ADMET copolymerization of divinyltetraethoxydisiloxane with 1,9-DECADIENE (cas 1647-16-1) catalyzed by Grubbs’ catalyst
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Add time:08/09/2019 Source:sciencedirect.com
The acyclic diene metathesis (ADMET) copolymerization of divinyltetraethoxydisiloxane with 1,9-DECADIENE (cas 1647-16-1), catalyzed by RuCl2(CHPh)(PCy3)2, is the first example of a siloxylene–vinylene–alkenylene copolymer reported in the literature. This copolymer was isolated and characterized by 1H, and 13C NMR spectroscopy and GPC analysis (Mn=18000, PDI=2.9).
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