Chemical Engineering ThermodynamicsNon-isothermal crystallization kinetics of Nylon 10T and Nylon 10T/1010 copolymers: Effect of Sebacic acid (cas 111-20-6) as a third comonomer☆

Add time:08/23/2019    Source:sciencedirect.com

Nylon 10T and Nylon 10T/1010 samples were synthesized by direct melt polymerization. The non-isothermal crystallization kinetics of Nylon 10T and Nylon 10T/1010 was investigated by means of differential scanning calorimetry (DSC). Jeziorny equation and Mo equation were applied to describe the non-isothermal crystallization kinetics of the Nylon 10T and the Nylon 10T/1010. The activation energies for non-isothermal crystallization were obtained by Vyazovkin's method and Friedman's method, respectively. These results showed that Jeziorny equation and Mo equation well described the non-isothermal crystallization kinetics of the Nylon 10T and the Nylon 10T/1010. It was found that the values of the activation energy for non-isothermal crystallization of the Nylon 10T/1010 were lower than those of the Nylon 10T at a given temperature or relative crystallinity degree, which revealed that crystallization ability of the Nylon 10T/1010 was higher. The crystal morphology was observed by means of a polarized optical microscope (POM) and X-ray diffraction (XRD). It was found that the addition of Sebacic acid (cas 111-20-6) comonomer not only did not change the crystal form of the Nylon 10T, but also significantly increased the number and decreased the size of spherulites. Comparing with the Nylon 10T, the crystallization rate was increased with the addition of the sebacic acid comonomer.

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