Synthesis of Benzoquinone Ansamycin‐Inspired Macrocyclic Lactams from Shikimic acid (cas 138-59-0)
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Add time:09/29/2019 Source:infona.pl
One is not like the other: The title approach proceeds by stepwise coupling of three relatively simple substrates. Three natural product‐inspired agents are described, one of which has natural product‐like toxicity for HeLa and MCF7 cells. It is isoform‐selective, thus targeting Hsp90α/β over Grp94, and adopts a conformation similar to that of geldanamycin when complexed with Hsp90.
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- Lipase-catalyzed enantio- and regioselective transformation of 3-epi-Shikimic acid (cas 138-59-0) derivatives as the key step for the entry of polyoxygenated carbacycles09/30/2019
- Expression of a hypovirulence-causing double-stranded RNA is associated with up-regulation of quinic acid pathway and down-regulation of Shikimic acid (cas 138-59-0) pathway in Rhizoctonia solani10/01/2019
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