The enthalpy of micellization of potassium decanoate (cas 13040-18-1) in solutions of H2O and D2O determined with microcalorimetry

Add time:09/03/2019    Source:sciencedirect.com

The microcalorimetrically determined heat of dilution data are used to evaluate the enthalpy of micellization at the CMC (ΔHM) for potassium decanoate (cas 13040-18-1) in H2O and D2O. The values for ΔHM based on a mass-action model are in good agreement with those determined graphically. That ΔHM in D2O is higher by 30% than in H2O at 298.4°K and that diminution in ΔHM at 307.9°K is observed in H2O are both consistent with the hydrogen bonding treatment of hydrophobic association.

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