Ethylene/hexene living copolymerization and ethylene/METHYL 10-UNDECENOATE (cas 111-81-9) copolymerization by titanium complexes bearing phenoxy-phosphine or thiophenoxy-phosphine ligands
-
Add time:08/26/2019 Source:sciencedirect.com
Several non-metallocene-type titanium(IV) complexes containing phenoxy-phosphine or thiophenoxy-phosphine ligands of type, (2-R1-4-R2-6-PPh2-C6H2X)2TiCl2 (2a: X = O, R1 = R2 = t-Bu; 2b: X = O, R1 = R2 = cumyl; 2c: X = S, R1 = SiMe3, R2 = H) have been synthesized by treating TiCl4 with the corresponding ligands 2-R1-4-R2-6-PPh2-C6H2XH in the presence of n-BuLi. The complexes 2a–c were investigated as the catalysts for ethylene with 1-hexene and/or polar alkenes copolymerizations. The catalytic activity and the comonomer incorporation were highly dependent upon catalyst and reaction conditions employed. Among these complexes, 2a can not only promote ethylene/1-hexene living copolymerization at room temperature, but also can utilize ethylene with methyl 10-undecenoate copolymerization.
We also recommend Trading Suppliers and Manufacturers of METHYL 10-UNDECENOATE (cas 111-81-9). Pls Click Website Link as below: cas 111-81-9 suppliers
Prev:Recognition enhancement of oxidized and methyl-10-undecenoate functionalized porous silicon in gas phase photoluminescence sensing
Next:Effect of carboxylic acids on the metathesis of METHYL 10-UNDECENOATE (cas 111-81-9)) - 【Back】【Close 】【Print】【Add to favorite 】
- Related Information
- Valorisation of plant oil derivatives via metathesis reactions: Study of the cross-metathesis of methyl oleate with cinnamaldehyde08/28/2019
- Effect of carboxylic acids on the metathesis of METHYL 10-UNDECENOATE (cas 111-81-9)08/27/2019
- Recognition enhancement of oxidized and methyl-10-undecenoate functionalized porous silicon in gas phase photoluminescence sensing08/25/2019
- Hydroesterification of METHYL 10-UNDECENOATE (cas 111-81-9) in thermomorphic multicomponent solvent systems—Process development for the synthesis of sustainable polymer precursors08/24/2019
- Short ReviewRIFM fragrance ingredient safety assessment, butyl 10-undecenoate, CAS Registry Number 109-42-208/23/2019
- Evaluation of new density based model to correlate the solubilities of ricinoleic acid, methyl ricinoleate and METHYL 10-UNDECENOATE (cas 111-81-9) in supercritical carbon dioxide08/22/2019
- Experimental determination and association model for the solubilities of METHYL 10-UNDECENOATE (cas 111-81-9) with methyl ricinoleate in supercritical carbon dioxide08/21/2019
- Experimental determination and development of solution theory based model for the mixture solubilities of 10-undecenoic acid with METHYL 10-UNDECENOATE (cas 111-81-9) and methyl ricinoleate in supercritical carbon dioxide08/20/2019
-
Health and Chemical more >
-
Related Products
- Methyl 1-Benzyl-5-oxopyrrolidine-3-carboxylate
- Methyl (((methoxymethylphosphinothioyl)thio)acetyl)methylcarbamate
- Methyl (+)-(3R)-7-[4-(4-fluorophenyl)-6-isopropyl-2-(N-methyl-N-methanesulfonylamino)pyrimidin-5-yl]-3-hydroxy-5-oxo-(6E)-heptenoate
- Methyl (2-amino-5-methyl-1,3-thiazol-4-yl)acetate
- Methyl (2-chloromethyl)oxazole-4-carboxylate
- Methyl (2E)-3-(4-methylphenyl)propenoate
- Methyl (2E)-3-cyclohexylprop-2-enoate
- Methyl (2R)-2-[(tert-butoxycarbonyl)amino]-3-iodopropanoate
- Methyl (2R)-2-[4-(2,4-dichlorophenoxy)phenoxy]propanoate
- Methyl (2R)-2-amino-2-cyclohexylethanoate hydrochloride