Corrosion protection ability of self-assembled monolayer of 3-Amino-5-mercapto-1,2,4-triazole (cas 16691-43-3) on copper electrode
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Add time:09/08/2019 Source:sciencedirect.com
The self-assembled monolayer (SAM) of 3-Amino-5-mercapto-1,2,4-triazole (cas 16691-43-3) (AMTa) was formed on a copper surface and characterized using cyclic voltammetry, Fourier Transform Infra-red spectroscopy and scanning electron microscopy. Quantum chemical calculations suggested the stronger interaction between AMTa and copper. The protection ability of SAM has been evaluated using electrochemical impedance spectroscopy and potentiodynamic polarization measurements. The formed monolayer showed significant protection ability in 1% NaCl medium. The enhanced corrosion protection ability could be due to the compact film structure which blocks the electron transfer from the solution to AMTa monolayer modified copper substrate.
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