USD $23.00-25.00 / Kilogram
USD $3.00-10.00 / Kilogram
USD $10.00-16.00 / Kilogram
USD $20.00-25.00 / Kilogram
USD $10.00-16.00 / Kilogram
USD $15.00-50.00 / Kilogram
USD $15.00-50.00 / Kilogram
USD $10.00-16.00 / Kilogram
USD $15.00-50.00 / Kilogram
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4,4'-diphenylmethane diisocyanate basic information |
product name: | 4,4'-diphenylmethane diisocyanate |
synonyms: | 1,1’-methylenebis(4-isocyanato)-benzene;1,1’-methylenebis(4-isocyanato-benzen;1,1’-methylenebis(4-isocyanatobenzene);1,1’-methylenebis[4-isocyanato-benzen;1,1’-methylenebis[4-isocyanato-benzene;1,1’-methylenebis[4-isocyanotobenzene];1,1-methylenebis4-isocyanatobenzene;1-isocyanato-4-(4-isocyanatobenzyl)benzene |
cas: | 101-68-8 |
mf: | c15h10n2o2 |
mw: | 250.25 |
einecs: | 202-966-0 |
product categories: | diphenylmethanes (for high-performance polymer research);functional materials;reagent for high-performance polymer research;alphabetic;m;meta - meth |
mol file: | 101-68-8.mol |
4,4'-diphenylmethane diisocyanate chemical properties |
mp | 38-44 °c |
bp | 392 °c |
density | 1.19 |
fp | 196 °c |
storage temp. | refrigerator |
water solubility | decomposes |
freezingpoint | 37℃ |
sensitive | moisture sensitive/lachrymatory |
brn | 797662 |
stability: | stable. combustible. incompatible with strong oxidizing agents. reacts violently with alcohols. |
cas database reference | 101-68-8(cas database reference) |
nist chemistry reference | benzene, 1,1'-methylenebis[4-isocyanato-(101-68-8) |
epa substance registry system | benzene, 1,1'-methylenebis[4-isocyanato- (101-68-8) |
safety information |
hazard codes | xn,t,c |
risk statements | 42/43-36/37/38-20-48/20-40 |
safety statements | 45-36/37-23 |
ridadr | 2206 |
rtecs | nq9350000 |
hazard note | toxic/corrosive/lachrymatory/moisture sensitive |
hazardclass | 6.1 |
packinggroup | ii |
hs code | 29291090 |
hazardous substances data | 101-68-8(hazardous substances data) |
msds information |
provider | language |
---|---|
1,1'-methylenebis(4-isocyanatobenzene) | english |
acros | english |
alfa | english |
4,4'-diphenylmethane diisocyanate usage and synthesis |
chemical properties | white to light yellow flakes or crystals |
usage | diphenyl methane diisocyanate (mdi) is widely used in polyurethane coatings, this product is made of polyurethane foam used as a warm (cold), building materials, vehicle, ship parts; masterwork can made car block, buffer, synthetic leather, non plastic polyurethane, polyurethane elastic fiber, no plastic elastic fibers, films, adhesives. |
general description | diphenylmethane-4,4-diisocyanate is a light yellow colored solid. 4,4'-diphenylmethane diisocyanate is not soluble in water. 4,4'-diphenylmethane diisocyanate may be toxic by ingestion, inhalation, or skin absorption. if in a solution 4,4'-diphenylmethane diisocyanate may or may not burn depending on the nature of the material and/or the solvent. it's used to make plastics. |
air & water reactions | 4,4'-diphenylmethane diisocyanate is not soluble in water. |
reactivity profile | isocyanates and thioisocyanates, such as 4,4'-diphenylmethane diisocyanate, are incompatible with many classes of compounds, reacting exothermically to release toxic gases. reactions with amines, aldehydes, alcohols, alkali metals, ketones, mercaptans, strong oxidizers, hydrides, phenols, and peroxides can cause vigorous releases of heat. acids and bases initiate polymerization reactions in these materials. some isocyanates react with water to form amines and liberate carbon dioxide. base-catalysed reactions of isocyanates with alcohols should be carried out in inert solvents. such reactions in the absence of solvents often occur with explosive violence, [wischmeyer(1969)]. |
health hazard | breathlessness, chest discomfort, and reduced pulmonary function. |
4,4'-diphenylmethane diisocyanate preparation products and raw materials |
preparation products | polyurethane foams |
raw materials | sodium hydroxide-->nitric acid-->chlorine-->formaldehyde-->aniline-->carbon monoxide |