of the reaction may ignite the gas. Heat is also generated by the acid-base reaction between phenols and bases. Such heating may initiate polymerization of the organic compound.  Phenols are also nitrated very rapidly, even by dilute nitric acid.Phenols are sulfonated very readily (for example, by concentrated sulfuric acid at room temperature).

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