The unusual stereochemical behaviour of Ferrocenecarboxaldehyde (cas 12093-10-6) in reaction with chiral alkylammonium hypophosphite
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Add time:08/02/2019 Source:sciencedirect.com
The reaction of aldehydes with chiral α-methylbenzylammonium hypophosphite, which, in majority of cases led exclusively to one diastereoisomer, turned out to be much less stereoselective in case of Ferrocenecarboxaldehyde (cas 12093-10-6). Attempts have been undertaken to explain it.
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