Spectroscopic characterization and thermal structural analysis of the charge-transfer complexes formed in the reaction of 1-Methylpiperazine (cas 109-01-3) with σ- and π-acceptors
-
Add time:08/28/2019 Source:sciencedirect.com
Charge-transfer complexes between 1-Methylpiperazine (cas 109-01-3) (1MPIPZ) as a donor with the π-acceptors 7,7,8,8-tetracyanoquinodimethane (TCNQ), tetracyanoethylene (TCNE), 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ), 2,3,5,6-tetrachloro-1,4-benzoquinone (chloranil = CHL) and σ-acceptor iodine (I2) have been studied spectrophotometrically in chloroform at room temperature by electronic and infrared spectra as well as elemental and thermal analysis. The obtained results indicate the formation of 1:3 M ratio for 1MPIPZ with TCNQ and TCNE, and 1:1 M ratio for 1MPIPZ with DDQ, CHL, and I2. Based on the obtained data, the formed charge-transfer complexes were formulated as [(1MPIPZ)(TCNQ)3], [(1MPIPZ) (TCNE)3], [(1MPIPZ)(DDQ)], [(1MPIPZ)(CHL)] and [(1MPIPZ)2I]+ I3-.
We also recommend Trading Suppliers and Manufacturers of 1-Methylpiperazine (cas 109-01-3). Pls Click Website Link as below: cas 109-01-3 suppliers
Prev:1-Alkyl-1-Methylpiperazine (cas 109-01-3)-1,4-diium salts: Synthetic, acid–base, XRD-analytical, FT-IR, FT-Raman spectral and quantum chemical study
Next:Thermodynamic inhibition of 4-Methylmorpholine (cas 109-02-4) while forming sH hydrate with methane) - 【Back】【Close 】【Print】【Add to favorite 】
- Related Information
- 1-Alkyl-1-Methylpiperazine (cas 109-01-3)-1,4-diium salts: Synthetic, acid–base, XRD-analytical, FT-IR, FT-Raman spectral and quantum chemical study08/27/2019
- Determination of the polyamines in human toenails as 1-(5-fluoro-2,4-dinitrophenyl)-4-methylpiperazine derivatives using high-performance liquid chromatography08/26/2019
- Synthesis, characterization, Hirshfeld surface analysis and antioxidant activity of a novel organic-inorganic hybrid material 1-Methylpiperazine (cas 109-01-3)-1,4-diium bis(nitrate)08/25/2019
- A sensitive and accurate LC-MS/MS assay with the derivatization of 1-Amino-4-methylpiperazine applied to serum allopregnanolone, pregnenolone and androsterone in pre- and postmenopausal women08/24/2019
- NBO, HOMO, LUMO analysis and vibrational spectra (FTIR and FT Raman) of 1-Amino 4-methylpiperazine using ab initio HF and DFT methods08/23/2019
- CO2 solubility measurement and thermodynamic modeling for 1-Methylpiperazine (cas 109-01-3)/water/CO208/22/2019
- An Original Strategy for the Analysis of Degradation Products in CO2 Capture Emissions: Monitoring of an Innovative Blend 1-Methylpiperazine (cas 109-01-3)/piperazine/water in Pilot Conditions☆08/21/2019
- Monitoring of the blend 1-Methylpiperazine (cas 109-01-3)/piperazine/water for post-combustion CO2 capture. Part 1: Identification and quantification of degradation products08/20/2019
- Process Simulation for CO2 Capture with the Aqueous Solution of 1-Methylpiperazine (cas 109-01-3) and its Mixture with Piperazine☆08/19/2019
-
Health and Chemical more >
-
Related Products