Effect of preparation method on the bimetallic NiCu/SAPO-11 catalysts for the hydroisomerization of n-Octane (cas 111-65-9)

Add time:08/22/2019    Source:sciencedirect.com

The bimetallic NiCu/SAPO-11 catalysts were prepared by co-impregnation, sequential impregnation, co-precipitation, and mechanical mixing methods. Powder X-ray diffraction, nitrogen adsorption-desorption, temperature-programmed desorption of ammonia, transmission electron microscopy, temperature-programmed reduction of hydrogen, and X-ray photoelectron spectroscopy were used to characterize the physicochemical properties of the catalysts. The catalytic performance of the catalysts was assessed by the hydroisomerization of n-octane. Results indicated that the conversion of n-octane and selectivity to n-octane isomers were related to the preparation methods of the catalysts. The catalysts with Ni-Cu alloy effectively restrained the hydrogenolysis reaction that decreases the selectivity of isomerization. The catalyst prepared by the mechanical mixing of NiO and CuO hardly formed Ni-Cu alloy, showing obvious hydrogenolysis and low selectivity to n-octane isomers. The unbalance between the metal and acid sites resulted in the low conversion of n-octane and selectivity to n-octane isomers. Among all the catalysts, the catalyst prepared by the co-impregnation method exhibited high catalytic activity and selectivity to n-octane isomers.

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